Abstract:
An amidine containing at least one structural unit of the formula (I) and the use thereof as catalyst for the crosslinking of a functional compound, especially of a polymer having silane groups. The amidine is preparable in a simple process from readily available starting materials, is largely odorless at room temperature and is of low toxicity. It accelerates the crosslinking of functional compounds surprisingly efficiently and can be adjusted for optimal compatibility with different compositions via the radical to which the structural units of the formula (I) is bonded, which means that such compositions do not have a tendency to migration-related defects such as separation, exudation or substrate soiling.
Abstract:
The invention relates to dioxomolybdenum (VI) complex compounds of the formula MoO2(L)x(Y)2-x, where the ligand L has the formula (I). Such complex compounds are suitable in particular as catalysts for one- and two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such dioxomolybdenum (VI) complex compound as the catalyst. The invention further relates to one-component polyurethane compositions comprising at least one polyurethane prepolymer with isocyanate groups, which are made from at least one polyisocyanate with at least one polyol, and comprising such a dioxomolybdenum (VI) complex compound as the catalyst. The invention additionally relates to different uses of said polyurethane compositions.
Abstract:
A silane of the formula (I) containing at least one aliphatic amidine group- or guanidine group-containing alkoxy group, to a method for producing same, to conversion products thereof, and to the use thereof as a catalyst in curable compositions, in particular based on silane group-containing polymers. The silane of the formula (I) is largely odorless and non-volatile at room temperature. The silane accelerates the hydrolysis and condensation reaction of silane groups very effectively without impairing the storage stability of silane group-containing polymers. Additionally, the silane is very tolerable in silane group-containing compositions, whereby such compositions are not prone to separate, migrate, or evaporate the catalyst.
Abstract:
The invention relates to a two-component polyurethane composition containing a polyol, a polyisocyanate, a blocked amine and a bismuth(III)- or zirconium(IV)-catalyst. The composition is easy to process, cures quickly and without bubbles, and has unexpectedly high strengths when in its cured state. It is particularly suitable as an adhesive, sealant, coating or potting compound.
Abstract:
The present invention relates to zinc(II) complex compounds of the formula Zn(L)x(Y)2-x, wherein the ligand L has the formula (I). Such complex compounds are particularly suitable as catalysts for two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as a first component, at least one polyol as a second component and at least one such zinc(II) complex compound as a catalyst. In addition, the invention relates to various uses of these two-component polyurethane compositions.
Abstract:
The present invention relates to iron (III) complexes of the formula Fe(L)x(Y)3-x, where the ligand L has the formula (I). Such complexes are especially suitable as a catalyst for two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions comprising at least one polyisocyanate as the first component, at least one polyol as the second component and at least one iron (III) complex of this kind as a catalyst. In addition, the invention relates to various uses of these two-component polyurethane compositions.
Abstract:
Invention relates to bismuth-containing catalysts, obtainable by reacting at least one bismuth(III) salt or bismuth(III) complex with at least one 1,3-ketoamide with the formula (I). Such complex compounds are suited in particular as catalysts for one- and two-component polyurethane compositions. The invention further relates to two-component polyurethane compositions, including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such bismuth-containing catalyst. The invention further relates one-component polyurethane compositions, including at least one polyurethane prepolymer having isocyanate groups, produced from at least one polyisocyanate with at least one polyol, and one such bismuth-containing catalyst. The invention also relates to various uses of the aforementioned polyurethane compositions.
Abstract:
The present invention relates to an amidine of the formula (I) and its use as a catalyst for crosslinking a curable composition. The amidine of the formula (I) contains at least one aliphatic amidine group. It is substantially odorless and nonvolatile at room temperature and accelerates the crosslinking of curable compositions very efficiently, without impairing the storage stability of the compositions. It is particularly suitable for compositions based on polymers containing silane groups, with which it is compatible, as a result of which such compositions do not have a tendency to separation or migration or evaporation of the catalyst.
Abstract:
Composition including at least one polymer containing silane groups and at least one zinc(II) complex compound of Znk(L)x(Y)2k-nx, where k is an integer from 1-10, x is 1, 2, 3, or 4, n corresponds to of ligand L, Y is ligand having −1 charge, and L is ligand of where n is 1, 2, or 3, A is R4 or polyoxyalkylene group or group of polyoxyalkylated compound optionally having one or two terminal 1,3-ketoamide groups, R1 and R2 are hydrogen residue or monovalent saturated or unsaturated hydrocarbon group having 1-10 carbon atoms independently of each other or jointly bivalent alkylene group having 3-6 carbon atoms; R3 and R4 are hydrogen residue or monovalent saturated hydrocarbon group having 1-12 carbon atoms independently of each other, hydrocarbon group optionally contains one or more heteroatoms, or jointly bivalent alkylene group having 3-6 carbon atoms, which alkylene group optionally contains one or more heteroatoms. The invention further relates to the use of the zinc(II) complex compound of the formula Znk(L)x(Y)2k-nx as a catalyst for the cross-linking of polymers containing silane groups by means of moisture.
Abstract:
The invention relates to metal complex compounds of the formula Mk(L)x(Y)kz-nx, where the ligand L has the formula (I), and to metal complex compounds which include the reaction product of at least one salt or a complex of a transition metal or a main group metal element of the groups 13 to 15 and at least one 1,3-ketoamide. Such complex compounds are suitable in particular as catalysts for polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such metal complex compound as the catalyst. The invention additionally relates to different uses of the two-component polyurethane compositions.