公开(公告)号：US08012628B2

公开(公告)日：2011-09-06

申请号：US11762470

申请日：2007-06-13

申请人： Toshinori Kato ,  Tomohiro Ono ,  Shinji Nakai ,  Takeshi Nakano ,  Hiroyuki Ogi

发明人： Toshinori Kato ,  Tomohiro Ono ,  Shinji Nakai ,  Takeshi Nakano ,  Hiroyuki Ogi

IPC分类号： H01M2/16

CPC分类号： F03G7/005 ,  H01M2300/0082

摘要： This invention relates to an electrochemical device which comprises a molding containing as a main ingredient a copolymer (Z) and at least two mutually insulated electrodes in joint with the molding, wherein the copolymer (Z) comprises a polymer block (A) having as a main unit an aromatic vinyl compound unit and a polymer block (B) being incompatible with the polymer block (A), and has ion-conducting groups on the polymer block (A). The electrochemical device of the invention can be used particularly as an actuator device.

摘要翻译： 本发明涉及一种电化学装置，该电化学装置包含以成型物为主要成分的共聚物（Z）和至少两个相互绝缘的电极，其中共聚物（Z）包含聚合物嵌段（A） 主要单元是芳族乙烯基化合物单元和与聚合物嵌段（A）不相容的聚合物嵌段（B），并且在聚合物嵌段（A）上具有离子传导性基团。 本发明的电化学装置可以特别用作致动装置。

公开(公告)号：US20100233569A1

公开(公告)日：2010-09-16

申请号：US12162375

申请日：2007-01-18

申请人： Tomohiro Ono ,  Shinji Nakai ,  Masahiro kawasaki ,  Takeshi Nakano ,  Hiroyuki Ogi

发明人： Tomohiro Ono ,  Shinji Nakai ,  Masahiro kawasaki ,  Takeshi Nakano ,  Hiroyuki Ogi

IPC分类号： H01M8/10

CPC分类号： H01M8/1067 ,  H01M4/8814 ,  H01M4/8828 ,  H01M4/8882 ,  H01M4/8896 ,  H01M4/921 ,  H01M4/926 ,  H01M8/04197 ,  H01M8/1023 ,  H01M8/1053 ,  H01M2300/0094

摘要： A multilayer electrolyte membrane for polymer electrolyte fuel cells, consisting of a laminate of at least two polymer electrolyte membranes at least one of which membranes comprises a block copolymer (I) which comprises, as its constituents, a polymer block (A) having as a main unit an aromatic vinyl compound unit and a flexible polymer block (B), and has ion-conducting groups on polymer block (A); and a membrane electrode assembly and a polymer electrolyte fuel cell. The multilayer membrane is economical, mild to the environment, and has high ion conductivity and high methanol barrier properties, together. It is preferred, from the object, that at least two of the constitutive electrolyte membranes comprise block copolymer (I), and/or at least one of the constitutive electrolyte membranes has an ion exchange capacity of 0.7 meq/g or more and at least one of them has an ion exchange capacity of less than 0.7 meq/g.

摘要翻译： 一种用于聚合物电解质燃料电池的多层电解质膜，其由至少两个聚合物电解质膜的层压体组成，其中至少一个膜包含嵌段共聚物（I），其包含作为其组分的聚合物嵌段（A），其具有 主要单元为芳族乙烯基化合物单元和柔性聚合物嵌段（B），并且在聚合物嵌段（A）上具有离子传导基团; 以及膜电极组件和聚合物电解质燃料电池。 多层膜是经济的，对环境温和，并且具有高离子传导性和高甲醇屏障性能。 从目的而言，优选至少两种组成型电解质膜包含嵌段共聚物（I），和/或至少一种组成型电解质膜的离子交换容量为0.7meq / g以上，至少 其中一个离子交换容量小于0.7meq / g。

公开(公告)号：US08349513B2

公开(公告)日：2013-01-08

申请号：US12278794

申请日：2007-02-05

申请人： Tomohiro Ono ,  Shinji Nakai ,  Hiroyuki Ogi ,  Takeshi Nakano

发明人： Tomohiro Ono ,  Shinji Nakai ,  Hiroyuki Ogi ,  Takeshi Nakano

IPC分类号： H01M8/10

CPC分类号： C08F297/00 ,  C08F297/02 ,  C08J5/2243 ,  C08J2353/02 ,  C08L53/00 ,  C08L53/005 ,  C08L53/02 ,  C08L53/025 ,  H01B1/122 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1067 ,  H01M2300/0082 ,  Y02E60/523 ,  C08L2666/02

摘要： A polymer electrolyte membrane comprising as a main ingredient a block copolymer which comprises, as its constituents, a polymer block (A) having as a main unit an aromatic vinyl compound unit and a polymer block (B) forming a flexible phase, and has ion-conducting groups on the polymer block (A), said aromatic vinyl compound unit being such that the hydrogen atom bonded to the α-carbon atom is non-replaced or replaced with an alkyl group or an aryl group optionally having substituent(s), and at least one of hydrogen atoms directly bonded to the aromatic ring is replaced with an alkyl group; and a membrane electrode assembly and a polymer electrolyte fuel cell both of which uses it. The polymer block (A) can have a restraining phase, and/or can be cross-linked. The electrolyte membrane is mild to the environment, has a high ion conductivity and good bonding properties to electrodes, is excellent in moldability, and is not easily influenced by methanol; and displays excellent performance in polymer electrolyte fuel cells, particularly direct methanol fuel cells.

摘要翻译： 一种聚合物电解质膜，其包含作为主要成分的嵌段共聚物，该嵌段共聚物作为其成分，包含作为主要单元的芳族乙烯基化合物单元的聚合物嵌段（A）和形成柔性相的聚合物嵌段（B），并且具有离子 在聚合物嵌段（A）上的导电基团，所述芳香族乙烯基化合物单元使得与α-碳原子键合的氢原子不被任选具有取代基的烷基或芳基取代或取代， 直接与芳环键合的氢原子中的至少一个被烷基取代; 以及两者都使用它的膜电极组件和聚合物电解质燃料电池。 聚合物嵌段（A）可具有约束相，和/或可交联。 电解质膜对环境温和，离子电导率高，与电极接合性好，成型性优良，不易受甲醇影响; 并且在聚合物电解质燃料电池，特别是直接甲醇燃料电池中显示出优异的性能。

公开(公告)号：US20100167159A1

公开(公告)日：2010-07-01

申请号：US12278794

申请日：2007-02-05

申请人： Tomohiro Ono ,  Shinji Nakai ,  Hiroyuki Ogi ,  Takeshi Nakano

发明人： Tomohiro Ono ,  Shinji Nakai ,  Hiroyuki Ogi ,  Takeshi Nakano

IPC分类号： H01M8/10

CPC分类号： C08F297/00 ,  C08F297/02 ,  C08J5/2243 ,  C08J2353/02 ,  C08L53/00 ,  C08L53/005 ,  C08L53/02 ,  C08L53/025 ,  H01B1/122 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1067 ,  H01M2300/0082 ,  Y02E60/523 ,  C08L2666/02

摘要： A polymer electrolyte membrane comprising as a main ingredient a block copolymer which comprises, as its constituents, a polymer block (A) having as a main unit an aromatic vinyl compound unit and a polymer block (B) forming a flexible phase, and has ion-conducting groups on the polymer block (A), said aromatic vinyl compound unit being such that the hydrogen atom bonded to the α-carbon atom is non-replaced or replaced with an alkyl group or an aryl group optionally having substituent(s), and at least one of hydrogen atoms directly bonded to the aromatic ring is replaced with an alkyl group; and a membrane electrode assembly and a polymer electrolyte fuel cell both of which uses it. The polymer block (A) can have a restraining phase, and/or can be cross-linked. The electrolyte membrane is mild to the environment, has a high ion conductivity and good bonding properties to electrodes, is excellent in moldability, and is not easily influenced by methanol; and displays excellent performance in polymer electrolyte fuel cells, particularly direct methanol fuel cells.

摘要翻译： 一种聚合物电解质膜，其包含作为主要成分的嵌段共聚物，该嵌段共聚物作为其成分，包含作为主要单元的芳族乙烯基化合物单元的聚合物嵌段（A）和形成柔性相的聚合物嵌段（B），并且具有离子 在聚合物嵌段（A）上的导电基团，所述芳香族乙烯基化合物单元使得与α-碳原子键合的氢原子不被任选具有取代基的烷基或芳基取代或取代， 直接与芳环键合的氢原子中的至少一个被烷基取代; 以及两者都使用它的膜电极组件和聚合物电解质燃料电池。 聚合物嵌段（A）可具有约束相，和/或可交联。 电解质膜对环境温和，离子电导率高，与电极接合性好，成型性优良，不易受甲醇影响; 并且在聚合物电解质燃料电池，特别是直接甲醇燃料电池中显示出优异的性能。

公开(公告)号：US20090123804A1

公开(公告)日：2009-05-14

申请号：US11722834

申请日：2005-12-27

申请人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono

发明人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono

IPC分类号： H01M8/10

CPC分类号： H01M4/926 ,  H01B1/122 ,  H01M4/921 ,  H01M8/0289 ,  H01M8/1004 ,  H01M8/1018 ,  H01M8/1023 ,  H01M8/1072 ,  H01M8/1083 ,  Y02P70/56

摘要： This invention relates to a polymer electrolyte membrane for polymer electrolyte fuel cells, comprising a block copolymer which comprises, as its constituents, a polymer block (A) having as a main unit an aromatic vinyl compound unit whose α-carbon is quaternary carbon, and a flexible polymer block (B), and has ion-conducting groups on the polymer block (A).The electrolyte membrane of this invention is economical, mild to the environment and excellent in moldability and chemical stability and thus durability, and, therefore, can suitably be used in membrane electrode assemblies and polymer electrolyte fuel cells.

摘要翻译： 本发明涉及一种聚合物电解质燃料电池用聚合物电解质膜，其包含嵌段共聚物，其包含以α-碳为季碳作为主要单元的以聚碳酸酯为主体的聚合物嵌段（A），以及 柔性聚合物嵌段（B），并且在聚合物嵌段（A）上具有离子传导基团。 本发明的电解质膜经济，对环境温和，成型性和化学稳定性优异，耐久性优良，因此适用于膜电极组件和聚合物电解质燃料电池。

公开(公告)号：US20080113244A1

公开(公告)日：2008-05-15

申请号：US11722251

申请日：2005-12-20

申请人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono ,  Masahiro Rikukawa

发明人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono ,  Masahiro Rikukawa

IPC分类号： H01M8/10 ,  C08J5/20

CPC分类号： H01M4/8668 ,  C08F8/24 ,  C08F297/04 ,  H01B1/122 ,  H01M4/8605 ,  H01M4/8807 ,  H01M4/8896 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1081 ,  Y02P70/56

摘要： This invention relates to an ion-conducting binder used for a membrane electrode assembly for polymer electrolyte fuel cells, the assembly consisting of a polymer electrolyte membrane and two gas diffusion electrodes stuck to the polymer electrolyte membrane with the membrane put between the electrodes, which binder comprises a block copolymer which comprises a polymer block (A) having as a main unit an aromatic vinyl compound unit whose α-carbon is quaternary carbon, and a flexible polymer block (B), and has ion-conducting groups on the polymer block (A), and a solution or suspension thereof, and a membrane electrode assembly and a polymer electrolyte fuel cell.The ion-conducting binder, membrane electrode assembly and polymer electrolyte fuel cell of this invention are economical, mild to the environment and excellent in moldability and oxidation stability.

摘要翻译： 本发明涉及一种用于聚合物电解质燃料电池的膜电极组件的离子传导性粘合剂，该组合物由聚合物电解质膜和粘附在聚合物电解质膜上的两个气体扩散电极组成，膜间置于电极之间，该粘合剂 包括嵌段共聚物，其包含以α-碳为季碳作为主要单元的聚合物嵌段（A）和柔性聚合物嵌段（B），并且在聚合物嵌段上具有离子传导性基团 A）及其溶液或悬浮液，以及膜电极组件和聚合物电解质燃料电池。 本发明的离子导电粘合剂，膜电极组件和聚合物电解质燃料电池是经济的，对环境温和，并且成型性和氧化稳定性优异。

公开(公告)号：US08137860B2

公开(公告)日：2012-03-20

申请号：US11722834

申请日：2005-12-27

申请人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono

发明人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono

IPC分类号： H01M8/10

CPC分类号： H01M4/926 ,  H01B1/122 ,  H01M4/921 ,  H01M8/0289 ,  H01M8/1004 ,  H01M8/1018 ,  H01M8/1023 ,  H01M8/1072 ,  H01M8/1083 ,  Y02P70/56

摘要： This invention relates to a polymer electrolyte membrane for polymer electrolyte fuel cells, comprising a block copolymer which comprises, as its constituents, a polymer block (A) having as a main unit an aromatic vinyl compound unit whose α-carbon is quaternary carbon, and a flexible polymer block (B), and has ion-conducting groups on the polymer block (A).The electrolyte membrane of this invention is economical, mild to the environment and excellent in moldability and chemical stability and thus durability, and, therefore, can suitably be used in membrane electrode assemblies and polymer electrolyte fuel cells.

摘要翻译： 本发明涉及一种聚合物电解质燃料电池用聚合物电解质膜，其包含嵌段共聚物，该嵌段共聚物以α-碳为季碳为主成分的作为主体的聚合物嵌段（A）和芳香族乙烯基化合物单元， 柔性聚合物嵌段（B），并且在聚合物嵌段（A）上具有离子传导基团。 本发明的电解质膜经济，对环境温和，成型性和化学稳定性优异，耐久性优良，因此适用于膜电极组件和聚合物电解质燃料电池。

公开(公告)号：US07740968B2

公开(公告)日：2010-06-22

申请号：US11722251

申请日：2005-12-20

申请人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono ,  Masahiro Rikukawa

发明人： Takashi Yamashita ,  Shinji Nakai ,  Hiroyuki Ogi ,  Tomohiro Ono ,  Masahiro Rikukawa

IPC分类号： H01M8/10 ,  C08J5/20

CPC分类号： H01M4/8668 ,  C08F8/24 ,  C08F297/04 ,  H01B1/122 ,  H01M4/8605 ,  H01M4/8807 ,  H01M4/8896 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1081 ,  Y02P70/56

摘要： This invention relates to an ion-conducting binder used for a membrane electrode assembly for polymer electrolyte fuel cells, the assembly consisting of a polymer electrolyte membrane and two gas diffusion electrodes stuck to the polymer electrolyte membrane with the membrane put between the electrodes, which binder comprises a block copolymer which comprises a polymer block (A) having as a main unit an aromatic vinyl compound unit whose α-carbon is quaternary carbon, and a flexible polymer block (B), and has ion-conducting groups on the polymer block (A), and a solution or suspension thereof, and a membrane electrode assembly and a polymer electrolyte fuel cell.The ion-conducting binder, membrane electrode assembly and polymer electrolyte fuel cell of this invention are economical, mild to the environment and excellent in moldability and oxidation stability.

摘要翻译： 本发明涉及一种用于聚合物电解质燃料电池的膜电极组件的离子传导性粘合剂，该组合物由聚合物电解质膜和粘附在聚合物电解质膜上的两个气体扩散电极组成，膜间置于电极之间，该粘合剂 包括嵌段共聚物，其包含以α-碳为季碳作为主要单元的聚合物嵌段（A）和柔性聚合物嵌段（B），并且在聚合物嵌段上具有离子传导性基团 A）及其溶液或悬浮液，以及膜电极组件和聚合物电解质燃料电池。 本发明的离子导电粘合剂，膜电极组件和聚合物电解质燃料电池是经济的，对环境温和，并且成型性和氧化稳定性优异。

公开(公告)号：US20140166942A1

公开(公告)日：2014-06-19

申请号：US14008654

申请日：2012-03-30

申请人： Takafumi Izawa ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takuya Inagaki ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

发明人： Takafumi Izawa ,  Hiromasa Shibuya ,  Takashi Sugioka ,  Takuya Inagaki ,  Yasushi Morihara ,  Atsuhiro Nakahara ,  Akio Fujita ,  Hiroyuki Ogi

IPC分类号： H01L51/00

CPC分类号： H01L51/0036 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/126 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/344 ,  C08G2261/91 ,  C08K3/045 ,  H01L51/0043 ,  H01L51/4253 ,  C08L65/00

摘要： Provide are: a conjugated block copolymer capable of increasing the amount of optical absorption by a photoelectric conversion active layer and controlling the morphology thereof and capable of achieving excellent photoelectric conversion efficiency; and a photoelectric conversion element comprising a composition including an electron accepting material and this kind of conjugated block polymer. A π-electron conjugated block copolymer comprising: a polymer block (A) which involving a monomer unit having at least one heteroaryl skeleton selected from the group consisting of a fused π-conjugated skeleton, a fluorene, a carbazole, a dibenzosilole and a dibenzogermole containing at least one thiophene ring in a part of a chemical structure thereof; and a polymer block (B) involving a monomer unit of a thiophene-2,5-diyl group having a substituent at least at a 3-position thereof.

摘要翻译： 提供：能够增加光电转换活性层的光吸收量并控制其形态并能够获得优异的光电转换效率的共轭嵌段共聚物; 和包含电子接受材料和这种共轭嵌段聚合物的组合物的光电转换元件。 一种电子共轭嵌段共聚物，其包含：聚合物嵌段（A），其包含具有至少一个杂芳基骨架的单体单元，所述杂芳基骨架选自稠合和共轭骨架，芴，咔唑，二苯并噻唑和 在其化学结构的一部分中含有至少一个噻吩环的二苯并茂莫; 和包含至少在其3位具有取代基的噻吩-2,5-二基的单体单元的聚合物嵌段（B）。

公开(公告)号：US20090102302A1

公开(公告)日：2009-04-23

申请号：US12232981

申请日：2008-09-26

申请人： Hiroyuki Ogi

发明人： Hiroyuki Ogi

IPC分类号： H02K5/06

CPC分类号： H02K5/00

摘要： A vehicle alternator has a rotor fixed to a rotary shaft, a stator placed around the rotor so that the stator faces an outer periphery of the rotor, and a frame accommodating the rotor and stator. The frame has a drive frame and a rear frame. The drive frame has stay parts. One stay part projects toward the outside of the vehicle alternator, and has a U-shaped hole formed at a front thereof. A circular part with a cut part is formed in the stay part. The circular part with the cut part is coaxial with the U-shaped hole and is larger in diameter and central angle than the U-shaped hole. The stay part is fastened to a mounting bracket of an internal combustion engine while the cut part of the circular part in the stay part is fitted to a step part formed in a fixing bolt.

摘要翻译： 车辆用交流发电机具有固定在旋转轴上的转子，定子配置在转子周围，使得定子面向转子的外周，以及容纳转子和定子的框架。 框架具有驱动框架和后框架。 驱动架有保持部件。 一个支撑部朝向车辆交流发电机的外部突出，并且在其前方形成有U形孔。 在停留部分形成具有切割部分的圆形部分。 切割部分的圆形部分与U形孔同轴，直径和中心角比U形孔大。 将支撑部固定在内燃机的安装支架上，同时将支撑部分的圆形部分的切割部分装配到形成在固定螺栓中的台阶部分上。