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公开(公告)号:US4182692A
公开(公告)日:1980-01-08
申请号:US913812
申请日:1978-06-08
CPC分类号: B01J29/18 , C07C5/2775 , Y10S502/52
摘要: Ammonia exchanged large port mordenite, which is subsequently mildly acid leached, and calcined, in which at least 95% of the exchangeable sodium has been removed and having from 0.38 to 0.8 milliequivalents of acid sites at least as strong as 48% sulfuric acid per gram (as measured by titration with butylamine, and employing dicinnamalacetone indicator) has been found to be a highly active hydrocarbon isomerization catalyst. Incorporation of noble metal, e.g. palladium, on the catalyst improves the selectivity for isomerization of normal pentane to isopentane for highly active catalysts at high conversion rates.
摘要翻译: 氨交换大口径丝光沸石,其随后是轻度酸浸出,并煅烧,其中至少95%的可交换的钠已经被除去,并且具有至少相当于48%硫酸的酸的0.38至0.8毫当量的酸性位点 (通过用丁胺滴定测量,并且使用二硝基丙酮指示剂测量)已被发现是高活性烃异构化催化剂。 掺入贵金属,例如 催化剂上的钯改善了在高转化率下用于高活性催化剂的正戊烷异构化到异戊烷的选择性。
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公开(公告)号:US4232181A
公开(公告)日:1980-11-04
申请号:US53078
申请日:1979-06-28
CPC分类号: B01J29/22 , C07C5/2791
摘要: Ammonia exchanged large port mordenite, which is subsequently mildly acid leached, and calcined, in which at least 95% of the exchangeable sodium has been removed and having from 0.38 to 0.8 milliequivalents of acid sites at least as strong as 48% sulfuric acid per gram (as measured by titration with butylamine, and employing dicinnamalacetone indicator) has been found to be highly active hydrocarbon isomerization catalyst. Incorporation of noble metal, e.g. palladium, on the catalyst improves the selectivity for isomerization of normal pentane to isopentane for highly active catalysts at high conversion rates.
摘要翻译: 氨交换大口径丝光沸石,其随后是轻度酸浸出,并煅烧,其中至少95%的可交换的钠已经被除去,并且具有至少相当于48%硫酸的酸的0.38至0.8毫当量的酸性位点 (通过用丁胺滴定测量并使用二硝基丙酮指示剂)已被发现是高活性烃异构化催化剂。 掺入贵金属,例如 催化剂上的钯改善了在高转化率下用于高活性催化剂的正戊烷异构化到异戊烷的选择性。
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公开(公告)号:US4410453A
公开(公告)日:1983-10-18
申请号:US344461
申请日:1982-02-01
IPC分类号: B01J23/50 , B01J23/68 , C07D301/10 , B01J21/04 , B01J21/12
CPC分类号: B01J23/50 , B01J23/68 , C07D301/10
摘要: The performance of a silver on alumina catalyst for the oxidation of ethylene to ethylene oxide is improved by the inclusion, in the raw mix for the carrier of an oxide, or oxide precursor, of zinc, lanthanum, or magnesium in the amount of 7 to 40%, calculated as the oxide.
摘要翻译: 在氧化乙烯到氧化乙烯的氧化铝催化剂上的银的性能通过在氧化物的载体或氧化物前体的锌,镧或镁的原料混合物中包含7至 40%,以氧化物计算。
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公开(公告)号:US4059543A
公开(公告)日:1977-11-22
申请号:US589070
申请日:1975-06-23
摘要: Clinoptilolite is exchanged to the ammonium form and then treated with a dilute solution of a strong acid. An adsorbent for acid gases of improved capacity and life is obtained. The adsorbent is preferably in the form of ceramic bonded pellets.
摘要翻译: 将斜发沸石交换成铵形式,然后用强酸的稀溶液处理。 获得了具有改善的容量和寿命的酸性气体吸附剂。 吸附剂优选为陶瓷结合丸剂的形式。
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公开(公告)号:US3945945A
公开(公告)日:1976-03-23
申请号:US324106
申请日:1973-01-16
CPC分类号: B01J23/868 , B01J21/04 , B01J23/72 , B01J23/74 , C04B35/10
摘要: High surface area alumina bodies for use as catalysts, catalyst carriers, and sorbents are made by controlled mixing of fine particle size platy boehmite alumina aggregates with a monobasic acid to produce non-pasty free-flowing particulate mass of aggregates of boehmite. This mass can then be formed by pressure into selected shapes such as rings, saddles, cylinders, solid, or hollow, or pellets, dried and fired to produce bodies of boehmite, gamma alumina, delta alumina, theta alumina or alpha alumina ranging in surface area of from 10 square meters per gram to greater than 300 square meters per gram. Catalytic metal can be included in the bodies by impregnation, before or after firing, or can be incorporated by inclusion in the aqueous acid treating solution.
摘要翻译: 用作催化剂,催化剂载体和吸附剂的高表面积氧化铝体是通过将微粒尺寸的扁平勃姆石氧化铝聚集体与一元酸控制混合制成勃姆石聚集体的非糊状自由流动的颗粒物。 然后可以通过压力将该质量形成为选定的形状,例如环,鞍座,圆柱体,固体或中空或颗粒,干燥和烧制以产生勃姆石,γ氧化铝,δ氧化铝,θ氧化铝或α氧化铝的表面 面积从10平方米每克到大于300平方米每克。 催化金属可以通过浸渍,烧制之前或之后包含在体内,或通过包含在酸性水溶液中而被引入。
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公开(公告)号:US4526690A
公开(公告)日:1985-07-02
申请号:US463747
申请日:1983-02-04
CPC分类号: G01N33/5302 , C12Q1/6804 , C12Q1/70 , G01N33/5304 , G01N33/548
摘要: A multiwell apparatus for the assay of microliter quantities of body fluids is provided which prevents fluid loss by lateral migration or gravity flow through a microporous membrane or ultrafilter. A sample is passed through a membrane to which an antibody has been bonded in order to harvest complementary viral antigens in the sample. The harvested viral antigen is converted to single strand DNA or RNA which then is deposited on a second membrane. The deposited single strand DNA or RNA is capable of reacting with labeled DNA or other suitable detection probe which can be detected and correlated with antigen concentration in the sample.
摘要翻译: 提供了用于微量体液的测定的多孔设备,其防止通过横向迁移或重力流过微孔膜或超滤器而导致的流体损失。 样品通过已经结合抗体的膜,以收获样品中的互补病毒抗原。 将收获的病毒抗原转化为单链DNA或RNA,然后将其沉积在第二膜上。 沉积的单链DNA或RNA能够与标记的DNA或其他合适的检测探针反应,其可以被检测并与样品中的抗原浓度相关。
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公开(公告)号:US4102978A
公开(公告)日:1978-07-25
申请号:US798887
申请日:1977-05-20
申请人: Joseph R. Kiovsky
发明人: Joseph R. Kiovsky
CPC分类号: C01F7/02 , B01J20/08 , B01J21/04 , C01P2004/50 , C01P2004/61 , C01P2006/10 , C01P2006/12 , C01P2006/22
摘要: Alumina catalyst carriers are produced by bonding pre-fired gibbsite with microcrystalline boehmite. Superior strength of the product is achieved by use of gibbsite fired to an L.O.I. at 1000.degree. C of 8% or less, or preferably less than 4%.
摘要翻译: 通过将预烧三水铝矿与微晶勃姆石结合来制备氧化铝催化剂载体。 通过使用向L.O.I.发射的三水铝矿实现产品的优异强度。 在1000℃下为8%以下,优选小于4%。
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