公开(公告)号：US08404357B2

公开(公告)日：2013-03-26

申请号：US12733272

申请日：2008-08-21

申请人： Nobuo Kadowaki ,  Toshio Senda

发明人： Nobuo Kadowaki ,  Toshio Senda

IPC分类号： B32B15/04 ,  B32B15/18 ,  B32B18/00

CPC分类号： B32B15/01 ,  C23C2/02 ,  C23C2/08 ,  C23C2/26 ,  C23C2/28 ,  C23C2/40 ,  C23C28/00 ,  C23C28/321 ,  C23C28/322 ,  C23C28/34 ,  C23C28/345 ,  C23C28/3455 ,  C25D5/34 ,  C25D5/48 ,  Y10T428/12618 ,  Y10T428/12722 ,  Y10T428/12806 ,  Y10T428/12972

摘要： Laminated steel sheet for a container material with a small environmental load container material and coating pre-coated steel sheet for a container material characterized by comprising steel sheet having on it a tin layer or iron-tin alloy layer which has on it a tin oxide layer of a thickness measured by an electric stripping method of 0 mC/cm2 to 3.5 mC/cm2 and has further formed on that a foundation layer including a zirconium compound not including fluorine or nitrate nitrogen, having an amount of coating converted to zirconium of 1 mg/m2 to 30 mg/m2, and having an amount of sulfuric acid radicals (SO42−) of 0 mg/m2 to 7 mg/m2.

摘要翻译： 用于具有小环境负荷容器材料的容器材料和用于容器材料的涂层预涂钢板的层压钢板，其特征在于包括具有锡层或铁 - 锡合金层的钢板，所述锡层或铁 - 锡合金层上具有氧化锡层 通过电剥离法测量的厚度为0mC / cm 3至3.5mC / cm 2的厚度，并且还形成有包含不含氟或硝酸盐氮的锆化合物的基础层，其中转化为锆的涂层量为1mg / m 2至30mg / m 2，并且具有0mg / m 2至7mg / m 2的硫酸根（SO 4 2-）的量。

公开(公告)号：US07312276B2

公开(公告)日：2007-12-25

申请号：US10827515

申请日：2004-04-19

申请人： Hiroshi Ohishi ,  Masahiro Kumagai ,  Nobuo Kadowaki ,  Keiko Kawakami

发明人： Hiroshi Ohishi ,  Masahiro Kumagai ,  Nobuo Kadowaki ,  Keiko Kawakami

IPC分类号： C08L51/00 ,  C09D133/06

CPC分类号： B32B15/08 ,  B32B7/12 ,  B32B15/082 ,  B32B15/09 ,  B32B27/36 ,  B32B2367/00 ,  B32B2439/00 ,  C08L23/08 ,  C08L33/06 ,  C08L51/06 ,  C09D167/02 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/254 ,  Y10T428/26 ,  C08L51/00 ,  C08L2666/02 ,  C08L2666/06

摘要： A resin composition for coating a metal sheet comprising a polyester resin (A) having an intrinsic viscosity of 0.5-2.0 dl/g, an elastomer resin (B) and a vinyl polymer (C) containing at least 1 wt % of a unit with a polar group, and having a structure wherein the elastomer resin (B) is finely dispersed in the polyester resin (A) and at least a portion of the elastomer resin (B) is capsulated by the vinyl polymer (C). Also, metal-sheet-coating resin films using the resin composition, resin-coated metal sheets coated with the resin film, and resin-coated metal containers made by molding the resin-coated metal sheets are disclosed.

摘要翻译： 一种用于涂覆金属片的树脂组合物，其包含特性粘度为0.5-2.0dl / g的聚酯树脂（A），弹性体树脂（B）和乙烯基聚合物（C），其含有至少1重量％的单元与 极性基团，并且具有将弹性体树脂（B）细分散在聚酯树脂（A）中的结构，弹性体树脂（B）的至少一部分被乙烯基聚合物（C）包封的结构。 另外，公开了使用该树脂组合物的金属薄片状树脂薄膜，涂布有树脂薄膜的树脂涂布金属薄片和通过模制树脂涂覆的金属薄片制成的树脂涂覆的金属容器。

公开(公告)号：US20130029176A1

公开(公告)日：2013-01-31

申请号：US13639322

申请日：2011-04-06

申请人： Nobuo Kadowaki ,  Hironori Nakayama ,  Yuji Abe

发明人： Nobuo Kadowaki ,  Hironori Nakayama ,  Yuji Abe

IPC分类号： B32B15/04 ,  C25D5/36

CPC分类号： C25D9/08 ,  C25D3/54 ,  C25D5/36 ,  C25F1/02 ,  Y10T428/12611

摘要： Disclosed is a method for the cathodic electrocoating of a tin-coated steel sheet in a treatment solution that does not contain any Cr compound, F or nitrite nitrogen. In the method, a tin oxide layer that is not subjected to a cathodic electrocoating treatment yet and is arranged on a tin-coated steel sheet is thinned to a specified thickness or less by a cathodic electrocoating treatment in an aqueous solution containing sodium carbonate or sodium hydrogen carbonate or a aqueous sulfuric acid solution immersion treatment, and the tin oxide layer is subjected to a cathodic electrocoating treatment in an aqueous solution of an alkaline metal sulfate containing a zirconium compound having a specified composition. In this manner, a coating film is formed on the tin oxide layer at a specific adhered amount in terms of Zr content. Also disclosed are: a process for producing a chromium-free steel sheet for a container material, which has excellent adhesion to an organic resin film and excellent iron elution resistance after dent impact; and a steel sheet for a container material, which is produced by the process.

摘要翻译： 公开了一种镀锡钢板在不含任何Cr化合物，F或亚硝酸盐氮的处理溶液中进行阴极电泳的方法。 在该方法中，通过在含有碳酸钠或钠的水溶液中进行阴极电泳处理，将未经阴极电涂覆处理的锡氧化物层设置在镀锡钢板上，变薄至规定厚度以下 碳酸氢钠或硫酸水溶液浸渍处理，并且将氧化锡层在含有具有指定组成的锆化合物的碱金属硫酸盐的水溶液中进行阴极电泳处理。 以这种方式，在氧化锡层上以特定的附着量以Zr含量形成涂膜。 还公开了一种用于生产用于容器材料的无铬钢板的方法，其对有机树脂膜具有优异的粘合性，并且在凹陷冲击之后具有优异的耐铁洗脱性; 以及通过该方法制造的用于容器材料的钢板。

公开(公告)号：US5288813A

公开(公告)日：1994-02-22

申请号：US748550

申请日：1991-08-22

申请人： Hiroshi Hirakouchi ,  Masanori Nakamura ,  Takeshi Yatsuka ,  Nobuo Kadowaki ,  Hiroshi Endoh ,  Yoshimasa Zama

发明人： Hiroshi Hirakouchi ,  Masanori Nakamura ,  Takeshi Yatsuka ,  Nobuo Kadowaki ,  Hiroshi Endoh ,  Yoshimasa Zama

IPC分类号： B32B15/09 ,  C08G59/00 ,  C08G59/42 ,  C08G59/62 ,  C08G63/66 ,  C08G63/668 ,  C08G63/90 ,  C08K5/09 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C09D167/00 ,  F16F9/00 ,  F16F15/02 ,  C08F20/00

CPC分类号： F16F9/006 ,  C08G59/62 ,  C08G63/668 ,  C08L63/00 ,  C09D167/00

摘要： There is disclosed a viscoelastic resin composition for vibration damping material containing as essential components a polyester resin having a molecular weight of 5,000 to 50,000 and an acid value of 50 to 500 equivalents/10.sup.6 g, at least 80 mol % of the polycarboxylic acid component of which is an aromatic dicarboxylic acid and, at least 30 mol % of the polyol component of which is a compound of the formula (I):H--(OR.sub.2).sub.n --O--A--R.sub.1 --A--O--(R.sub.2 O).sub.n --H(I)wherein R.sub.1 is oxygen or a straight or branched chain C.sub.1-6 alkylene group; R.sub.2 is a straight or branched C.sub.1-6 alkylene group; A is a group of the formula: ##STR1## (wherein R.sub.3 is hydrogen or a C.sub.1-6 alkyl group); and n is an integer of 1 to 6, an acid anhydride compound having at least two acid anhydride groups in a molecule, and an epoxy compound having at least two epoxy groups in a molecule.

摘要翻译： 公开了一种用于减振材料的粘弹性树脂组合物，其包含分子量为5,000至50,000，酸值为50至500当量/ 106g，至少80mol％的多元羧酸组分的聚酯树脂作为必要组分 其为芳族二羧酸，并且其多元醇成分的至少30摩尔％为式（I）的化合物：其中R1为（OR2）nOA-R1-AO-（R2O）nH 氧或直链或支链C 1-6亚烷基; R2是直链或支链C 1-6亚烷基; A是下式的基团：（*化学结构*）（其中R 3是氢或C 1-6烷基）; n为1〜6的整数，分子内具有至少2个酸酐基的酸酐化合物和分子中具有至少2个环氧基的环氧化合物。

公开(公告)号：US4859523A

公开(公告)日：1989-08-22

申请号：US85718

申请日：1987-08-17

申请人： Hiroshi Endoh ,  Yoshimasa Zama ,  Nobuo Kadowaki ,  Takeshi Yatuka ,  Hiroshi Nagai ,  Yutaka Mizumura

发明人： Hiroshi Endoh ,  Yoshimasa Zama ,  Nobuo Kadowaki ,  Takeshi Yatuka ,  Hiroshi Nagai ,  Yutaka Mizumura

IPC分类号： F16F15/02 ,  B32B15/08 ,  C08G18/42 ,  C08G18/66 ,  C09J175/06 ,  F16F9/30

CPC分类号： F16F9/306 ,  B32B15/08 ,  C08G18/4202 ,  C08G18/6637 ,  C09J175/06 ,  C08G2350/00 ,  Y10T428/24967 ,  Y10T428/31605 ,  Y10T428/31678 ,  Y10T428/31786

摘要： A viscoelastic resin which comprises a reaction product of:(A) a polyester diol having a molecular weight of 400 to 6,000, at least 60 mol % of the dicarboxylic acid component of which is an aromatic dicarboxylic acid and at least 30 mol % of the glycol component of which is neopentyl glycol or its derivative;(B) an aliphatic polyester diol having a molecular weight of 600 to 6,000;(C) a diisocyanate compound; and(D) a chain extender;said (A), (B), (C) and (D) being reacted in a weight ratio (A):(B):(C) of 100:0 to 150:10 to 100:0 to 30.

摘要翻译： 一种粘弹性树脂，其包含以下反应产物：（A）分子量为400至6,000的聚酯二醇，至少60摩尔％的二羧酸组分为芳族二羧酸和至少30摩尔％的 二元醇组分是新戊二醇或其衍生物; （B）分子量为600〜6000的脂肪族聚酯二醇; （C）二异氰酸酯化合物; 和（D）扩链剂; 所述（A），（B），（C）和（D）以100:0至150:10至100:0至30的重量比（A）：（B）：（C）反应。

公开(公告)号：US09121105B2

公开(公告)日：2015-09-01

申请号：US13639322

申请日：2011-04-06

申请人： Nobuo Kadowaki ,  Hironori Nakayama ,  Yuji Abe

发明人： Nobuo Kadowaki ,  Hironori Nakayama ,  Yuji Abe

IPC分类号： C25D5/36 ,  C25D5/34 ,  C25D9/08 ,  C25D3/54 ,  C25F1/02

CPC分类号： C25D9/08 ,  C25D3/54 ,  C25D5/36 ,  C25F1/02 ,  Y10T428/12611

摘要： A method for the cathodic electrocoating of a tin-coated steel sheet in a treatment solution that does not contain any Cr compound, F or nitrite nitrogen. A tin oxide layer that is not subjected to a cathodic electrocoating treatment yet and is arranged on a tin-coated steel sheet is thinned to a specified thickness or less by a cathodic electrocoating treatment in an aqueous solution containing sodium carbonate or sodium hydrogen carbonate or an aqueous sulfuric acid solution immersion treatment, and the tin oxide layer is subjected to a cathodic electrocoating treatment in an aqueous solution of an alkaline metal sulfate containing a zirconium compound having a specified composition. In this manner, a coating film is formed on the tin oxide layer at a specific adhered amount in terms of Zr content.

摘要翻译： 在不含任何Cr化合物，F或亚硝酸盐氮的处理溶液中的镀锡钢板的阴极电涂覆方法。 未经阴极电涂覆处理而设置在镀锡钢板上的氧化锡层通过阴极电泳处理在含有碳酸钠或碳酸氢钠的水溶液中稀释至规定厚度以下 硫酸水溶液浸渍处理，氧化锡层在含有具有规定组成的锆化合物的碱金属硫酸盐水溶液中进行阴极电泳处理。 以这种方式，在氧化锡层上以特定的附着量以Zr含量形成涂膜。

公开(公告)号：US5411810A

公开(公告)日：1995-05-02

申请号：US84296

申请日：1993-06-28

申请人： Hiroshi Hirakouchi ,  Masanori Nakamura ,  Takeshi Yatsuka ,  Nobuo Kadowaki

发明人： Hiroshi Hirakouchi ,  Masanori Nakamura ,  Takeshi Yatsuka ,  Nobuo Kadowaki

IPC分类号： C08L63/00 ,  C08G59/00 ,  C08L67/00 ,  C08L67/02 ,  C08L71/08 ,  C08L71/10 ,  F16F15/02 ,  B32B15/06 ,  B32B27/06 ,  B32B27/36 ,  C08F22/10

CPC分类号： C08L67/02 ,  Y10T428/31681 ,  Y10T428/31786

摘要： The present invention relates to a viscoelastic resin composition for a vibration damping material and a vibration damping material using the same. The viscoelastic resin composition includes as its main components: Low Tg resin (A) with a glass transition temperature of -60.degree. C. to 0.degree. C. and a number average molecular weight of 5000 to 50000, the Low Tg resin (A) being a polyester containing an acid component having 50 to 90 mol % of aromatic dicarboxylic acid and 10 to 50 mol % of dimer acid, and a glycol component having at least 30 mol % of glycol with an alkyl group as its side chain and the glycol having at least four carbon atoms; and High Tg resin (B) which is at least one selected from the group consisting of amorphous polyester resins, phenoxy resins, and epoxy resins, the epoxy resins having a number average molecular weight of at least 1000, the respective resins having a glass transition temperature in the range of 0.degree. C. to 80.degree. C.; wherein the weight ratio between the Low Tg resin (A) and the High Tg resin (B) is in the range of 90:10 to 30:70. This viscoelastic resin composition is used for a resin layer of an attachable vibration damping material and a sandwich type vibration damping material.

摘要翻译： 本发明涉及一种用于减振材料的粘弹性树脂组合物和使用其的减震材料。 粘弹性树脂组合物的主要成分为：玻璃化转变温度为-60℃〜0℃，数均分子量为5000〜50000的低Tg树脂（A），低Tg树脂（A） 是含有具有50〜90摩尔％的芳族二羧酸和10〜50摩尔％的二聚酸的酸成分的聚酯，以及具有至少30摩尔％的具有烷基作为侧链的二醇的二醇成分和二醇 具有至少四个碳原子; 和选自无定形聚酯树脂，苯氧基树脂和环氧树脂中的至少一种的高Tg树脂（B），数均分子量为至少1000的环氧树脂，各树脂具有玻璃化转变 温度在0℃至80℃的范围内。 其中低Tg树脂（A）和高Tg树脂（B）之间的重量比在90:10至30:70的范围内。 该粘弹性树脂组合物用于可附接的减震材料和夹心型减震材料的树脂层。

公开(公告)号：US5183863A

公开(公告)日：1993-02-02

申请号：US890116

申请日：1992-05-29

申请人： Masanori Nakamura ,  Hiroshi Hirakouchi ,  Takeshi Yatsuka ,  Nobuo Kadowaki ,  Hiroshi Endoh

发明人： Masanori Nakamura ,  Hiroshi Hirakouchi ,  Takeshi Yatsuka ,  Nobuo Kadowaki ,  Hiroshi Endoh

IPC分类号： B32B15/08 ,  C08G18/42 ,  C08G59/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  F16F9/00 ,  F16F15/02

CPC分类号： F16F9/006 ,  C08G18/4202 ,  C08L63/00 ,  C08L67/02 ,  C08G2350/00

摘要： Disclosed herein is a viscoelastic resin composition for vibration-damping material which comprises (A) at least one amorphous polyester resin of low specific gravity in which more than 40 mol % of the dibasic acid moiety is of aromatic type, (B) at least one amorphous polyester resin of high specific gravity in which more than 80 mol % of the dibasic acid moiety is of aromatic type, and (C) at least one hardener selected from the group consisting of polyisocyanate compounds, epoxy group-containing compounds, and acid anhydrides, said consitutents (A) and (B) being in the ratio of from 90:10 to 30:70 by weight and differing from each other in specific gravity (at 30.degree. C.) by 0.06 to 0.15 and also in molecular weight by more than 10000, with that of either of them being higher than 5000. This resin composition gives a vibration-damping material which exhibits improved vibration-damping properties, adhesive strength, formability, and heat resistance after forming.

公开(公告)号：US4942219A

公开(公告)日：1990-07-17

申请号：US260303

申请日：1988-10-20

申请人： Takeshi Yatsuka ,  Seiji Yamazoe ,  Hiroshi Hirakouchi ,  Yutaka Mizumura ,  Hiroshi Endo ,  Nobuo Kadowaki

发明人： Takeshi Yatsuka ,  Seiji Yamazoe ,  Hiroshi Hirakouchi ,  Yutaka Mizumura ,  Hiroshi Endo ,  Nobuo Kadowaki

IPC分类号： F16F15/02 ,  B32B7/04 ,  B32B27/36 ,  C08G18/42 ,  C08G59/00 ,  C08G59/40 ,  C08G59/42 ,  C08G63/08 ,  C08G63/60 ,  C08L63/00 ,  C08L67/04 ,  F16F1/36

CPC分类号： F16F1/3605 ,  B32B7/04 ,  C08G18/4286 ,  C08G63/08 ,  C08G63/60 ,  C08L67/04 ,  C08G2350/00 ,  Y10S428/924 ,  Y10T428/31681

摘要： The use of an amorphous block copolyester resin as a viscoelastic resin for a composite vibration damping material, and a viscoelastic resin composition for a composite vibration damping material which comprises the amorphous block copolyester resin and at least one compound selected from the group consisting of polyepoxy compounds, polyisocyanate compounds and acid anhydrides.

摘要翻译： 使用无定形嵌段共聚酯树脂作为复合减振材料的粘弹性树脂，以及复合减震材料用粘弹性树脂组合物，其包含非晶嵌段共聚酯树脂和至少一种选自聚环氧化合物 ，多异氰酸酯化合物和酸酐。

公开(公告)号：US07921961B2

公开(公告)日：2011-04-12

申请号：US11720823

申请日：2005-11-29

申请人： Nobuo Kadowaki

发明人： Nobuo Kadowaki

IPC分类号： F16F15/02 ,  F16F7/00 ,  F16F15/00

CPC分类号： B32B15/08 ,  B32B15/18 ,  B32B15/20 ,  B32B27/36 ,  B32B2250/40 ,  B32B2307/51 ,  B32B2307/56 ,  B32B2307/702 ,  C09D5/082 ,  C23C28/00 ,  F16F9/306 ,  G10K11/162 ,  G10K11/168 ,  Y02P20/582

摘要： A chromate-free resin composite damping material is provided having a multilayer structure. The material can include an viscoelastic resin composition provided between two metal plates as an intermediate layer, where the viscoelastic resin composition can include a thermosetting resin further including an amorphous copolymerizable polyester resin and a curing agent. A surfaces of each metal plate contacting the resin composition can be provided with a chromate-free adhesion boundary film which includes between about 5 and 50 mass % of silica, between about 5 and 50 mass % of a polyester resin, between about 1 and 50 mass % of tannic acid, and between about 0 and 30 mass % of a silane coupling agent. Such damping material can provide excellent durable adhesion properties.

摘要翻译： 提供了一种具有多层结构的无铬酸盐树脂复合阻尼材料。 该材料可以包括在作为中间层的两个金属板之间提供的粘弹性树脂组合物，其中粘弹性树脂组合物可以包括还包含无定形共聚聚酯树脂和固化剂的热固性树脂。 与树脂组合物接触的每个金属板的表面可以具有不含铬酸盐的粘合边界膜，其包含约5至50质量％的二氧化硅，约5至50质量％的聚酯树脂，约1至50 单宁酸的质量％，硅烷偶联剂的约0〜30质量％。 这种阻尼材料可提供优异的耐久粘合性能。