公开(公告)号：US10892517B2

公开(公告)日：2021-01-12

申请号：US16923567

申请日：2020-07-08

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Yasuhiro Harada ,  Norio Takami ,  Hiroki Inagaki

IPC分类号： H01M10/0562 ,  H01B1/08 ,  C04B35/645 ,  C04B35/486 ,  C01G23/00 ,  B32B18/00 ,  C04B35/626 ,  C04B35/462 ,  C04B35/01 ,  C01G25/00

摘要： According to one embodiment, a solid electrolyte includes a sintered body of ceramic grains. The sintered body includes a crystal plane having an ion conducting path. The crystal plane is oriented in a direction which intersects at least one surface of the solid electrolyte.

公开(公告)号：US10727540B2

公开(公告)日：2020-07-28

申请号：US15457406

申请日：2017-03-13

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Norio Takami ,  Yasunobu Yamashita ,  Shinsuke Matsuno ,  Yasuhiro Harada ,  Hiroki Inagaki

IPC分类号： H01M4/00 ,  H01M10/38 ,  H01M4/485 ,  H01M2/10 ,  H01M4/58 ,  H01M4/02

摘要： According to one embodiment, a secondary battery including a positive electrode, a negative electrode, and an electrolyte is provided. The negative electrode includes titanium-containing oxide and at least one kind of element selected from the group consisting of B, P, Al, La, Zr, Ge, Zn, Sn, Ga, Pb, In, Bi, and Tl. The electrolyte includes lithium ions and a solvent containing water.

公开(公告)号：US10700351B2

公开(公告)日：2020-06-30

申请号：US15899550

申请日：2018-02-20

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Norio Takami ,  Hiroki Inagaki ,  Takashi Kishi

IPC分类号： H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569

摘要： According to one embodiment, a nonaqueous electrolyte battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes at least one oxide selected from the group consisting of a first oxide having a spinel structure and represented by LixNi0.5Mn1.5O4, a second metal phosphate having an olivine structure and represented by LixMn1-wFewPO4, and a third oxide having a layered structure and represented by LixNiyMnzCo1-y-zO2. The nonaqueous electrolyte includes a first solvent. The first solvent includes at least one compound selected from the group consisting of trimethyl phosphate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, and fluorinated phosphate ester.

公开(公告)号：US10347906B2

公开(公告)日：2019-07-09

申请号：US15698345

申请日：2017-09-07

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Kazuki Ise ,  Shinsuke Matsuno ,  Norio Takami ,  Hiroki Inagaki

IPC分类号： H01M4/24 ,  H01M10/39 ,  B32B27/06 ,  H01M10/42 ,  H01M4/04 ,  H01M2/06 ,  H01M2/08 ,  H01M2/10 ,  H01M10/36 ,  H01M4/02

摘要： According to one embodiment, a secondary battery is provided. The secondary battery includes a negative electrode including a negative electrode current collector, a negative electrode terminal electrically connected to the negative electrode current collector, a joint electrically connecting the negative electrode terminal and the negative electrode current collector, and a water repellent layer covering the joint. The joint is covered with the inner surface of the water repellent layer. A contact angle θ with respect to water on an outer surface of the water repellent layer satisfies 80°≤θ.

公开(公告)号：US20190089010A1

公开(公告)日：2019-03-21

申请号：US15908189

申请日：2018-02-28

申请人： Kabushiki Kaisha Toshiba

发明人： Yasunobu Yamashita ,  Shinsuke Matsuno ,  Norio Takami ,  Hiroki Inagaki

IPC分类号： H01M10/38 ,  H01M4/505 ,  H01M4/485 ,  H01M4/525 ,  H01M4/48 ,  H01M10/42 ,  H01M10/46 ,  H01M2/10 ,  H02J7/14 ,  B60L11/18

摘要： According to one embodiment, a secondary battery including a positive electrode, a negative electrode, and an electrolyte is provided. The negative electrode contains a negative electrode active material. The negative electrode active material includes titanium-containing metal oxide particles, an anatase type TiO2 phase, and a solid electrolyte phase. Each of the anatase type TiO2 phase and the solid electrolyte phase is disposed on at least a portion of a surface of the titanium-containing metal oxide particles. The electrolyte contains an electrolyte salt and water.

公开(公告)号：US10218005B2

公开(公告)日：2019-02-26

申请号：US15445057

申请日：2017-02-28

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Kazuki Ise ,  Yasunobu Yamashita ,  Shinsuke Matsuno ,  Norio Takami ,  Hiroki Inagaki

IPC分类号： H01M14/00 ,  H01M4/66 ,  B60L11/18 ,  H01M2/30 ,  H01M4/04 ,  H01M4/485 ,  H01M4/505 ,  H01M4/62 ,  H01M10/36 ,  H01M10/42 ,  H01M4/38 ,  H01M4/48 ,  H01M4/02

摘要： According to one embodiment, a secondary battery is provided. The secondary battery includes a positive electrode, a negative electrode, and an electrolyte including a water-containing solvent and a lithium ion. The negative electrode includes an aluminum-containing negative electrode current collector and a boehmite-containing cover layer, and the boehmite-containing cover layer is provided on at least a part of a surface of the negative electrode current collector, and has a thickness of 10 nm to 1000 nm.

公开(公告)号：US09812704B2

公开(公告)日：2017-11-07

申请号：US15066663

申请日：2016-03-10

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Hiroki Inagaki ,  Norio Takami

IPC分类号： H01M4/36 ,  H01M4/485 ,  H01M4/62 ,  H01M10/0525 ,  H01M4/02

CPC分类号： H01M4/364 ,  H01M4/366 ,  H01M4/485 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/027 ,  H01M2220/20 ,  Y02E60/122 ,  Y02T10/7011

摘要： According to one embodiment, an active material is provided. This active material includes a mixed phase of a phase of titanium-including composite oxide and a phase of titanium oxide. The titanium-including composite oxide has a crystal structure belonging to a space group Cmca or a space group Fmmm.

公开(公告)号：US09508981B2

公开(公告)日：2016-11-29

申请号：US14604376

申请日：2015-01-23

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Hiroki Inagaki ,  Norio Takami

IPC分类号： H01M4/58 ,  H01M4/131 ,  H01M4/485 ,  C01G23/00 ,  C01G23/047 ,  C01B25/45 ,  H01M10/0525

CPC分类号： H01M4/131 ,  C01B25/45 ,  C01G23/001 ,  C01G23/005 ,  C01G23/047 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2006/12 ,  H01M4/485 ,  H01M4/5825 ,  H01M10/0525 ,  Y02E60/122 ,  Y02T10/7011

摘要： According to one embodiment, a non-aqueous electrolyte battery is provided. The non-aqueous electrolyte battery includes a negative electrode contained a negative electrode active material. The negative electrode active material includes a monoclinic β-type titanium-based oxide or lithium titanium-based oxide. The monoclinic β-type titanium-based oxide or lithium titanium-based oxide has a peak belonging to (011), which appears at 2θ1 in a range of 24.40° or more and 24.88° or less, in an X-ray diffraction pattern obtained by wide angle X-ray diffractometry using CuKα radiation as an X-ray source.

摘要翻译： 根据一个实施方案，提供非水电解质电池。 非水电解质电池包括含有负极活性物质的负极。 负极活性物质包括单斜晶型β型钛系氧化物或锂钛系氧化物。 单斜晶β型钛基氧化物或锂钛基氧化物具有属于（011）的峰，其在所获得的X射线衍射图中在2.40°以上且24.88°以下的范围出现在2θ1 通过使用CuKα辐射作为X射线源的广角X射线衍射法。

公开(公告)号：US09406973B2

公开(公告)日：2016-08-02

申请号：US14242943

申请日：2014-04-02

申请人： KABUSHIKI KAISHA TOSHIBA

发明人： Norio Takami ,  Hiroki Inagaki ,  Keigo Hoshina

IPC分类号： H01M4/13 ,  H01M10/0564 ,  H01M4/36 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/0525 ,  H01M4/02

CPC分类号： H01M10/0564 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/021 ,  Y02E60/122 ,  Y02T10/7011

摘要： A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode contains active material particles and a coating material. The active material particles are represented by any one of the following formulae (1) to (3): LixM1yO2  (1) LizM22wO4  (2) LisM3tPO4  (3) and have an average particle diameter of 0.1 to 10 μm. The coating material comprises at least particles having an average particle diameter of 60 nm or less or layers having an average thickness of 60 nm or less. The particles or the layers contain at least one element selected from the group consisting of Mg, Ti, Zr, Ba, B and C.

摘要翻译： 非水电解质电池包括正极，负极和非水电解质。 正极含有活性物质粒子和涂料。 活性物质粒子由下述式（1）〜（3）中的任一个表示：LixM1yO2（1）LizM22wO4（2）LisM3tPO4（3），平均粒径为0.1〜10μm。 涂层材料至少包含平均粒径为60nm以下的平均粒径或者60nm以下的平均粒径的粒子。 颗粒或层包含至少一种选自Mg，Ti，Zr，Ba，B和C的元素。

公开(公告)号：US09373836B2

公开(公告)日：2016-06-21

申请号：US13863405

申请日：2013-04-16

申请人： Kabushiki Kaisha Toshiba

发明人： Hiroki Inagaki ,  Keigo Hoshina ,  Norio Takami

IPC分类号： H01M4/02 ,  H01M4/131 ,  H01M4/36 ,  H01M4/38 ,  H01M4/485 ,  H01M10/48 ,  H01M2/10 ,  H01M4/50 ,  H01M4/58 ,  H01M10/0525 ,  H01M10/0569

CPC分类号： H01M4/131 ,  H01M2/1061 ,  H01M2/1077 ,  H01M4/366 ,  H01M4/38 ,  H01M4/386 ,  H01M4/485 ,  H01M4/502 ,  H01M4/58 ,  H01M4/5825 ,  H01M10/0525 ,  H01M10/0569 ,  H01M10/482 ,  H01M2004/027 ,  H01M2200/00 ,  Y02E60/122 ,  Y02P70/54

摘要： According to one embodiment, a non-aqueous electrolyte battery includes an outer package, a positive electrode housed in the outer package, a negative electrode housed with a space from the positive electrode in the outer package and including an active material, and a non-aqueous electrolyte filled in the outer package. The active material includes a lithium-titanium composite oxide particle, and a coating layer formed on at least a part of the surface of the particle and including at least one metal selected from the group consisting of Mg, Ca, Sr, Ba, Zr, Fe, Nb, Co, Ni, Cu and Si, an oxide of at least one metal selected from the group or an alloy containing at least one metal selected from the group.

摘要翻译： 根据一个实施方案，非水电解质电池包括外包装，容纳在外包装中的正电极，在外包装中具有来自正电极的空间的负极，并且包括活性材料， 填充在外包装中的水性电解质。 活性物质包括锂 - 钛复合氧化物颗粒和形成在颗粒的表面的至少一部分上的涂层，并且包括选自Mg，Ca，Sr，Ba，Zr中的至少一种金属， Fe，Nb，Co，Ni，Cu和Si，选自该组中的至少一种金属的氧化物或含有选自该组的至少一种金属的合金。