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公开(公告)号：US20070260099A1
公开(公告)日：2007-11-08
申请号：US10589141
申请日：2004-02-16
申请人： Sumit Bhaduri , Virendra Gupta , Krishna Sarma
发明人： Sumit Bhaduri , Virendra Gupta , Krishna Sarma
CPC分类号： C08F110/06 , C08F4/6494
摘要： Catalytic system for polymerization of lower alpha alkene including a selectivity control agent which consists of naturally derived pure isomers of tartrates such as esters of (2-R,3-R)-dihydroxy-butane-1,4dicarboxylic acid or (2-S,3-S)-dihydroxybutane-1,4-dicarboxylic acid. The molar ratio of the optically pure isomers of the tartrates to titanium being 0.0375 to 1.5.
摘要翻译： 用于聚合低级α-烯烃的催化体系包括选择性控制剂，其由天然衍生的酒石酸酯的纯异构体如（2-R，3-R） - 二羟基 - 丁烷-1,4-二羧酸或（2-S， 3-S） - 二羟基丁烷-1,4-二羧酸。 酒石酸盐的旋光纯异构体与钛的摩尔比为0.0375〜1.5。
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2.发明申请Single step process for the preparation of lower alpha-alkene polymerization heterogeneous solid catalyst 有权用于制备低级α-烯烃聚合异相固体催化剂的单步法公开(公告)号：US20060217503A1
公开(公告)日：2006-09-28
申请号：US10552217
申请日：2003-04-10
申请人： Sumit Bhaduri , Virendra Gupta , Krishna Sarma
发明人： Sumit Bhaduri , Virendra Gupta , Krishna Sarma
CPC分类号： C08F110/00 , C08F110/02 , C08F110/06 , C08F4/651 , C08F4/654
摘要： Single step process for the preparation of lower α-alkene polymerisation heterogeneous solid catalyst, wherein the procatalyst is obtained by reacting organomagnesium precursor and titanium tetrahalide or titanium haloalkoxo species of the formula Ti(OR)m Xn, with a hydrocarbon or halohydrocarbon solvent and internal electron donor and optionally an acid halide under microwave irradiation of 300 to 1200 W. The mole ratio of the organomagnesium precursor to the titanium tetrachloride or titanium haloalko species is 1:6 to 1:20 and the mole ratios of the electron donor and acid halide to titanium is 0.3 to 1.5 and 0.02 to 0.2, respectively.
摘要翻译： 用于制备低级α-烯烃聚合异相固体催化剂的单步法，其中通过有机镁前体和式Ti（OR）m Xn的四卤化钛或卤代烷氧基钛与烃或卤代烃溶剂和内部 电子给体和任选的酰卤，在微波辐射下为300〜1200W。有机镁前体与四氯化钛或钛卤代烷烃的摩尔比为1:6〜1:20，电子给体和酰卤的摩尔比 钛分别为0.3〜1.5,0.02〜0.2。
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3.发明授权Single step process for the preparation of lower α-alkene polymerization heterogeneous solid catalyst 有权用于制备低级α-烯烃聚合异相固体催化剂的单步法公开(公告)号：US07265074B2
公开(公告)日：2007-09-04
申请号：US10552217
申请日：2003-04-10
CPC分类号： C08F110/00 , C08F110/02 , C08F110/06 , C08F4/651 , C08F4/654
摘要： Single step process for the preparation of lower α-alkene polymerisation heterogeneous solid catalyst, wherein the procatalyst is obtained by reacting organomagnesium precursor and titanium tetrahalide or titanium haloalkoxo species of the formula Ti(OR)m Xn, with a hydrocarbon or halohydrocarbon solvent and internal electron donor and optionally an acid halide under microwave irradiation of 300 to 1200 W. The mole ratio of the organomagnesium precursor to the titanium tetrachloride or titanium haloalko species is 1:6 to 1:20 and the mole ratios of the electron donor and acid halide to titanium is 0.3 to 1.5 and 0.02 to 0.2, respectively.
摘要翻译： 用于制备低级α-烯烃聚合异相固体催化剂的单步法，其中通过有机镁前体和式Ti（OR）m Xn的四卤化钛或卤代烷氧基钛与烃或卤代烃溶剂和内部 电子给体和任选的酰卤，在微波辐射下为300〜1200W。有机镁前体与四氯化钛或钛卤代烷烃的摩尔比为1:6〜1:20，电子给体和酰卤的摩尔比 钛分别为0.3〜1.5,0.02〜0.2。
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