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    Catalytic dewaxing process for producing lubricating oils
    1.
    发明授权
    Catalytic dewaxing process for producing lubricating oils 失效
    用于生产润滑油的催化脱蜡方法

    公开(公告)号：US06287454B1

    公开(公告)日：2001-09-11

    申请号：US08291320

    申请日：1994-08-16

    申请人： Thomas R. Forbus, Jr. ,  Chwan P. Kyan

    发明人： Thomas R. Forbus, Jr. ,  Chwan P. Kyan

    IPC分类号： C10G7302

    CPC分类号： C10G45/64 ,  C10G2400/10

    摘要： Lubricant oils of low pour point and improved oxidation stability are produced by catalytically dewaxing a lube feedstock over a zeolite dewaxing catalyst such as ZSM-5 in the hydrogen or decationized form. The use of these catalysts enables products of excellent oxidative stability to be obtained and reduces the catalyst aging rate in the first and subsequent dewaxing cycles to values below 5° F./day. The duration of the dewaxing cycles may be extended, particularly in the second and subsequent cycles after hydrogen reactivation.

    摘要翻译： 通过在沸石脱蜡催化剂如ZSM-5上以氢气或分解形式催化脱蜡润滑剂原料来制备低倾点和改善的氧化稳定性的润滑油。 使用这些催化剂可以获得优异的氧化稳定性的产物，并将第一次和随后的脱蜡循环中的催化剂老化速率降低到低于5°F /天的值。 脱蜡循环的持续时间可以延长，特别是在氢再活化后的第二个和随后的循环中。

    Catalytic dewaxing process for producing lubricating oils
    2.
    发明授权
    Catalytic dewaxing process for producing lubricating oils 失效
    用于生产润滑油的催化脱蜡方法

    公开(公告)号：US5456820A

    公开(公告)日：1995-10-10

    申请号：US812312

    申请日：1991-12-23

    申请人： Thomas R. Forbus, Jr. ,  David S. Shihabi ,  Chwan P. Kyan ,  Robert W. Bortz ,  Rene B. LaPierre

    发明人： Thomas R. Forbus, Jr. ,  David S. Shihabi ,  Chwan P. Kyan ,  Robert W. Bortz ,  Rene B. LaPierre

    IPC分类号： C10G45/64 ,  C10G47/16

    CPC分类号： C10G45/64 ,  C10G2400/10

    摘要： A process for making a lubricant oil of low pour point which comprises a) catalytically dewaxing a lube boiling range feedstock in the presence of hydrogen over a dewaxing catalyst comprising an intermediate pore size zeolite in the hydrogen or decationized form during a dewaxing cycle in which the temperature is progressively increased to maintain a substantially constant product pour point to produce a lubricant oil product of improved oxidation stability. The feedstock is sequenced during a dewaxing cycle from a heavy feed to a lighter feed in order to avoid contacting the lighter feed with the catalyst in its most active conditions.

    摘要翻译： 一种制备低倾点润滑油的方法，其包括：a）在氢气存在下催化脱蜡润滑油原料，在脱蜡循环期间，在含脱氢形式的氢气或脱盐形式的脱蜡催化剂中脱蜡催化剂， 逐渐增加温度以保持基本上恒定的产物倾点以产生改进的氧化稳定性的润滑油产品。 在从重进料到较轻进料的脱蜡循环期间将原料排序，以避免在其最活跃的条件下使较轻的进料与催化剂接触。

    Thermal treatment of petroleum residua with alkylaromatic or paraffinic co-reactant
    4.
    发明授权
    Thermal treatment of petroleum residua with alkylaromatic or paraffinic co-reactant 失效
    用烷基芳烃或链烷烃共反应物热处理石油渣

    公开(公告)号：US5370787A

    公开(公告)日：1994-12-06

    申请号：US55934

    申请日：1993-04-30

    申请人： Thomas R. Forbus, Jr.

    发明人： Thomas R. Forbus, Jr.

    IPC分类号： C10G9/00

    CPC分类号： C10G9/00

    摘要： Thermal treatment of heavy petroleum resid in the presence of moderate amounts of light aromatics or paraffins produces more liquid product at the expense of gas and coke than when treated alone under identical conditions.

    摘要翻译： 在中等量的轻质芳烃或链烷烃的存在下，重质石油渣的热处理以与在相同条件下单独处理相比，以气体和焦炭为代价产生更多的液体产物。

    Fluids having partially hydrogenated substituted styrene linear dimers and method of making same
    5.
    发明授权
    Fluids having partially hydrogenated substituted styrene linear dimers and method of making same 有权
    具有部分氢化取代苯乙烯线性二聚体的流体及其制备方法

    公开(公告)号：US07629303B2

    公开(公告)日：2009-12-08

    申请号：US11205679

    申请日：2005-08-17

    申请人： Mark Paul Hagemeister ,  Thomas R. Forbus, Jr.

    发明人： Mark Paul Hagemeister ,  Thomas R. Forbus, Jr.

    IPC分类号： C10M127/04 ,  C07C2/72

    CPC分类号： C07C13/28 ,  C07C15/12 ,  C10M105/02 ,  C10M111/02 ,  C10M171/002 ,  C10M2203/045 ,  C10M2203/06 ,  C10M2203/065 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/06 ,  C10N2230/60 ,  C10N2230/68 ,  C10N2240/046

    摘要： A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.

    摘要翻译： 包含完全氢化的取代的苯乙烯线型二聚体的基础油; 部分氢化的单芳族取代的苯乙烯线性二聚体; 和部分氢化的二芳族取代的苯乙烯线型二聚体。 一种制备基础油料的方法，包括在溶剂存在下使包含取代的苯乙烯，醇和二聚催化剂的进料流反应，以形成二聚取代的苯乙烯的粗浆料; 并且用氢在VIII族催化剂上部分氢化二聚取代的苯乙烯以形成包含完全氢化的取代的苯乙烯线性二聚体和部分氢化的取代的苯乙烯线型二聚体的基础油。

    Fluids having partially hydrogenated substituted styrene linear dimers and method of making same
    7.
    发明授权
    Fluids having partially hydrogenated substituted styrene linear dimers and method of making same 有权
    具有部分氢化取代苯乙烯线性二聚体的流体及其制备方法

    公开(公告)号：US08252735B2

    公开(公告)日：2012-08-28

    申请号：US12607758

    申请日：2009-10-28

    申请人： Mark Paul Hagemeister ,  Thomas R. Forbus, Jr.

    发明人： Mark Paul Hagemeister ,  Thomas R. Forbus, Jr.

    IPC分类号： C10M127/04 ,  C07C2/72

    CPC分类号： C07C13/28 ,  C07C15/12 ,  C10M105/02 ,  C10M111/02 ,  C10M171/002 ,  C10M2203/045 ,  C10M2203/06 ,  C10M2203/065 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/06 ,  C10N2230/60 ,  C10N2230/68 ,  C10N2240/046

    摘要： A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.

    摘要翻译： 包含完全氢化的取代的苯乙烯线型二聚体的基础油; 部分氢化的单芳族取代的苯乙烯线性二聚体; 和部分氢化的二芳族取代的苯乙烯线型二聚体。 一种制备基础油料的方法，包括在溶剂存在下使包含取代的苯乙烯，醇和二聚催化剂的进料流反应，以形成二聚取代的苯乙烯的粗浆料; 并且用氢在VIII族催化剂上部分氢化二聚取代的苯乙烯以形成包含完全氢化的取代的苯乙烯线性二聚体和部分氢化的取代的苯乙烯线型二聚体的基础油。

    Process for the production of reduced viscosity high VI hydrocarbon lubricant
    9.
    发明授权
    Process for the production of reduced viscosity high VI hydrocarbon lubricant 失效
    用于生产降粘度高VI烃类润滑剂的方法

    公开(公告)号：US4906799A

    公开(公告)日：1990-03-06

    申请号：US266041

    申请日：1988-11-02

    申请人： Thomas R. Forbus, Jr. ,  Andrew Jackson

    发明人： Thomas R. Forbus, Jr. ,  Andrew Jackson

    IPC分类号： C10G50/02

    CPC分类号： C10G50/02

    摘要： A process is disclosed for the production of low viscosity, high viscosity index liquid lubricant in high yield by the thermally-induced cleavage or pyrolysis of higher molecular weight oligomers of 1-alkenes. Further, it has been discovered that the reduced viscosity lubricants produced by pyrolysis of higher viscosity 1-alkene oligomers retain the superior characteristics of high viscosity index and low pour point of the starting material.The process comprises contacting C.sub.6 -C.sub.20 1-alkene feedstock with reduced valence state chromium oxide catalyst on porous silica support under oligomerizing conditions in an oligomerization zone whereby viscosity, high VI liquid hydrocarbon lubricant is produced having branch ratio less than 0.19 and pour point below --15.degree. C.; passing said high viscosity liquid lubricant through a pyrolysis zone under pyrolyzing conditions; separating reduced viscosity liquid hydrocarbon lubricant having high VI and low pour point.

    摘要翻译： 公开了通过1-烯烃的较高分子量低聚物的热诱导裂解或热解生产低粘度，高粘度指数液体润滑剂的方法，该产品以高产率生产。 此外，已经发现通过高粘度1-烯烃低聚物的热解生产的降粘性润滑剂保持了起始材料的高粘度指数和低倾点的优异特性。 该方法包括在低聚区域的低聚条件下使C6-C20 1-烯烃原料与多价二氧化硅载体上的还原价态氧化铬催化剂接触，由此产生具有分支比小于0.19并且倾点低于的粘度，高VI液态烃润滑剂， 15℃。 在热解条件下将所述高粘度液体润滑剂通过热解区; 分离具有高VI和低倾点的还原粘度液体烃润滑剂。

    Trialkymethane mixtures as synthetic lubricants
    10.
    发明授权
    Trialkymethane mixtures as synthetic lubricants 有权
    三烷基甲烷混合物作为合成润滑剂

    公开(公告)号：US6150574A

    公开(公告)日：2000-11-21

    申请号：US306091

    申请日：1999-05-06

    申请人： Thomas R. Forbus, Jr.

    发明人： Thomas R. Forbus, Jr.

    IPC分类号： C10M105/04 ,  C10N20/00 ,  C10N20/02 ,  C10N30/00 ,  C10N30/02 ,  C10N30/08 ,  C10N30/10 ,  C10N40/25 ,  C10N70/00 ,  C07C7/20

    CPC分类号： C10M105/04

    摘要： When different trialkyl methanes containing 25 through 36 carbon atoms are mixed the mixture exhibits surprisingly superior lubricant properties including low viscosity, high VI, low volatility, very low pour point and a dynamic viscosity at low temperatures that is less than those of PAO lubricants. Statistically predictable mixture compositions of mixed trialkyl methanes are prepared by reaction of mixtures of n-alkyl organometallic compounds with mixed aliphatic esters or equivalent compounds.

    摘要翻译： 当含有25至36个碳原子的不同三烷基甲烷混合时，混合物显示令人惊奇的优异的润滑剂性能，包括低粘度，高VI，低挥发性，非常低的倾点和在低于PAO润滑剂的低温下的动态粘度。 通过将正烷基有机金属化合物与混合脂族酯或等价化合物的混合物反应来制备混合三烷基甲烷的统计学上可预测的混合物组合物。