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    Single step process for the preparation of lower α-alkene polymerization heterogeneous solid catalyst
    1.
    发明授权
    Single step process for the preparation of lower α-alkene polymerization heterogeneous solid catalyst 有权
    用于制备低级α-烯烃聚合异相固体催化剂的单步法

    公开(公告)号：US07265074B2

    公开(公告)日：2007-09-04

    申请号：US10552217

    申请日：2003-04-10

    申请人： Sumit Bhaduri ,  Virendra Kumar Gupta ,  Krishna Sarma

    发明人： Sumit Bhaduri ,  Virendra Kumar Gupta ,  Krishna Sarma

    IPC分类号： C08F4/626 ,  C08F4/64

    CPC分类号： C08F110/00 ,  C08F110/02 ,  C08F110/06 ,  C08F4/651 ,  C08F4/654

    摘要： Single step process for the preparation of lower α-alkene polymerisation heterogeneous solid catalyst, wherein the procatalyst is obtained by reacting organomagnesium precursor and titanium tetrahalide or titanium haloalkoxo species of the formula Ti(OR)m Xn, with a hydrocarbon or halohydrocarbon solvent and internal electron donor and optionally an acid halide under microwave irradiation of 300 to 1200 W. The mole ratio of the organomagnesium precursor to the titanium tetrachloride or titanium haloalko species is 1:6 to 1:20 and the mole ratios of the electron donor and acid halide to titanium is 0.3 to 1.5 and 0.02 to 0.2, respectively.

    摘要翻译： 用于制备低级α-烯烃聚合异相固体催化剂的单步法，其中通过有机镁前体和式Ti（OR）m Xn的四卤化钛或卤代烷氧基钛与烃或卤代烃溶剂和内部 电子给体和任选的酰卤，在微波辐射下为300〜1200W。有机镁前体与四氯化钛或钛卤代烷烃的摩尔比为1:6〜1:20，电子给体和酰卤的摩尔比 钛分别为0.3〜1.5,0.02〜0.2。

    Olefin polymerization titanium catalyst
    2.
    发明授权
    Olefin polymerization titanium catalyst 失效
    烯烃聚合钛催化剂

    公开(公告)号：US06969747B2

    公开(公告)日：2005-11-29

    申请号：US10502219

    申请日：2002-01-25

    申请人： Sumit Bhaduri ,  Virendra Kumar Gupta

    发明人： Sumit Bhaduri ,  Virendra Kumar Gupta

    IPC分类号： C08F4/649 ,  C08F10/00 ,  C08F110/02

    CPC分类号： C08F110/02 ,  C08F10/00 ,  Y10S526/904 ,  C08F4/6428 ,  C08F4/651 ,  C08F4/655 ,  C08F4/027

    摘要： An olefin polymerization titanium catalyst. It comprises a titanium compound and an organoaluminium compound cocatalyst supported on a soluble polysulfone comprising free reactive sulfone groups. The molar ratio of titanium of aluminum is 1–10:200 and the weight ratio of titanium to polysulfone is 0.01–0.1:0.3–2.5. The process for preparing the catalyst comprises preparing a supported titanium compound by contacting a solution of a polysulfone in a halogenated or polar solvent with a titanium compound or a solution thereof in a halogenated or polar solvent in an inert atmosphere at a temperature between 10° C. and the boiling point of the solvent such that the weight ratio of titanium to polysulfone is 0.01–0.1:0.3–2.5. The supported titanium compound is mixed with an organoaluminium cocatalyst such that the molar ratio of titanium to aluminum is 1–10:200.

    摘要翻译： 烯烃聚合钛催化剂。 它包括负载在包含游离反应性砜基团的可溶性聚砜上的钛化合物和有机铝化合物助催化剂。 铝的摩尔比为1-10：200，钛与聚砜的重量比为0.01-0.1：0.3-2.5。 制备催化剂的方法包括通过使卤化或极性溶剂中的聚砜溶液与卤化或极性溶剂中的钛化合物或其溶液在惰性气氛中在10℃的温度下接触来制备负载的钛化合物 和溶剂的沸点，使得钛与聚砜的重量比为0.01-0.1:0.3-2.5。 将负载的钛化合物与有机铝助催化剂混合，使得钛与铝的摩尔比为1-10:200。

    Lower α-alkene polymerization heterogeneous solid catalyst
    3.
    发明授权
    Lower α-alkene polymerization heterogeneous solid catalyst 失效
    低级烯烃聚合异相固体催化剂

    公开(公告)号：US06841633B2

    公开(公告)日：2005-01-11

    申请号：US10110045

    申请日：2000-11-29

    申请人： Sumit Bhaduri ,  Virendra Kumar Gupta

    发明人： Sumit Bhaduri ,  Virendra Kumar Gupta

    IPC分类号： C08F4/654 ,  C08F10/00 ,  C08F210/06 ,  C08F4/42

    CPC分类号： C08F10/00 ,  C08F210/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F210/14 ,  C08F2500/15

    摘要： A lower α-alkene polymerization heterogeneous solid catalyst which comprises a hydrated magnesium chloride derived procatalyst, a cocatalyst comprising an organoaluminium compound and a selectivity control agent comprising an ester or ether. The procatalyst comprises a titanium tetrahalide supported on a magnesium chloride ester complex precursor. Magnesium chloride alcoholate is reacted with an activated carbonyl compound in the presence of a hydrocarbon and/or halohydrocarbon solvent to generate insitu an internal electron donor ester component of the precursor. The precursor is reacted with a titanium tetrahalide optionally in the presence of a hydrocarbon and/or halohydrocarbon solvent.

    摘要翻译： 低级α-烯烃聚合异相固体催化剂，其包含水合氯化镁衍生的原催化剂，包含有机铝化合物的助催化剂和包含酯或醚的选择性控制剂。 前催化剂包括负载在氯化镁酯复合物前体上的四卤化钛。 在烃和/或卤代烃溶剂的存在下，氯化镁醇化物与活化的羰基化合物反应以产生前体的内部电子给体酯组分。 任选地在烃和/或卤代烃溶剂的存在下将前体与四卤化钛反应。