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    1-[2-(4-Diphenyl)-1,3-dioxolan-2-yl-methyl]-1-H-triazoles
    1.
    发明授权
    1-[2-(4-Diphenyl)-1,3-dioxolan-2-yl-methyl]-1-H-triazoles 失效
    1- [2-（4-二苯基）-1,3-二氧戊环-2-基 - 甲基] -1H-三唑

    公开(公告)号：US4479004A

    公开(公告)日：1984-10-23

    申请号：US423391

    申请日：1982-09-24

    Applicant: Adolf Hubele ,  Peter Riebli

    Inventor： Adolf Hubele ,  Peter Riebli

    IPC: A01N43/50 ,  A01N43/653 ,  C07D405/06 ,  C07D521/00 ,  A01N43/64

    CPC classification number: C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08 ,  C07D405/06 ,  Y10S514/937

    Abstract: A description is given of new compounds of the formula defined herein: ##STR1## which display valuable microbicidal properties. The compounds can be used for combatting microorganisms harmful to plants, especially phytopathogenic fungi. The compounds of formula I thus possess a curative, systemic, and preventive action very useful for practical requirements for the protection of cultivated plants, without causing these to suffer any undesirable side effects. In practice, the compounds can be used by themselves or in the form of pesticides.

    Abstract translation: 给出了本文定义的新化合物的描述：显示有价值的杀菌性质的图像（I）。 该化合物可用于对有害于植物，特别是植物病原真菌的微生物进行防治。 因此，式I化合物具有对保护栽培植物的实际需要非常有用的治疗性，系统性和预防性作用，而不会使它们遭受任何不期望的副作用。 实际上，这些化合物可以自己或以农药的形式使用。

    1-phenoxyphenyl-1-triazolylmethyl-carbinol compound as microbicides
    2.
    发明授权
    1-phenoxyphenyl-1-triazolylmethyl-carbinol compound as microbicides 失效
    1-苯氧基苯基-1-三唑基甲基 - 甲醇化合物作为杀微生物剂

    公开(公告)号：US4992458A

    公开(公告)日：1991-02-12

    申请号：US376185

    申请日：1989-07-06

    Applicant: Peter Riebli ,  Adolf Hubele

    Inventor： Peter Riebli ,  Adolf Hubele

    IPC: A01N43/653 ,  C07D249/08 ,  C07D521/00

    CPC classification number: C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

    Abstract: Novel 1-phenoxyphenyl-1-triazolylmethyl-carbinols of formula I ##STR1## in which R.sub.1 is fluorine, chlorine or bromine and R.sub.2 is fluorine, chlorine, bromine or methyl,and the phytophysiologically tolerable acid addition salts thereof have excellent microbicidal, in particular phytofungicidal, properties. They can be used for controlling and/or preventing infections caused by microorganisms in useful plants. The preparation of these compounds and compositions containing them is described.

    Abstract translation: 式I的1-苯氧基苯基-1-三唑基甲基 - 甲醇其中R1是氟，氯或溴，R2是氟，氯，溴或甲基，其植物生理学上可耐受的酸加成盐具有优异的杀微生物剂 ，特别是植物杀灭剂的性质。 它们可用于控制和/或预防有用植物中的微生物引起的感染。 描述了这些化合物和含有它们的组合物的制备。

    Organotin compounds and pesticidal compositions
    3.
    发明授权
    Organotin compounds and pesticidal compositions 失效
    有机锡化合物和杀虫剂组合物

    公开(公告)号：US4546109A

    公开(公告)日：1985-10-08

    申请号：US504021

    申请日：1983-06-13

    Applicant: Adolf Hubele ,  Peter Riebli

    Inventor： Adolf Hubele ,  Peter Riebli

    IPC: A01N55/04 ,  C07F7/22 ,  A61K31/32

    CPC classification number: A01N55/04 ,  C07F7/2244

    Abstract: There are described novel organotin compounds of the formula I ##STR1## wherein R.sub.1 is unsubstituted or substituted lower alkyl, lower alkenyl, cycloalkyl, furyl or tetrahydrofuryl;R.sub.2 is unsubstituted or substituted aryl;R.sub.3 and R.sub.4 independently of one another are each hydrogen, or unsubstituted or substituted lower alkyl; andR.sub.5, R.sub.6 and R.sub.7 independently of one another are each unsubstituted or substituted lower alkyl, cycloalkyl or aryl.There are also disclosed methods of producing these products, and also pesticidal compositions containing one of the said compounds as active ingredient. Also described is a method for controlling plant pests, which method is based on the application of the stated active substances or of compositions prepared therefrom.

    Abstract translation: 描述了式I的新型有机锡化合物（I）其中R 1是未取代的或取代的低级烷基，低级烯基，环烷基，呋喃基或四氢呋喃基; R2是未取代或取代的芳基; R 3和R 4彼此独立地为氢，或未取代或取代的低级烷基; R 5，R 6和R 7彼此独立地是各自未取代或取代的低级烷基，环烷基或芳基。 还公开了生产这些产品的方法，以及含有所述化合物之一作为活性成分的杀虫组合物。 还描述了一种用于控制植物害虫的方法，该方法基于所述活性物质或由其制备的组合物的应用。

    Sulfinyl- and sulfonylacetanilides and their use as microbicides
    5.
    发明授权
    Sulfinyl- and sulfonylacetanilides and their use as microbicides 失效
    亚磺酰基和磺酰乙酰苯胺及其作为杀微生物剂的用途

    公开(公告)号：US4428964A

    公开(公告)日：1984-01-31

    申请号：US182197

    申请日：1980-08-28

    Applicant: Adolf Hubele ,  Peter Riebli ,  Wolfgang Eckhardt ,  Walter Kunz

    Inventor： Adolf Hubele ,  Peter Riebli ,  Wolfgang Eckhardt ,  Walter Kunz

    IPC: A01N37/46 ,  A01N41/10 ,  C07C67/00 ,  C07C313/00 ,  C07C317/44 ,  C07C147/13 ,  C07C147/14

    CPC classification number: A01N41/10

    Abstract: There are described novel compounds of the formula I defined herein: ##STR1## which have valuable microbicidal properties. The novel compounds can be used for combating microorganisms harmful to plants, particularly for combating phytopathogenic fungi. The compounds of the formula I thus have a very favorable curative and preventive action for practical requirements for the protection of cultivated plants, without the plants being impaired as a result of undesirable secondary effects. The compounds can be used in practice on their own or in the form of pesticidal compositions.

    Abstract translation: 描述了本文定义的式I的新颖化合物：其具有有价值的杀微生物性质。 新型化合物可用于对抗对植物有害的微生物，特别是用于防治植物病原真菌。 因此，式I化合物对于保护栽培植物的实际需要具有非常有利的治疗和预防作用，而不会由于不期望的二次效应而损害植物。 这些化合物可以在实践中以其本身或以杀虫组合物的形式使用。

    Pesticidal compositions
    6.
    发明授权
    Pesticidal compositions 失效
    杀虫剂组合物

    公开(公告)号：US4694009A

    公开(公告)日：1987-09-15

    申请号：US746432

    申请日：1985-06-19

    Applicant: Adolf Hubele ,  Helmut Zondler ,  Peter Riebli ,  Wolfgang Eckhardt

    Inventor： Adolf Hubele ,  Helmut Zondler ,  Peter Riebli ,  Wolfgang Eckhardt

    IPC: A01N43/54 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  A61K31/505

    CPC classification number: C07D239/42 ,  A01N43/54 ,  C07D239/47

    Abstract: The invention discloses novel N-(2-nitrophenyl)-2-aminopyrimidine derivatives of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen, NO.sub.2 or CF.sub.3, with the proviso that only R.sub.1 or R.sub.2 can be NO.sub.2 ;R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio;R.sub.5, R.sub.6 and R.sub.7 are each independently halogen, nitro, cyano, thiocyano, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.8 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 haloalkenyloxy, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 haloalkynyloxy, C.sub.1 -C.sub.8 alkyl which is substituted by halogen, cyano and/or C.sub.1 -C.sub.4 alkoxy, or are unsubstituted C.sub.1 -C.sub.8 alkoxy or halogen-substituted C.sub.1 -C.sub.8 alkoxy, the alkyl moiety of which may be interrupted by one or more single oxygen atoms, or are the Q--(E).sub.n --(X).sub.m group, in which n is 0 or 1, m is 0 or 1, Q is phenyl which is unsubstituted or substituted by halogen, nitro, C.sub.1 -C.sub.3 alkyl, CF.sub.3 and/or C.sub.1 -C.sub.3 alkoxy, or is a saturated or unsaturated heterocyclic radical containing one or more hetero atoms, E is a C.sub.1 -C.sub.3 alkylene bridge, and X is oxygen or sulfur, and R.sub.6 and/or one of the radicals R.sub.5 or R.sub.7 can also be hydrogen.Also disclosed are methods of preparing these compounds, and agrochemical compositions which contain one such compound as active ingredient. The invention further relates to the use of the novel compounds, or compositions containing them, in agriculture and related fields.

    Abstract translation: 本发明公开了通式I（I）的新型N-（2-硝基苯基）-2-氨基嘧啶衍生物，其中R 1和R 2是氢，NO 2或CF 3，条件是只有R 1或R 2可以是NO 2; R 4是氢或-C（O）R'基团，其中R'是未被取代或被卤素，C 1 -C 3烷氧基或C 1 -C 3烷硫基取代的C 1 -C 4烷基; R5，R6和R7各自独立地为卤素，硝基，氰基，氰基，C1-C12烷基，C3-C8环烷基，C1-C8烷硫基，C1-C6烷基磺酰基，C1-C6烷基亚磺酰基，C3-C6链烯基，C3-C6卤代烯基，C3-C6炔基， C 6卤代炔基，C 3 -C 6烯氧基，C 3 -C 6卤代烯氧基，C 3 -C 6烯基硫基，C 3 -C 6炔氧基，C 3 -C 6卤代炔氧基，被卤素，氰基和/或C 1 -C 4烷氧基取代的C 1 -C 8烷基，或未取代的C 1 -C 8烷氧基或卤素取代的C 1 C 1-8烷氧基，其烷基部分可被一个或多个单个氧原子间隔，或是Q-（E）n-（X）m基团，其中n为0或1，m为0或1，Q 是未取代的或被卤素，硝基，C 1 -C 3烷基，CF 3和/或C 1 -C 3烷氧基取代的苯基，或是含有一个或多个杂原子的饱和或不饱和杂环基，E是C 1 -C 3亚烷基桥，X是 氧或硫，R6和/或基团R5或R7之一也可以是氢。 还公开了制备这些化合物的方法和含有一种这样的化合物作为活性成分的农药组合物。 本发明还涉及在农业和相关领域中使用含有它们的新化合物或组合物。

    Homoserine derivatives and their use as microbicides
    7.
    发明授权
    Homoserine derivatives and their use as microbicides 失效
    高丝氨酸衍生物及其作为杀微生物剂的用途

    公开(公告)号：US4442117A

    公开(公告)日：1984-04-10

    申请号：US199903

    申请日：1980-10-23

    Applicant: Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele ,  Peter Riebli

    Inventor： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele ,  Peter Riebli

    IPC: C07C231/12 ,  A01N37/46 ,  A01N41/04 ,  A01N43/08 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N47/12 ,  A01N47/16 ,  A01N47/20 ,  A01N53/00 ,  C07C233/54 ,  C07D307/24 ,  C07D521/00 ,  A01N37/22 ,  C07C103/66 ,  C07C103/737

    CPC classification number: C07D231/12 ,  A01N37/46 ,  A01N41/04 ,  A01N43/08 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N47/12 ,  A01N47/16 ,  A01N47/20 ,  A01N53/00 ,  C07D233/56 ,  C07D249/08 ,  C07D307/24

    Abstract: There are described novel homoserine derivatives of the formula (I) ##STR1## which possess valuable microbicidal properties. In the formula: Ar is substituted phenyl or naphthyl; R.sub.1 is C.sub.2 -C.sub.6 alkyl optionally interrupted by oxygen or sulfur, 2-furyl, 2-tetrahydrofuryl, 1H-1,2,4-triazolylmethyl, 1-imidazolylmethyl, 1-pyrazolylmethyl, C.sub.2 -C.sub.4 alkenyl or cyclopropyl, each of which is optionally substituted by halogen; R.sub.2 is hydrogen or methyl; R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl; and B is halogen or an ester, thioester, sulfonic acid ester or sulfonic acid amide group. Additionally, where B is halogen, R.sub.1 may be halomethyl. The novel derivatives can be used for combating microorganisms harmful to plants, particularly for combating phytopathogenic fungi, and they have for practical requirements a very favorable curative and protective action for protecting cultivating plants, without the plants being impaired as a result of undesirable secondary effects. A notable feature is their stability to heat and to solar irradiation. They can be used in practice on their own or in the form of pesticidal compositions.

    Abstract translation: 描述了具有有价值的杀微生物性质的式（I）的新颖高丝氨酸衍生物。 式中Ar是取代的苯基或萘基; R1是任选被氧或硫中断的C 2 -C 6烷基，2-呋喃基，2-四氢呋喃基，1H-1,2,4-三唑基甲基，1-咪唑基甲基，1-吡唑基甲基，C 2 -C 4烯基或环丙基， 任选被卤素取代; R2是氢或甲基; R3是氢或C1-C4烷基; 和B是卤素或酯，硫酯，磺酸酯或磺酸酰胺基。 另外，当B是卤素时，R 1可以是卤代甲基。 新型衍生物可用于对抗对植物有害的微生物，特别是用于防治植物病原性真菌，并且它们具有非常有利的治疗和保护作用，用于保护栽培植物，而不会由于不期望的二次作用而损害植物。 它的一个显着特点是它们对热和太阳辐射的稳定性。 它们可以自己使用或以农药组合物的形式使用。

    Arylphenyl ether derivatives, compositions containing these compounds and use thereof
    8.
    发明授权
    Arylphenyl ether derivatives, compositions containing these compounds and use thereof 失效
    芳基苯基醚衍生物，含有这些化合物的组合物及其用途

    公开(公告)号：US5266585A

    公开(公告)日：1993-11-30

    申请号：US540261

    申请日：1983-10-11

    Applicant: Adolf Hubele ,  Peter Riebli

    Inventor： Adolf Hubele ,  Peter Riebli

    IPC: A01N43/50 ,  A01N43/653 ,  C07C45/63 ,  C07D317/16 ,  C07D317/22 ,  C07D319/06 ,  C07D521/00 ,  A01N43/54 ,  A61K31/41 ,  A61K31/415

    CPC classification number: C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07C45/63 ,  C07D233/56 ,  C07D249/08 ,  C07D317/16 ,  C07D317/22 ,  C07D319/06

    Abstract: Arylphenyl ether derivatives of the formula ##STR1## wherein Az is 1H-(1,2,4-triazolyl) or is 1-imidazolyl optionally substituted by alkyl,each of R.sub.a and R.sub.b is hydrogen, halogen, alkyl, alkoxy or nitro,Ar is phenyl or naphthyl, optionally substituted by halogen, alkyl, alkoxy, nitro or CF.sub.3,each of U and V, is alkyl optionally substituted by halogen or alkoxy, or together form an alkylene bridge ##STR2## wherein each of R.sub.1 and R.sub.2 is hydrogen, or alkyl optionally substituted by halogen; phenyl optionally substituted by halogen or alkyl; or --CH.sub.2 --Z--R.sub.7 in which Z is oxygen or sulfur, and R.sub.7 is hydrogen, alkyl optionally substituted by alkoxy, alkenyl, prop-2-ynyl, 3-halo-prop-2-ynyl, phenyl optionally substituted by halogen, alkyl, alkoxy, nitro or by CF.sub.3, benzyl optionally substituted by halogen, alkyl or by alkoxy,each of R.sub.3, R.sub.4 and R.sub.5 is hydrogen or alkyl, the total number of carbon atoms in R.sub.3, R.sub.4 and R.sub.5 not exceeding 6, andR.sub.6 is hydrogen or alkyl,together with the acid addition salts and metal complexes thereof. They may be used in agriculture for controlling phytopathogenic microorganisms and as antimycotic and/or anticonvulsive and anxiolytic agents in the pharmaceutical field.

    Abstract translation: 其中Az是1H-（1,2,4-三唑基）或任选被烷基取代的1-咪唑基，其中R a和R b各自是氢，卤素，烷基，烷氧基或硝基，Ar 任选被卤素，烷基，烷氧基，硝基或CF 3取代的苯基或萘基，U和V各自为任选被卤素或烷氧基取代的烷基，或一起形成亚烷基桥基，其中R1和 R2是氢或任选被卤素取代的烷基; 任选被卤素或烷基取代的苯基; 或-CH2-Z-R7，其中Z是氧或硫，R7是氢，任选被烷氧基，烯基，丙-2-炔基，3-卤代 - 丙-2-炔基取代的烷基，任选被卤素取代的苯基， 烷基或烷氧基，R3，R4和R5各自为氢或烷基，R3，R4和R5中碳原子总数不超过6，R6为 是氢或烷基，以及其酸加成盐和金属络合物。 它们可以用于农业中以控制植物病原微生物和作为抗真菌和/或抗惊厥和抗焦虑剂在制药领域。

    N-(2-nitrophenyl)-2-aminopyrimidine derivatives, the preparation and use thereof
    9.
    发明授权
    N-(2-nitrophenyl)-2-aminopyrimidine derivatives, the preparation and use thereof 失效
    N-（2-硝基苯基）-2-氨基嘧啶衍生物，的制备及应用

    公开(公告)号：US4659363A

    公开(公告)日：1987-04-21

    申请号：US632161

    申请日：1984-07-18

    Applicant: Adolf Hubele ,  Helmut Zondler ,  Peter Riebli ,  Wolfgang Eckhardt

    Inventor： Adolf Hubele ,  Helmut Zondler ,  Peter Riebli ,  Wolfgang Eckhardt

    IPC: A01N43/54 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  C07D239/56 ,  C07D401/12

    CPC classification number: C07D239/42 ,  A01N43/54 ,  C07D239/47 ,  C07D239/52 ,  C07D239/56 ,  C07D401/12

    Abstract: The invention discloses novel N-(2-nitrophenyl)-2-aminopyrimidine derivatives of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently NO.sub.2 or CF.sub.3, with the proviso that only R.sub.1 or R.sub.2 can be NO.sub.2R.sub.3 is halogen,R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio,R.sub.5, R.sub.6 and R.sub.7 are each independently hydrogen, halogen, nitro, cyano, thiocyano, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.8 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 -haloalkenyloxy, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 haloalkynyloxy, C.sub.1 -C.sub.8 alkyl which is substituted by halogen, cyano and/or C.sub.1 -C.sub.4 alkoxy, unsubstituted C.sub.1 -C.sub.8 alkoxy or halogen-substituted C.sub.1 -C.sub.8 alkoxy, the alkyl moiety of which may be interrupted by one or more single oxygen atoms; or are the Q--(E).sub.n --(X).sub.m -group, in which n is 0 or 1, m is 0 or 1, Q is phenyl which is unsubstituted or substituted by halogen, nitro, C.sub.1 -C.sub.3 alkyl, CF.sub.3 and/or C.sub.1 -C.sub.3 alkoxy, or is a saturated or unsaturated heterocyclic radical containing one or more hetero atoms, E is a C.sub.1 -C.sub.3 alkylene bridge, and X is oxygen or sulfur.Also disclosed are methods of preparing these compounds, and also agrochemical compositions which contain one such compound as active ingredient. The invention further relates to the use of the novel compounds, or, compositions containing them, in agriculture and related fields.

    Abstract translation: 本发明公开了通式I（I）的新型N-（2-硝基苯基）-2-氨基嘧啶衍生物，其中R 1和R 2各自独立地为NO 2或CF 3，条件是仅R 1或R 2可为NO 2 R 3 C 1 -C 3烷氧基或C 1 -C 3烷硫基，R 5，R 6和R 7各自独立地为氢，R 4为氢或-C（O）R'基团，其中R'为未被取代或被卤素取代的C 1 -C 4烷基， 卤素，硝基，氰基，硫氰基，C 1 -C 12烷基，C 3 -C 8环烷基，C 1 -C 8烷硫基，C 1 -C 6烷基磺酰基，C 1 -C 6烷基亚磺酰基，C 3 -C 6烯基，C 3 -C 6卤代烯基，C 3 -C 6炔基，C 3 -C 6卤代炔基，C 3 -C 6烯氧基， C 6-卤代链烯氧基，C 3 -C 6烯基硫基，C 3 -C 6炔氧基，C 3 -C 6卤代炔氧基，被卤素，氰基和/或C 1 -C 4烷氧基取代的C 1 -C 8烷基，未取代的C 1 -C 8烷氧基或卤素取代的C 1 -C 8烷氧基， 其可被一个或多个单个氧原子中断; 或者是Q-（E）n-（X）m-基，其中n为0或1，m为0或1，Q为未被取代或被卤素，硝基，C 1 -C 3烷基，CF 3和 或C1-C3烷氧基，或是含有一个或多个杂原子的饱和或不饱和杂环基，E是C1-C3亚烷基桥，X是氧或硫。 还公开了制备这些化合物的方法，以及含有一种这样的化合物作为活性成分的农药组合物。 本发明还涉及在农业和相关领域中新颖化合物或含有它们的组合物的用途。

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