Abstract:
A polyurethane crosslinker is provided by reacting a partially-blocked diisocyanate and a hydroxyl-terminated, carboxyl group-containing polyurethane precursor. The precursor is a reaction product of a diol containing a carboxyl group and another diol of high molecular weight, and a diisocyanate. The instant crosslinkers are particularly useful in water-based coating compositions for metal containers.
Abstract:
An aqueous resinous dispersion and a method of coating employing the aqueous resinous dispersion are disclosed. The aqueous resinous dispersions are solubilized with base and comprise an acrylic polymer containing N-ethoxymethylacrylamide or methacrylamide moieties and an epoxy resin. The dispersion is useful for coating metal containers particularly as a coating for the interior of containers which are used for alcoholic beverages, for example, beer cans.
Abstract:
An aqueous resinous dispersion and a method of coating employing the aqueous resinous dispersion are disclosed. The aqueous resinous dispersions are solubilized with base and comprise an acrylic polymer containing N-ethoxymethylacrylamide or methacrylamide moieties and an epoxy resin. The dispersion is useful for coating metal containers particularly as a coating for the interior of containers which are used for alcoholic beverages, for example, beer cans.
Abstract:
Aqueous coating compositions which may be applied by conventional coating techniques as well as by electrodeposition are provided by reacting an epoxy-containing organic material with a compound containing a mercaptan group and at least one group hydrolyzable to a carboxyl group. Examples of such hydrolyzable groups include ester groups, amide groups and nitrile groups. The resultant product is then hydrolyzed and solubilized using hydrolyzing agents such as aqueous alkali metal hydroxides and aqueous solutions of various amines.
Abstract:
Resinous compositions which are the Michael adducts of primary and/or secondary amines and polymers containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties are disclosed. The compositions are depositable on substrates to form films. The films are amenable to oxidative and aminoplast cures and cure with light color. The compositions are desirable for use in cationic electrodeposition.
Abstract:
Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acids, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.
Abstract:
Amine group-containing addition interpolymers having improved stability under conditions of storage and use are prepared by interpolymerizing at least one polymerizable ethylenically unsaturated carboxylic acid monomer and at least one polymerizable ethylenically unsaturated aminolysis-resistant organic monomer to form an addition interpolymer containing carboxyl groups pendent to the polymer chain and aminolysis-resistant organic groups pendent to the polymer chain, following which a portion of the pendent carboxyl groups of the addition interpolymer are reacted with an alkylenimine to form pendent amine groups and a portion of the pendent carboxyl groups of the addition interpolymer are neutralized with a basic compound to form pendent anionic salt groups. The addition interpolymer is preferably reducible with organic solvents, water or a mixture thereof, and can be utilized as pigment grinding vehicles or they can be formulated with conventional additives to form useful coating compositions. A preferred use for these interpolymers is in combination with a polyepoxide to provide two-package cocurable polymeric compositions for coatings and other uses.
Abstract:
Amine group-containing addition interpolymers having improved stability under conditions of storage and use are prepared by interpolymerizing at least one polymerizable ethylenically unsaturated carboxylic acid monomer and at least one polymerizable ethylenically unsaturated aminolysis-resistant organic monomer to form an addition interpolymer containing carboxyl groups pendent to the polymer chain and aminolysis-resistant organic groups pendent to the polymer chain, following which a portion of the pendent carboxyl groups of the addition interpolymer are reacted with an alkylenimine to form pendent amine groups and a portion of the pendent carboxyl groups of the addition interpolymer are neutralized with a basic compound to form pendent anionic salt groups.
Abstract:
A method of cleaning a membrane such as an ultrafilter which has been used in the treatment of a cataphoretic paint is disclosed. The method involves treating the membrane with an aqueous solution of an acid, a fatty amine and a water-soluble organic solvent.
Abstract:
A method of cationic electrodeposition, electrocoated articles and novel electrocoating compositions are disclosed. The compositions comprise a cationic resin containing blocked isocyanate functionality and are capable of being electrodeposited over rough steel and producing extremely smooth films upon curing.