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    Crosslinkable polymers based on unsaturated esters of furoic acid and process for their preparation and application in the manufacture of coatings
    1.
    发明授权
    Crosslinkable polymers based on unsaturated esters of furoic acid and process for their preparation and application in the manufacture of coatings 失效
    基于糠酸不饱和酯的交联聚合物及其在制备涂料中的制备和应用

    公开(公告)号：US4663411A

    公开(公告)日：1987-05-05

    申请号：US820218

    申请日：1986-01-21

    Applicant: Roland Reeb ,  Bernard Chauvel

    Inventor： Roland Reeb ,  Bernard Chauvel

    IPC: C08F20/00 ,  C08F2/22 ,  C08F20/10 ,  C08F20/26 ,  C08F20/30 ,  C08F220/40 ,  C08G65/00

    CPC classification number: C08F20/30

    Abstract: Crosslinkable polymers having about 1 to 100% of units derived from an unsaturated ester of furoic acid of the formula: ##STR1## where R denotes hydrogen or an alkyl group, R' denotes a straight-chain or branched alkylene group and n denotes an integer from 1 to 4, and 0 to about 99% of units from an unsaturated monomer which is copolymerizable with the ester. The crosslinkable polymers may be in the form of latices. The crosslinkable polymers are prepared by polymerization of the unsaturated ester of furoic acid and, if appropriate, an unsaturated comonomer, in aqueous emulsion. The polymers and latices can be used in the manufacture of coatings.

    Abstract translation: 具有约1至100％衍生自下式的糠酸不饱和酯的单元的交联聚合物：其中R表示氢或烷基，R'表示直链或支链亚烷基，n表示整数 1至4，以及0至约99％的可与该酯共聚的不饱和单体的单元。 可交联聚合物可以是胶乳的形式。 可交联聚合物通过在水性乳液中聚合糠酸的不饱和酯和如果合适的不饱和共聚单体来制备。 聚合物和胶乳可用于制造涂料。

    Aqueous interpolymer emulsions, process for their preparation and use of the emulsions as binders for coating paper
    2.
    发明授权
    Aqueous interpolymer emulsions, process for their preparation and use of the emulsions as binders for coating paper 失效
    水溶性互聚物乳液，其制备方法和使用乳液作为涂布纸的粘合剂

    公开(公告)号：US4448924A

    公开(公告)日：1984-05-15

    申请号：US476258

    申请日：1983-03-17

    Applicant: Roland Reeb ,  Bernard Chauvel

    Inventor： Roland Reeb ,  Bernard Chauvel

    IPC: C08F2/00 ,  C08F2/22 ,  C08F20/00 ,  C08F20/22 ,  C08F22/00 ,  C08F22/10 ,  C08F257/00 ,  C08F257/02 ,  C08F279/00 ,  C08F279/02 ,  D21H19/44 ,  D21H19/58 ,  D21H19/60 ,  C08L25/10

    CPC classification number: D21H19/60 ,  C08F257/02 ,  C08F279/02 ,  D21H19/58 ,  Y10T428/31895

    Abstract: Latex of an interpolymer composed of (1) a copolymer A of butadiene, styrene and at least one ethylenically unsaturated carboxylic acid, and (2) a polymer B of a halogenohydroxyalkyl ester of an ethylenically unsaturated monocarboxylic or dicarboxylic acid, polymer B being at least partially grafted onto the copolymer A. The latex is prepared by the emulsion polymerization of butadiene, styrene and at least one copolymerizable, ethylenically unsaturated carboxylic acid, followed by the polymerization, in the presence of the copolymer latex, of a halogenohydroxyalkyl ester of an ethylenically unsaturated monocarboxylic or dicarboxylic acid. The latex may be used as a binder in aqueous compositions for coating paper.

    Abstract translation: 由（1）丁二烯，苯乙烯和至少一种烯键式不饱和羧酸的共聚物A构成的互聚物的乳胶，和（2）烯属不饱和单羧酸或二羧酸的卤代羟烷基酯的聚合物B，聚合物B至少 部分接枝到共聚物A上。胶乳通过丁二烯，苯乙烯和至少一种可共聚的烯属不饱和羧酸的乳液聚合制备，然后在共聚物胶乳存在下聚合烯键式的卤代羟烷基酯 不饱和一元羧酸或二羧酸。 胶乳可用作涂布纸的水性组合物中的粘合剂。

    Interpolymer latex, process for its preparation and use of the latex for coating paper
    3.
    发明授权
    Interpolymer latex, process for its preparation and use of the latex for coating paper 失效
    共聚物胶乳，其制备和使用用于涂布纸的胶乳的方法

    公开(公告)号：US4448923A

    公开(公告)日：1984-05-15

    申请号：US476257

    申请日：1983-03-17

    Applicant: Roland Reeb ,  Bernard Chauvel

    Inventor： Roland Reeb ,  Bernard Chauvel

    IPC: C08L51/00 ,  C08F257/02 ,  C08F279/02 ,  C08L7/00 ,  C08L9/08 ,  C08L21/00 ,  C08L51/02 ,  C08L51/04 ,  D21H19/58 ,  C08L25/10

    CPC classification number: D21H19/58 ,  C08F257/02 ,  C08F279/02 ,  Y10T428/31895

    Abstract: Latex of an interpolymer composed of (1) a copolymer A of butadiene, styrene and at least one ethylenically unsaturated carboxylic acid, and (2) a polymer B of at least one halogenoalkyl or halogenoacetoxyalkyl ester of an ethylenically unsaturated monocarboxylic or dicarboxylic acid, polymer B being at least partially grafted onto the copolymer A.The latex is prepared by the emulsion polymerization of butadiene, styrene and at least one copolymerizable, ethylenically unsaturated carboxylic acid to form a copolymer latex, followed by the polymerization in the presence of the copolymer latex of a halogenoalkyl or halogenoacetoxyalkyl ester of an ethylenically unsaturated monocarboxylic or dicarboxylic acid.The latex may be used as a binder in aqueous compositions for coating paper.

    Abstract translation: 由（1）丁二烯，苯乙烯和至少一种烯键式不饱和羧酸的共聚物A组成的互聚物的乳胶，和（2）至少一种烯属不饱和一元羧酸或二羧酸的卤代烷基或卤代乙酰氧基烷基酯的聚合物B，聚合物 B至少部分接枝到共聚物A上。通过丁二烯，苯乙烯和至少一种可共聚的烯属不饱和羧酸的乳液聚合制备胶乳以形成共聚物胶乳，然后在共聚物胶乳存在下进行聚合 的烯属不饱和单羧酸或二羧酸的卤代烷基或卤代乙酰氧基烷基酯。 胶乳可用作涂布纸的水性组合物中的粘合剂。

    Polyoxyalkyleneamine-neutralized, low MFFT aqueous dispersions of ethylenic/carboxylic polymers
    7.
    发明授权
    Polyoxyalkyleneamine-neutralized, low MFFT aqueous dispersions of ethylenic/carboxylic polymers 失效
    乙烯/羧酸聚合物的聚氧亚烷基亚胺中和的低MFFT水分散体

    公开(公告)号：US5331042A

    公开(公告)日：1994-07-19

    申请号：US792676

    申请日：1991-11-15

    Applicant: Dominique Charmot ,  Roland Reeb

    Inventor： Dominique Charmot ,  Roland Reeb

    IPC: C08K5/17 ,  C08L33/06 ,  C08L71/02 ,  C08L31/00

    CPC classification number: C08K5/17 ,  C08L33/064 ,  C08L2201/50 ,  C08L71/02

    Abstract: Low MFFT aqueous polymer dispersions of film-forming, relatively low Tg ethylenic/carboxylic polymer particulates, e.g., styrene/alkyl acrylate/acrylic acid copolymer particles, are well adapted for the production of wear- and soil-resistant coatings and adhesives, and include an effective, at least partially "neutralizing" amount of a polyoxyalkyleneamine, e.g., a polyoxyalkyleneamine bearing at least one primary and/or secondary amine functional group.

    Abstract translation: 成膜薄膜，较低Tg的乙烯/羧酸聚合物颗粒（如苯乙烯/丙烯酸烷基酯/丙烯酸共聚物颗粒）的低MFFT聚合物水分散体很适合生产耐磨和防污涂料和粘合剂，包括 有效的，至少部分“中和”的聚氧亚烷基胺，例如具有至少一个伯和/或仲胺官能团的聚氧亚烷基胺。

    Composition, for use in coatings, based on a mixture of emulsion(s) and of dispersion(s) of polyolpolymer and coating(s) produced therefrom
    8.
    发明授权
    Composition, for use in coatings, based on a mixture of emulsion(s) and of dispersion(s) of polyolpolymer and coating(s) produced therefrom 有权
    用于涂料的组合物，基于乳液和多元醇聚合物的分散体和由其制备的涂料的混合物

    公开(公告)号：US07244782B2

    公开(公告)日：2007-07-17

    申请号：US11154250

    申请日：2005-06-16

    Applicant: Gilles Guerin ,  Bruno Langlois ,  Roland Reeb

    Inventor： Gilles Guerin ,  Bruno Langlois ,  Roland Reeb

    IPC: C08K3/20

    CPC classification number: C08G18/6216 ,  C08G18/0866 ,  C08G18/6229 ,  C08G18/706 ,  C08G18/794 ,  C08G18/8061 ,  C08G18/807 ,  C08G18/8077 ,  C09D175/04

    Abstract: The present invention relates to a composition comprising at least one masked or unmasked polyisocyanate in the form of an aqueous emulsion whose mean size is between 0.1 and 10 micrometers; and at least one polyhydroxylated polymer, advantageously a polyol, in the form of a second aqueous dispersion whose mean size is between 10 and 200 nanometers wherein the content of polyhydroxylated polymer, advantageously of polyol, expressed in mass percent, is at least equal to ⅚R−20, with R equal to the ratio of the mean size (d50) of the emulsion to that of the dispersion of polyhydroxylated polymer, advantageously of polyol.

    Abstract translation: 本发明涉及一种组合物，其包含至少一种平均尺寸为0.1至10微米的水性乳液形式的掩蔽或未掩蔽的多异氰酸酯; 和至少一种多羟基化聚合物，有利地为多元醇，其形式为第二水分散体，其平均尺寸为10-200纳米，其中多羟基化聚合物（有利地多元醇）以质量百分比表示的含量至少等于5 / 6R-20，其中R等于乳液的平均尺寸（d <50％）与多羟基化聚合物的分散体的比例，有利地为多元醇。

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