公开(公告)号：US07375061B2

公开(公告)日：2008-05-20

申请号：US10937247

申请日：2004-09-08

Applicant: Karl J. Duyck ,  Theodore E. Nalesnik ,  Wadim Batorewicz

Inventor： Karl J. Duyck ,  Theodore E. Nalesnik ,  Wadim Batorewicz

IPC: C10M173/02 ,  C10L1/22

CPC classification number: C10L10/18 ,  C08C19/22 ,  C08F8/30 ,  C08F255/02 ,  C08F255/04 ,  C08L23/16 ,  C10L1/226 ,  C10L1/2383 ,  C10L10/04 ,  C10M133/16 ,  C10M133/56 ,  C10M149/00 ,  C10M2205/024 ,  C10M2215/08 ,  C10M2217/06 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10 ,  C10N2240/14 ,  C10N2260/09 ,  C08F222/06

Abstract: A composition of matter is disclosed wherein the composition comprises a hydrazide compound of the formula: wherein: R1 is selected from the group consisting of alkyl, alkyl ether, and phenyl;R2, R3, R4, R5, and R6 are independently selected from the group consisting of hydrogen, alkyl, alkyl ether, and aryl; andn is an integer of from 0 to 10;and wherein:when R1 is phenyl, it is of the structure: wherein R7, R8, and R9 are independently selected from the group consisting of hydrogen, alkyl, alkyl ether, and aryl, or R7 can be combined with R8 to form a ring of 5 or 6 carbon atoms.The hydrazides are useful as stabilizers for lubricants, greases, and polymeric systems, particularly lubricating oils, as are maleated polymers that have been functionalized with them.

Abstract translation: 公开了一种物质组合物，其中组合物包含下式的酰肼化合物：其中：R 1选自烷基，烷基醚和苯基; R 2，R 3，R 4，R 5和R 6， 独立地选自氢，烷基，烷基醚和芳基; n为0〜10的整数。 并且其中：当R 1是苯基时，其结构如下：其中R 7，R 8和R 9， / SUB>独立地选自氢，烷基，烷基醚和芳基，或者R 7可以与R 8'一起形成环5 或6个碳原子。 酰肼可用作润滑剂，润滑脂和聚合物体系的稳定剂，特别是润滑油，以及已经用它们官能化的马来酸化聚合物。

公开(公告)号：US4384062A

公开(公告)日：1983-05-17

申请号：US329630

申请日：1981-12-11

Applicant: Wadim Batorewicz

Inventor： Wadim Batorewicz

IPC: C08K5/526 ,  C08K5/52 ,  C07F9/141

CPC classification number: C08K5/526

Abstract: Diphosphites having the structural formula: ##STR1## wherein: R.sup.1 and R.sup.2 may be the same or different and are C.sub.4 to C.sub.12 tertiary alkyl or C.sub.9 to C.sub.14 tertiary aralkyl;R.sup.3 is hydrogen, C.sub.1 to C.sub.18 alkyl or C.sub.7 to C.sub.18 aralkyl. These hydrolytically stable solid diphosphites are useful as antioxidants in organic polymers such as polypropylene.

Abstract translation: 具有以下结构式的二亚磷酸酯：其中：R 1和R 2可以相同或不同，为C 4至C 12叔烷基或C 9至C 14叔芳烷基; R3是氢，C1至C18烷基或C7至C18芳烷基。 这些水解稳定的固体二亚磷酸酯可用作有机聚合物如聚丙烯中的抗氧化剂。

公开(公告)号：US4794135A

公开(公告)日：1988-12-27

申请号：US90298

申请日：1987-08-28

Applicant: Edward L. Wheeler ,  Franklin H. Barrows ,  Robert J. Franko ,  Wadim Batorewicz

Inventor： Edward L. Wheeler ,  Franklin H. Barrows ,  Robert J. Franko ,  Wadim Batorewicz

IPC: C07D251/54 ,  C08K5/3492 ,  C08L9/00 ,  C08K5/34 ,  C08K5/17

CPC classification number: C08K5/34922

Abstract: Disclosed are novel tris(N-alkyl-p-phenylenediamino)-1,3,5-triazine compounds useful as antiozonants for unsaturated high polymers. The compounds may be prepared by reacting N-alkylphenylenediamine with a cyanuric halide.

Abstract translation: 公开了用作不饱和高聚物的抗臭氧剂的新型三（N-烷基 - 对苯二胺基）-1,3,5-三嗪化合物。 化合物可以通过N-烷基苯二胺与氰尿酰卤反应制备。

公开(公告)号：US3945954A

公开(公告)日：1976-03-23

申请号：US519441

申请日：1974-10-31

Applicant: Wadim Batorewicz

Inventor： Wadim Batorewicz

IPC: C07F9/12 ,  C08G18/38 ,  C08G79/06 ,  C08G18/14 ,  C08G18/32

CPC classification number: C08G79/06 ,  C07F9/12 ,  C08G18/3885

Abstract: Polymeric halogenated organophosphorus diols are obtained by reacting chlorine or bromine with spirocyclic phosphites and thereafter reacting the halogenated product with a diol, in the presence of an acid acceptor. These novel viscous polymers react with polyisocyantes to produce polyurethanes. Polyurethanes so made are characterized by improved flame retardant properties compared with conventional polyurethanes. Such polyurethanes are preferably in the form of foams, especially flexible foams.

Abstract translation: 聚合卤代有机磷二醇通过氯或溴与亚硫酸氢酯反应获得，然后在酸受体存在下使卤代产物与二醇反应。 这些新型粘性聚合物与聚异氰酸酯反应生成聚氨酯。 如此制成的聚氨酯的特征在于与常规聚氨酯相比具有改进的阻燃性能。 这种聚氨酯优选为泡沫形式，特别是柔性泡沫。

公开(公告)号：US4723040A

公开(公告)日：1988-02-02

申请号：US944262

申请日：1986-12-19

Applicant: Wadim Batorewicz

Inventor： Wadim Batorewicz

IPC: C07C85/11

Abstract: A process for preparing an N-mono-substituted-p-phenylenediamine by reacting the corresponding p-nitroso-N-mono-substituted aniline compound with a primary or secondary alcohol in the presence of a base.

Abstract translation: 通过在碱存在下使相应的对亚硝基-N-单取代苯胺化合物与伯醇或仲醇反应来制备N-单取代对苯二胺的方法。

公开(公告)号：US4479008A

公开(公告)日：1984-10-23

申请号：US430104

申请日：1982-09-30

Applicant: Wadim Batorewicz ,  Edward L. Wheeler

Inventor： Wadim Batorewicz ,  Edward L. Wheeler

IPC: C07C211/52 ,  C07C67/00 ,  C07C209/00 ,  C07C209/54 ,  C07C211/56 ,  C07C76/00 ,  C07C81/00

CPC classification number: C07C209/00

Abstract: A process for preparing p-nitrosodiphenylamine hydrochloride is provided from N-nitrosodiphenylamine and hydrogen chloride. The product is prepared in the absence of an aromatic solvent and using a solvent consisting essentially of aliphatic C.sub.5 -C.sub.10 alcohol.

Abstract translation: 制备对硝基二苯胺盐酸盐的方法由N-亚硝基二苯胺和氯化氢提供。 产物在不存在芳族溶剂的情况下制备，并使用基本上由脂族C 5 -C 10醇组成的溶剂。

公开(公告)号：US4341721A

公开(公告)日：1982-07-27

申请号：US193220

申请日：1980-10-01

Applicant: Wadim Batorewicz

Inventor： Wadim Batorewicz

IPC: C08K5/00 ,  C07F9/145 ,  C07F9/38 ,  C07F9/40 ,  C08K5/50 ,  C08K5/52 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  C09K15/32 ,  C07F9/141

CPC classification number: C07F9/145

Abstract: Diphosphites having the structural formula: ##STR1## wherein: R.sup.1 and R.sup.2 may be the same or different and are C.sub.4 to C.sub.12 tertiary alkyl or C.sub.9 to C.sub.14 tertiary aralkyl;R.sup.3 is hydrogen, C.sub.1 to C.sub.18 alkyl or C.sub.7 to C.sub.18 aralkyl. These hydrolytically stable solid diphosphites are useful as antioxidants in organic polymers such as polypropylene.

Abstract translation: 具有以下结构式的二亚磷酸酯：其中：R 1和R 2可以相同或不同，为C 4至C 12叔烷基或C 9至C 14叔芳烷基; R3是氢，C1至C18烷基或C7至C18芳烷基。 这些水解稳定的固体二亚磷酸酯可用作有机聚合物如聚丙烯中的抗氧化剂。

公开(公告)号：US5047530A

公开(公告)日：1991-09-10

申请号：US254005

申请日：1988-10-05

Applicant: Edward L. Wheeler ,  Franklin H. Barrows ,  Robert J. Franko ,  Wadim Batorewicz

Inventor： Edward L. Wheeler ,  Franklin H. Barrows ,  Robert J. Franko ,  Wadim Batorewicz

IPC: C08K5/3492

CPC classification number: C08K5/34922

Abstract: Disclosed are novel tris(N-alkyl-p-phenylenediamino)-1,3,5-triazine compounds useful as antiozonants for unsaturated high polymers. The compounds may be prepared by reacting N-alkylphenylenediamine with a cyanuric halide.

Abstract translation: 公开了用作不饱和高聚物的抗臭氧剂的新型三（N-烷基 - 对苯二胺基）-1,3,5-三嗪化合物。 化合物可以通过N-烷基苯二胺与氰尿酰卤反应制备。

公开(公告)号：US4518803A

公开(公告)日：1985-05-21

申请号：US430100

申请日：1982-09-30

Applicant: Wadim Batorewicz ,  Edward L. Wheeler

Inventor： Wadim Batorewicz ,  Edward L. Wheeler

IPC: C07C209/54 ,  C07C67/00 ,  C07C209/00 ,  C07C209/68 ,  C07C211/56 ,  C07C76/00 ,  C07C85/11

CPC classification number: C07C209/68

Abstract: A process is disclosed for the preparation of p-nitrosodiphenylamine hydrochloride comprising reacting diphenylamine, C.sub.5 -C.sub.10 alkyl nitrite and anhydrous HCl in the presence of a C.sub.5 -C.sub.10 aliphatic alcohol and essentially in the absence of an aromatic solvent.

Abstract translation: 公开了用于制备对亚硝基二苯胺盐酸盐的方法，包括在C5-C10脂族醇存在下，基本上不存在芳族溶剂的情况下使二苯胺，亚硝酸C5-C10烷基酯和无水HCl反应。

公开(公告)号：US3970726A

公开(公告)日：1976-07-20

申请号：US543289

申请日：1975-01-23

Applicant: Wadim Batorewicz

Inventor： Wadim Batorewicz

IPC: C08K5/00 ,  C07F9/09 ,  C07F9/6574 ,  C08G79/00 ,  C08G79/02 ,  C08G79/04 ,  C08K5/52 ,  C08L67/00 ,  C07F9/15 ,  C08J9/00

CPC classification number: C08G79/04 ,  C07F9/091

Abstract: Phosphate esters having the formula RO[-(A).sub.m (B).sub.n ] H wherein A has the structural formula ##SPC1##And B has the structural formula ##SPC2##Wherein the R groups are alkyl radicals, m and n are each integers from 0 to 4 and the sum of m + n is from 1 to about 4, are useful as flame retardants, especially for rigid polyurethane foams.

Abstract translation: 具有式RO [ - （A）m（B）n] H的磷酸酯，其中A具有结构式AND B具有结构式，其中R基团是烷基，m和n各自为0至4的整数， m + n的和为1至约4，可用作阻燃剂，特别是用于刚性聚氨酯泡沫。