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1.发明申请公开(公告)号：US20170130089A1
公开(公告)日：2017-05-11
申请号：US15413703
申请日：2017-01-24
申请人： MATERIA, INC.
IPC分类号： C09D143/00
CPC分类号： C09D143/00 , C09D143/04
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
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2.发明申请LATENT, HIGH-ACTIVITY OLEFIN METATHESIS CATALYSTS CONTAINING AN N-HETEROCYCLIC CARBENE LIGAND 有权专利，高活性烯烃催化剂含有N-杂环碳酸盐配体公开(公告)号：US20150141603A1
公开(公告)日：2015-05-21
申请号：US14497387
申请日：2014-09-26
发明人： Thay UNG , Yann SCHRODI , Mark S. TRIMMER , Andrew HEJL , Daniel SANDERS , Robert H. GRUBBS
IPC分类号： C08G61/02 , C07D493/10
CPC分类号： C08G61/02 , C07C67/333 , C07D493/10 , C07F15/0046 , C08F132/08 , C08G61/06 , C08G2261/11 , C08G2261/3325 , C08G2261/418
摘要： The invention provides novel organometallic complexes useful as olefin metathesis catalysts. The complexes have an N-heterocyclic carbene ligand and a chelating carbene ligand associated with a Group 8 transition metal center. The molecular structure of the complexes can be altered so as to provide a substantial latency period. The complexes are particularly useful in catalyzing ring closing metathesis of acyclic olefins and ring opening metathesis polymerization of cyclic olefins.
摘要翻译： 本发明提供了用作烯烃复分解催化剂的新型有机金属络合物。 络合物具有与8族过渡金属中心相关的N-杂环卡宾配体和螯合卡宾配体。 可以改变配合物的分子结构，以便提供大量潜伏期。 该络合物特别可用于催化环烯烃的闭环复分解和环烯烃的开环易位聚合。
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3.发明申请公开(公告)号：US20180237581A1
公开(公告)日：2018-08-23
申请号：US15955876
申请日：2018-04-18
申请人： MATERIA, INC.
IPC分类号： C08G61/02 , C03C17/32 , C09D165/00 , B29B15/12
CPC分类号： C08G61/02 , B29B15/122 , B29K2309/08 , C03C17/328 , C03C25/30 , C08G61/08 , C08G2261/3325 , C08G2261/964 , C08J5/043 , C08J2323/20 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
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4.发明申请公开(公告)号：US20130296511A1
公开(公告)日：2013-11-07
申请号：US13779190
申请日：2013-02-27
发明人： Thay UNG , Yann SCHRODI , Mark S. TRIMMER , Andrew HEJL , Daniel SANDERS , Robert H. GRUBBS
IPC分类号： C07F15/00 , C08F132/08 , C07C67/333
CPC分类号： C08G61/02 , C07C67/333 , C07D493/10 , C07F15/0046 , C08F132/08 , C08G61/06 , C08G2261/11 , C08G2261/3325 , C08G2261/418
摘要： The invention provides novel organometallic complexes useful as olefin metathesis catalysts. The complexes have an N-heterocyclic carbene ligand and a chelating carbene ligand associated with a Group 8 transition metal center. The molecular structure of the complexes can be altered so as to provide a substantial latency period. The complexes are particularly useful in catalyzing ring closing metathesis of acyclic olefins and ring opening metathesis polymerization of cyclic olefins.
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公开(公告)号：US20180037677A1
公开(公告)日：2018-02-08
申请号：US15547942
申请日：2016-02-11
申请人： MATERIA, INC.
CPC分类号： C08F4/70 , C07F15/02 , C08F32/04 , C08F285/00 , C08G18/7671 , C08G61/08 , C08G2261/135 , C08G2261/3325 , C08G2261/418 , C08G2261/62 , C08G2261/76 , C08J5/24 , C08J2365/04 , C08K5/205 , C08K5/32 , C08K7/06 , C08K7/14 , C08L51/04 , C08L53/025 , C08L65/00
摘要： This invention relates to compositions and methods for improving the impact properties of polymer-matrix composites and to improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the impact properties of ring opening metathesis polymerization (ROMP) polymer-matrix composites and to improving the adhesion of ROMP compositions to substrate materials using adhesion promoters containing at least two isocyanate groups and functional elastomers comprising a maleic anhydride grafted styrene-ethylene/butylene-styrene hydrogenated copolymer in a resin composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.
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6.发明申请公开(公告)号：US20170233876A1
公开(公告)日：2017-08-17
申请号：US15374327
申请日：2016-12-09
申请人： MATERIA, INC.
发明人： Michael A. GIARDELLO , Mark S. TRIMMER , Christopher J. CRUCE , Anthony R. STEPHEN , Stuart A. M. TONER , Albert E. PAPPANO
CPC分类号： C25B9/00 , B29C39/003 , B29C67/246 , B29K2023/00 , B29K2023/38 , B29K2105/0014 , B29K2995/0029 , B29L2031/7146 , C08G61/02 , C08G2120/00 , C08G2261/3325 , C08G2261/418 , C08G2261/58 , C25B1/34
摘要： Articles of manufacture possessing corrosion resistance characteristics are described, in particular for use in the chlor-alkali and other industries. The articles are formed from a resin composition, e.g., a cyclic olefin composition, polymerized with a Group 8 olefin metathesis catalyst. In particular aspects, an electrolytic cell component, such as a cell cover for use in the electrolysis of brine, may be formed from the resin composition. Among other benefits, such articles provide improved corrosion resistance compared to articles molded from other resin compositions, such as fiberglass reinforced polyesters and vinyl esters, and two-component dicyclopentadiene (DCPD) resins comprising molybdenum or tungsten pre-catalysts.
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7.发明申请METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-公开用于改善基材组成的粘合的方法和组合物公开(公告)号：US20160326304A1
公开(公告)日：2016-11-10
申请号：US15109703
申请日：2015-01-12
申请人： MATERIA, INC.
IPC分类号： C08G61/02 , B29B15/12 , C09D165/00 , C03C25/30
CPC分类号： C08G61/02 , B29B15/122 , B29K2309/08 , C03C17/328 , C03C25/30 , C08G61/08 , C08G2261/3325 , C08G2261/964 , C08J5/043 , C08J2323/20 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter.
摘要翻译： 公开了一种改善复分解组合物如开环易位聚合（ROMP）组合物对基材的粘合性的方法，其中向可聚合树脂组合物中加入粘合促进剂以改善聚合树脂的粘合性 涉及基材。 已经发现添加粘合促进剂对复分解素，特别是ROMP，组合物对基材，特别是玻璃表面的粘附性提供有益的改进，导致由其形成的ROMP材料的改进的特性。 粘合促进剂通常包含官能化的硅烷化合物和过氧化物。 还公开了一种ROMP组合物，其包含环烯烃，ROMP复分解催化剂和粘合促进剂。
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公开(公告)号：US20160257779A1
公开(公告)日：2016-09-08
申请号：US14899165
申请日：2014-07-03
申请人： MATERIA, INC.
发明人： Christopher J. CRUCE , Michael A. GIARDELLO , Mark S. TRIMMER , Anthony R. STEPHEN , Paul W. BOOTHE , Brian EDGECOMBE , Jason L. MOORE
IPC分类号： C08G61/08
CPC分类号： C08G61/08 , C07C13/38 , C07C13/61 , C08F4/80 , C08G2261/3325 , C08G2261/418 , C08J5/043 , C08J2323/20 , C08K7/14 , C08L65/00
摘要： The present invention relates to methods and compositions for olefin metathesis. More particularly, the present invention relates to methods and compositions for ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles and/or polymer composite articles via ROMP Polymer products produced via the metathesis reactions of the invention may be utilized in a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.
摘要翻译： 本发明涉及烯烃复分解的方法和组合物。 更具体地说，本发明涉及用于开环易位聚合（ROMP）反应的方法和组合物以及通过ROMP制备聚合物制品和/或聚合物复合制品通过本发明的复分解反应生产的聚合物产品可用于宽 材料和复合材料应用范围。 本发明在聚合物和材料化学和制造领域具有实用性。
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公开(公告)号：US20160017089A1
公开(公告)日：2016-01-21
申请号：US14774347
申请日：2014-03-14
申请人： MATERIA, INC.
CPC分类号： C08G61/08 , B29C37/0032 , B29C41/00 , B29C41/22 , B29K2075/00 , C08G2261/3325 , C08G2261/418 , C08K5/05 , C08K5/053 , C08K5/101 , C08L65/00 , Y10T428/31938
摘要： The present invention relates to in-mold coating of a cyclic olefin polymer. More particularly, the present invention relates to methods and compositions for in-mold coating cyclic olefin polymers prepared by ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and material chemistry and manufacture.
摘要翻译： 本发明涉及环状烯烃聚合物的模内涂覆。 更具体地，本发明涉及通过开环易位聚合（ROMP）反应制备的环烯烃聚合物的模内涂布方法和组合物，以及通过ROMP制备聚合物制品。 通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。 本发明在聚合物和材料化学和制造领域具有实用性。
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10.发明申请METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-公开用于改善基材组成的粘合的方法和组合物公开(公告)号：US20150152283A1
公开(公告)日：2015-06-04
申请号：US13914919
申请日：2013-06-11
申请人： MATERIA, INC.
IPC分类号： C09D145/00
CPC分类号： C09D143/00 , C09D143/04
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
摘要翻译： 公开了一种改善复分解组合物如开环易位聚合（ROMP）组合物对基材的粘合性的方法，其中向可聚合树脂组合物中加入粘合促进剂以改善聚合树脂的粘合性 涉及基材。 已经发现添加粘合促进剂对复分解素，特别是ROMP，组合物对基材，特别是玻璃表面的粘附性提供有益的改进，导致由其形成的ROMP材料的改进的特性。 粘合促进剂通常包含官能化的硅烷化合物和过氧化物。 还公开了一种ROMP组合物，其包含环烯烃，ROMP复分解催化剂和粘合促进剂。 通过本发明的复分解（ROMP）反应制备的聚合物产物可用于提供广泛的材料和各种复合应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。
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