N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates
    1.
    发明授权
    N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates 失效
    N-取代的3,4,5,6-四氢去唾液酸及其中间体

    公开(公告)号:US5062884A

    公开(公告)日:1991-11-05

    申请号:US463817

    申请日:1990-01-16

    Abstract: N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates of the general formula I ##STR1## where A is --NO.sub.2, --NH.sub.2 or ##STR2## corresponding to the compounds Ia, Ib and Ic, B is --CH.sub.2 --, --CH.sub.2 --CHR.sup.1 --, --CH.sub.2 --CHR.sup.1 --CH.sub.2 --, --CH.dbd., --CH.dbd.CR.sup.1 -- or --CH.dbd.CR.sup.1 --CH.dbd., R.sup.1 being --H, --Cl, --Br or --CH.sub.3, D is ##STR3## depending on the terminal group B, X is --H, --Cl or --Br, Y is --H, C.sub.1 -C.sub.7 --alkyl, --Cl, --Br, --CN, --CONH.sub.2 --CO.sub.2 R.sup.2, where R.sup.2 is H, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -- or C.sub.6 -cycloalkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylmercapto-C.sub.2 -C.sub.4 -alkyl, propargyl, benzyl, .alpha.-phenylethyl, .alpha.-phenylpropyl, C.sub.2 -C.sub.4 -alkyl which is monosubstituted, disubstituted or trisubstituted by F or Cl, or CH.sub.3 -substituted or Cl-substituted allyl, and Z is --COOR.sup.2, --CONR.sup.3 R.sup.4, ##STR4## where R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.4 -alkyl or together form a 5-membered or 6-membered cycloaliphatic ring whose carbon chain may be interrupted by an oxygen atom.

    Abstract translation: B)是N-取代的3,4,5,6-四氢邻苯二甲酰亚胺及其中间体,其中A是与化合物Ia,Ib和Ic相对应的-NO 2,-NH 2或 -CH 2 - , - CH 2 -CHR 2 - , - CH =, - CH = CR 1或-CH = CR 1 -CH =,R 1是-H,-Cl,-Br或-CH 3, D是取代基末端基团B,X是-H,-Cl或-Br,Y是-H,C 1 -C 7 - 烷基,-Cl,-Br,-CN,-CONH 2 -CO 2 R 2,其中R 2 是C 1 -C 6烷基,C 5 - 或C 6 - 环烷基,C 1 -C 4 - 烷氧基-C 1 -C 4烷基,C 1 -C 4烷基巯基-C 2 -C 4 - 烷基,炔丙基,苄基,α-苯乙基,α- 苯基丙基,被F或Cl单取代或三取代的C 2 -C 4 - 烷基,Z是-COOR 2,-CONR 3 R 4,其中R 3和R 4各自为H或C 1 -C 1-4 - 烷基或一起形成其碳链可以被氧原子间隔开的5元或6元环脂族环。

    Nitro or amino substituted phenylalkyl or phenylalkenyl carboxylic acid
derivatives
    2.
    发明授权
    Nitro or amino substituted phenylalkyl or phenylalkenyl carboxylic acid derivatives 失效
    硝基或氨基取代的苯基烷基或苯基烯基羧酸衍生物

    公开(公告)号:US5237089A

    公开(公告)日:1993-08-17

    申请号:US985534

    申请日:1992-12-03

    Abstract: N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates of the general formula I ##STR1## where A is --NO.sub.2, --NH.sub.2 or ##STR2## corresponding to the compounds Ia, Ib and Ic, B is --CH.sub.2 --, --CH.sub.2 --CHR.sup.1 --, --CH.sub.2 --CHR.sup.1 --CH.sub.2 --, --CH.dbd., --CH.dbd.CR.sup.1 -- or --CH.dbd.CR.sup.1 --CH.dbd., R.sup.1 being --H, --Cl, --Br or --CH.sub.3, D is ##STR3## or .dbd.C

    Abstract translation: B)是N-取代的3,4,5,6-四氢邻苯二甲酰亚胺及其中间体,其中A是与化合物Ia,Ib和Ic相对应的-NO 2,-NH 2或 -CH 2 - , - CH 2 -CHR 2 - , - CH =, - CH = CR 1或-CH = CR 1 -CH =,R 1是-H,-Cl,-Br或-CH 3, D为或= C <,取决于末端基团B,X为-H,-Cl或-Br,Y为-H,C 1 -C 7 - 烷基,-Cl,-Br,-CN,-CONH 2 或-CO2R2,其中R2是H,C1-C6-烷基,C5-或C6-环烷基,C1-C4-烷氧基-C2-C4-烷基,C1-C4-烷基巯基-C2-C4-烷基,炔丙基,苄基, α-苯基乙基,α-苯基丙基,被F或Cl单取代或三取代的C 2 -C 4烷基,或CH 3取代或Cl取代的烯丙基,Z是-COOR 2,-CONR 3 R 4, 其中R 3和R 4各自为H或C 1 -C 4烷基或一起形成其碳链可被氧原子间隔的5元或6元环脂环。

    Phenylalkenylcarboxylic acids and their esters
    5.
    发明授权
    Phenylalkenylcarboxylic acids and their esters 失效
    苯基链烯基羧酸及其酯

    公开(公告)号:US4933001A

    公开(公告)日:1990-06-12

    申请号:US217563

    申请日:1988-07-11

    CPC classification number: C07D209/48 A01N37/32

    Abstract: Phenylalkenylcarboxylic acid and esters thereof of the general formula I ##STR1## where X is hydrogen or fluorine, R.sup.1 is hydrogen, C.sub.1 C.sub.6 -alkyl, C.sub.5 - or C.sub.6 -cycloalkyl, (C.sub.1 -C.sub.4 -alkoxy)-C.sub.2 -C.sub.4 -alkyl or (C.sub.1 -C.sub.4 -alkylthio)-C.sub.2 -C.sub.4 -alkyl; W is a divalent radical --CH.dbd.CR.sup.2 --; --CH.dbd.CY--; --CH.dbd.CR.sup.2 --CH.sub.2 --; --CH.dbd.CR.sup.2 --CH.dbd.CR.sup.3 -- or ##STR2## where Y is chlorine or bromine and R.sup.2 and R.sup.3 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, with the proviso that X is not F when W is --CH.dbd.CR.sup.2 --, their manufacture, and their use as herbicides.

    Abstract translation: 苯基链烯基羧酸及其通式I的酯其中X是氢或氟,R 1是氢,C 1 -C 6 - 烷基,C 5 - 或C 6 - 环烷基,(C 1 -C 4 - 烷氧基)-C 2 -C 4烷基或 (C 1 -C 4 - 烷硫基)-C 2 -C 4 - 烷基; W是二价基团-CH = CR2-; -CH = CY-; -CH = CR 2 -CH 2 - ; -CH = CR2-CH = CR3-或其中Y是氯或溴,R2和R3各自是氢或C1-C4-烷基,条件是当W是-CH = CR2-时,X不是F, 它们的制造及其作为除草剂的用途。

    Pyridine derivatives and their use for controlling undesirable plant
growth
    9.
    发明授权
    Pyridine derivatives and their use for controlling undesirable plant growth 失效
    吡啶衍生物及其用于控制​​不希望的植物生长的用途

    公开(公告)号:US5262387A

    公开(公告)日:1993-11-16

    申请号:US783310

    申请日:1991-11-20

    CPC classification number: C07D213/81 A01N43/40 A01N43/90 C07D213/82 C07D471/04

    Abstract: Pyridine derivatives of the formulae ##STR1## wherein W, X, Y and Z are each C--R.sup.4, N or N.fwdarw.O, with the proviso that the ring contains only one heteroatom, and the substituents R.sup.1, R.sup.2 and R.sup.3 have the following meanings:R.sup.1 is alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl,R.sup.2 is hydrogen,R.sup.3 is formyl, 4,5-dihydrooxazol-2-yl or --CO--A--R.sup.5 or --CO--NR.sup.6.sup.R.sup.7, whereR.sup.4 is halogen, nitro, cyano, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, alkenyloxy, alkynyloxy, alkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, or is substituted or unsubstituted phenyl,A is oxygen or sulfur,R.sup.5 is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, cycloalkyl, substituted or unsubstituted phenyl,one equivalent of a cation or the radical --N.dbd.CR.sup.8 R.sup.9 andR.sup.6 and R.sup.7 are hydrogen or alkyl or together denote a methylene chain having 4 or 5 members,their agriculturally utilizable salts, and their use for controlling unwanted plant growth.

    Abstract translation: 其中W,X,Y和Z各自为C-R 4,N或N-> O的吡啶衍生物,条件是环仅含有一个杂原子,并且取代基R 1,R 2和 R3具有以下含义:R 1是烷氧基,取代或未取代的烷基,取代或未取代的环烷基,取代或未取代的烯基,或取代或未取代的炔基,R 2是氢,R 3是甲酰基,4,5-二氢恶唑-2-基或 - CO-A-R5或-CO-NR6R7,其中R4是卤素,硝基,氰基,取代或未取代的烷基,取代或未取代的苄基,取代或未取代的环烷基,取代或未取代的烯基,取代或未取代的炔基,烷氧基,烷硫基,卤代烷氧基 卤代烷硫基,烯氧基,炔氧基,烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,取代或未取代的苯氧基或苯硫基,取代或未取代的具有一个或两个选自基团的杂原子的5-或6-元杂环基 氧,硫和氮的取代基,或者是取代或未取代的苯基,A是氧或硫,R5是氢,取代或未取代的烷基,取代或未取代的苄基,环烷基,取代或未取代的苯基,1当量的阳离子或基团 -N = CR8R9,R6和R7是氢或烷基或一起表示具有4或5个成员的亚甲基链,它们的农业上可利用的盐,以及它们用于控制不想要的植物生长的用途。

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