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1.发明申请(Meth)acrylate-grafted polyether polyol, and production process and use thereof 审中-公开（甲基）丙烯酸酯接枝聚醚多元醇及其制备方法和用途公开(公告)号：US20090111952A1
公开(公告)日：2009-04-30
申请号：US11991283
申请日：2006-08-31
IPC分类号： C08F283/06 , C08G18/36 , C09J151/08
CPC分类号： C08G18/632 , C08F283/06 , C08G18/638
摘要： A (meth)acrylate-grafted polyether polyol produced by reacting 40 to 95 parts by weight of a polyoxyalkylene polyol and 5 to 60 parts by weight of a vinyl monomer, both relative to 100 parts by weight of the sum total of the polyoxyalkylene polyol and the vinyl monomer, and 0.1 to 5 moles of an alkyl peroxide as a radical initiator per mole of the hydroxyl group in the polyoxyalkylene polyol, wherein the polyoxyalkylene polyol has a hydroxyl number of 25 mg KOH/g or less, and the vinyl monomer contains a (meth)acrylate and/or a hydroxyl-containing (meth)acrylate in an amount of 50% by weight or higher. The (meth)acrylate-grafted polyether polyol is excellent in colorless-transparency, compatibility, mechanical strength, weather resistance, and blending resistance, and therefore is useful as a raw material for a polyurethane resin cured article.
摘要翻译： 通过使40〜95重量份的聚氧化烯多元醇与5〜60重量份的乙烯基单体反应而得到的（甲基）丙烯酸酯接枝的聚醚多元醇，相对于100重量份的聚氧化烯多元醇和 乙烯基单体和0.1〜5摩尔作为自由基引发剂的烷基过氧化物，相对于聚氧化烯多元醇中的每摩尔羟基，其中聚氧化烯多元醇的羟值为25mgKOH / g以下，乙烯基单体含有 （甲基）丙烯酸酯和/或含羟基的（甲基）丙烯酸酯的量为50重量％以上。 （甲基）丙烯酸酯接枝聚醚多元醇的无色透明性，相容性，机械强度，耐候性和共混性优异，因此可用作聚氨酯树脂固化物的原料。
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公开(公告)号：US20070293631A1
公开(公告)日：2007-12-20
申请号：US11667953
申请日：2005-10-20
IPC分类号： C08F283/06 , C08G18/63 , C09J151/06
CPC分类号： C08G18/26 , C08F283/06 , C08G18/10 , C08G18/6229 , C08G18/632 , C08G18/638 , C09J175/04 , C08G18/40
摘要： A polyether polyol grafted with hydroxyl group-containing (meth)acrylate related to the present invention has an ester group represented by formula (1) below in the molecule. (In the formula, R1 represents a hydrogen atom or a methyl group, and R2 is an alkylene group having 1 to 18 carbon atoms.) This polyether polyol is suitably used as a raw material for polyurethane resin cured products excellent in mechanical strength and weather resistance.
摘要翻译： 与本发明相关的含羟基的（甲基）丙烯酸酯接枝的聚醚多元醇在分子中具有由下式（1）表示的酯基。 （式中，R 1表示氢原子或甲基，R 2是具有1〜18个碳原子的亚烷基。）该聚醚多元醇适当地 用作机械强度和耐候性优异的聚氨酯树脂固化产物的原料。
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3.发明申请ALKOXYSILANE-CONTAINING RESIN, MODIFIED ALKOXYSILANE-CONTAINING RESIN, THEIR PRODUCTION METHODS, HOT MELT ADHESIVE, AND RESIN CURED PRODUCT 审中-公开含烷氧基树脂，改性含烷氧基树脂，其生产方法，热熔胶和树脂固化产品公开(公告)号：US20100029860A1
公开(公告)日：2010-02-04
申请号：US12449461
申请日：2008-01-15
申请人： Shirou Honma , Tamotsu Kunihiro , Tsuyoshi Iwa
发明人： Shirou Honma , Tamotsu Kunihiro , Tsuyoshi Iwa
IPC分类号： C08G77/38
CPC分类号： C08G18/718 , C08G18/341 , C08G18/4202 , C08G18/4208 , C08G18/4238 , C08G18/757 , C08G18/7657 , C08G63/914 , C08G2170/20 , C09J167/00
摘要： An alkoxysilane-containing resin is produced by reacting a terminal carboxyl group-containing oligomer with an isocyanato alkoxysilane compound.
摘要翻译： 通过使含末端含羧基的低聚物与异氰酸酯基烷氧基硅烷化合物反应制造含烷氧基硅烷的树脂。
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4.发明申请A terminal isocyanate group-containing polyamide resin, alkoxysilane-modified polyamide resin, processes for production of the resins, hot-melt adhesive agent, and cured resin product 审中-公开含末端异氰酸酯基的聚酰胺树脂，烷氧基硅烷改性聚酰胺树脂，树脂的制造方法，热熔粘合剂和固化树脂产品公开(公告)号：US20100022717A1
公开(公告)日：2010-01-28
申请号：US12311285
申请日：2007-09-07
申请人： Shirou Honma , Tamotsu Kunihiro , Tsuyoshi Iwa
发明人： Shirou Honma , Tamotsu Kunihiro , Tsuyoshi Iwa
CPC分类号： C08G18/4263 , C08G18/10 , C08G18/36 , C08G18/752 , C08G2170/20 , C08G18/289
摘要： A terminal isocyanate group-containing polyamide resin can be produced by reacting a terminal carboxyl group-containing oligomer and a polyisocyanate compound at such a ratio that the amount of an isocyanate group exceeds that of a carboxyl group. An alkoxysilane-modified polyamide resin can be produced by reacting the terminal isocyanate group-containing polyamide resin with an alkoxysilane compound containing a secondary amine.
摘要翻译： 含末端含异氰酸酯基的聚酰胺树脂可以通过使含末端羧基的低聚物和多异氰酸酯化合物的比例使异氰酸酯基的量超过羧基的比例来制备。 烷氧基硅烷改性聚酰胺树脂可以通过使含末端异氰酸酯基团的聚酰胺树脂与含有仲胺的烷氧基硅烷化合物反应来制备。
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5.发明授权公开(公告)号：US09382372B2
公开(公告)日：2016-07-05
申请号：US13814437
申请日：2011-08-08
申请人： Mikio Matsufuji , Tamotsu Kunihiro , Atsushi Miyata , Shinsuke Matsumoto , Koichi Sano , Toru Hiraide
发明人： Mikio Matsufuji , Tamotsu Kunihiro , Atsushi Miyata , Shinsuke Matsumoto , Koichi Sano , Toru Hiraide
IPC分类号： C08G18/32 , C08G18/48 , C08G18/63 , C08G18/76 , C07C31/18 , C08G18/40 , C07C41/02 , C07C41/03 , C07C43/178 , C08G101/00
CPC分类号： C08G18/3212 , C07C31/18 , C07C41/02 , C07C41/03 , C07C43/178 , C08G18/3206 , C08G18/4072 , C08G18/48 , C08G18/4841 , C08G18/632 , C08G18/7664 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： Disclosed are a polyol with a molecular weight distribution Mw/Mn of 4 or more, obtained by reacting a compound comprising an alkylene oxide compound (II) having a hydroxyl group in a base polyol (I) with a molecular weight of 2000 or more; and a polyol composition for a flexible polyurethane foam, comprising a polyol compound and a crosslinker, wherein the crosslinker comprises a polyol (a) with a hydroxyl value of 50 to 1100 mgKOH/g and with a primary hydroxylate ratio of 25% or more and 60% or less, which is obtained by an addition of a compound comprising alkylene oxide compound (ii) having a hydroxyl group to active hydrogen compound (i).
摘要翻译： 公开了通过在基础多元醇（I）中具有羟基的烯化氧化合物（II）的化合物与分子量为2000以上的化合物反应得到的分子量分布Mw / Mn为4以上的多元醇; 和含有多元醇化合物和交联剂的软质聚氨酯泡沫塑料用多元醇组合物，其中交联剂包含羟基值为50〜1100mgKOH / g，羟基羟基化合物的比例为25％以上的多元醇（a）和 通过向活性氢化合物（i）中加入包含具有羟基的烯化氧化合物（ⅱ）的化合物而得到的含量为60％以下。
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公开(公告)号：US20130131208A1
公开(公告)日：2013-05-23
申请号：US13814437
申请日：2011-08-08
申请人： Mikio Matsufuji , Tamotsu Kunihiro , Atsushi Miyata , Shinsuke Matsumoto , Koichi Sano , Toru Hiraide
发明人： Mikio Matsufuji , Tamotsu Kunihiro , Atsushi Miyata , Shinsuke Matsumoto , Koichi Sano , Toru Hiraide
CPC分类号： C08G18/3212 , C07C31/18 , C07C41/02 , C07C41/03 , C07C43/178 , C08G18/3206 , C08G18/4072 , C08G18/48 , C08G18/4841 , C08G18/632 , C08G18/7664 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： Disclosed are a polyol with a molecular weight distribution Mw/Mn of 4 or more, obtained by reacting a compound comprising an alkylene oxide compound (II) having a hydroxyl group in a base polyol (I) with a molecular weight of 2000 or more; and a polyol composition for a flexible polyurethane foam, comprising a polyol compound and a crosslinker, wherein the crosslinker comprises a polyol (a) with a hydroxyl value of 50 to 1100 mgKOH/g and with a primary hydroxylate ratio of 25% or more and 60% or less, which is obtained by an addition of a compound comprising alkylene oxide compound (ii) having a hydroxyl group to active hydrogen compound (i).
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7.发明申请POLYESTER POLYOL COMPOSITION FOR POLYURETHANE, COMPOSITION FOR POLYURETHANE FOAM, POLYURETHANE RESIN, AND POLYURETHANE FOAM 审中-公开用于聚氨酯的聚酯多元醇组合物，聚氨酯泡沫的组合物，聚氨酯树脂和聚氨酯泡沫公开(公告)号：US20110166245A1
公开(公告)日：2011-07-07
申请号：US13055999
申请日：2009-07-28
CPC分类号： C08G18/36 , C08G18/4072 , C08G18/4266 , C08G18/4288 , C08G18/4841 , C08G18/632 , C08G18/72 , C08G63/06 , C08G63/60 , C08G2101/0008 , C08G2101/0083 , C08J9/12 , C08J2375/06
摘要： The present invention provides a polyester polyol, preferably a plant-derived polyester polyol, suitable for a composition for polyurethane foam that contributes to the reduction of load on the environment and has a good balance of high resilience, moderate hardness, and high durability as a cushioning material for vehicle seat cushions. A polyester polyol having a hydroxyl value in the range of 15 to 100 mgKOH/g according to the present invention is produced by a condensation of raw materials comprising at least one selected from the group consisting of fatty acids having a hydroxy group and fatty acid esters having a hydroxy group with a polyhydric alcohol having an average number of functional groups of more than three but not more than eight. The raw materials contain 90% to 100% by mass of a fatty acid having a hydroxy group and a fatty acid ester having a hydroxy group in total.
摘要翻译： 本发明提供一种聚酯多元醇，优选植物衍生的聚酯多元醇，其适用于聚氨酯泡沫的组合物，其有助于降低环境负荷，并且具有高弹性，适度硬度和高耐久性的良好平衡，如 汽车座垫缓冲材料。 本发明的羟值在15〜100mgKOH / g范围内的聚酯多元醇是通过将包含羟基的脂肪酸和脂肪酸酯中的至少一种的原料缩合制成的 具有羟基与多官能团的平均数大于3但不大于8的多元醇。 原料含有90〜100质量％的具有羟基的脂肪酸和总共具有羟基的脂肪酸酯。
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8.发明申请Thermoplastic polymer, thermoplastic polymer composition, antistatic agent, and resin composition 审中-公开热塑性聚合物，热塑性聚合物组合物，抗静电剂和树脂组合物公开(公告)号：US20060155096A1
公开(公告)日：2006-07-13
申请号：US10528335
申请日：2003-09-22
IPC分类号： C08G18/52
CPC分类号： C08G18/73 , C08G18/4879 , C08G18/506 , C08L23/06 , C08L75/08 , C08L2666/06
摘要： A thermoplastic polymer compound can be obtained by allowing a compound having a bivalent organic group to react with a polyoxyalkylene diol obtained by addition-polymerization of an urea compound having a partial structure refractivity of 14 to 35 and a dipole moment of 2.5 D to 5.5 D with an alkylene oxide. A thermoplastic polymer composition comprises the thermoplastic polymer compound and an inorganic salt of an alkali metal or the like. The polymer compound and the polymer composition are useful as an antistatic agent and have excellent antistatic properties and excellent transparency.
摘要翻译： 热塑性聚合物化合物可以通过使具有二价有机基团的化合物与通过将部分结构折射率为14〜35的偶氮二异氰酸酯化合物加成聚合的聚氧化亚烷基二醇与2.5D〜5.5D的偶极矩反应而得到 与烯化氧。 热塑性聚合物组合物包含热塑性聚合物化合物和碱金属等的无机盐。 高分子化合物和聚合物组合物可用作抗静电剂，具有优异的抗静电性和优异的透明性。
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公开(公告)号：US06410676B1
公开(公告)日：2002-06-25
申请号：US09555338
申请日：2000-05-30
申请人： Satoshi Yamasaki , Yasunori Hara , Tamotsu Kunihiro , Fumio Yamazaki , Mikio Matsufuji , Ariko Nishikawa , Shinsuke Matsumoto , Tsukuru Izukawa , Masahiro Isobe , Kazuhiko Ohkubo , Kaoru Ueno
发明人： Satoshi Yamasaki , Yasunori Hara , Tamotsu Kunihiro , Fumio Yamazaki , Mikio Matsufuji , Ariko Nishikawa , Shinsuke Matsumoto , Tsukuru Izukawa , Masahiro Isobe , Kazuhiko Ohkubo , Kaoru Ueno
IPC分类号： C08G1848
CPC分类号： C08G18/48 , C08G65/2642 , C08G65/2675 , C08G65/30
摘要： The object is to provide a method for producing a polyoxyalkylene polyol and a method for producing a derivative thereof wherein the remaining catalyst compound is efficiently removed from a crude polyoxyalkylene polyol by a simple manner, and a method for producing a polyoxyalkylene polyol wherein a crude polyoxyalkylene polyol is produced by addition polymerization of an epoxide compound to an active hydrogen compound using as a catalyst a compound having a P═N bond, then, the crude polyoxyalkylene polyol is allowed to contact with a solid acid having a specific surface area of 450 to 1200 m2/g and an average pore diameter of 40 to 100 Å to control the catalyst-remaining amount in the polyoxyalkylene polyol to 150 ppm or less, and a method for producing a derivative of the-above-described polyol are provided.
摘要翻译： 本发明的目的是提供一种聚氧化烯多元醇的制造方法及其衍生物的制造方法，其中通过简单的方法从粗聚氧化烯多元醇中有效地除去剩余的催化剂化合物，以及聚氧化烯多元醇的制备方法，其中粗聚氧化烯 通过使用P = N键的化合物作为催化剂将环氧化合物加成活性氢化合物，然后使粗聚氧化烯多元醇与比表面积为450的固体酸接触，生成多元醇 1200m 2 / g，平均孔径为40〜100，将聚氧化烯多元醇中的催化剂残留量控制在150ppm以下，提供上述多元醇的衍生物的制造方法。
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10.发明授权Polyurethane foam prepared from high concentration-low viscosity polymer-polyol 失效聚氨酯泡沫由高浓度低粘度聚合物多元醇制成
公开(公告)号：US5416123A
公开(公告)日：1995-05-16
申请号：US233945
申请日：1994-04-28
CPC分类号： C08G18/4072 , C08F283/06 , C08G18/63 , C08G2101/005
摘要： High concentration-low viscosity polymer-polyols are prepared by polymerizing mixtures of acrylonitrile and styrene in polyols, which are free of any polymerizable carbon-carbon double bond, in the presence of alkyl-substituted tertiary amines. Without use, as a dispersion stabilizer, of organic compounds which have a polymerizable carbon-carbon double bond and terminal hydroxyl groups, there can be obtained polymer-polyols which have a concentration of the polymer of 33-60 wt % and a glass transition temperature of the polymer of 90.degree.-120.degree. C.
摘要翻译： 在烷基取代的叔胺存在下，通过聚合丙烯腈和苯乙烯的混合物在不含任何可聚合碳 - 碳双键的多元醇中制备高浓度 - 低粘度聚合物 - 多元醇。 不用作为具有可聚合碳 - 碳双键和末端羟基的有机化合物作为分散稳定剂，可以得到聚合物的浓度为33〜60重量％，玻璃化转变温度 的聚合物为90°-120℃
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