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1.发明申请COMPOSITIONS FOR CARBOXYLIC ACID PRODUCTION AND METHODS FOR MAKING AND USING SAME 审中-公开羧酸生产的组合物及其制备和使用方法公开(公告)号：US20090326268A1
公开(公告)日：2009-12-31
申请号：US12494098
申请日：2009-06-29
CPC分类号： C07C51/12 , B01J8/00 , B01J31/20 , B01J2219/00006 , B01J2231/321 , B01J2531/822 , B01J2531/827 , C07C51/50 , C07C2523/46 , C07C53/08
摘要： An alcohol such as methanol is reacted with carbon monoxide in a liquid reaction medium including a catalyst, an alkyl iodide such as methyl iodide, alkyl acetate such as methyl acetate in specified proportions, an additive, and an effective amount of water, where the additive increases an ionic character of the hydrogen iodide bond and the effective amount of water is sufficient to facilitate carboxylic acid release after carbonylation at the catalyst and to reduce anhydride formation. The present reaction system not only provides an acid product at water levels considerable below levels currently used, but also provides unexpected reaction rates and unexpected high catalyst stability.
摘要翻译： 醇等甲醇与一氧化碳在液体反应介质中反应，该反应介质包括催化剂，甲基碘等烷基碘，特定比例的乙酸烷基酯如乙酸甲酯，添加剂和有效量的水，其中添加剂 增加碘化氢键的离子特性，有效量的水足以促进催化剂羰基化后的羧酸释放并减少酸酐形成。 本反应体系不仅提供了水含量相当低于目前使用的酸产品，而且提供了出人意料的反应速率和出人意料的高催化剂稳定性。
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公开(公告)号：US6031129A
公开(公告)日：2000-02-29
申请号：US538561
申请日：1995-10-03
申请人： James A. Hinnenkamp , Noel Hallinan
发明人： James A. Hinnenkamp , Noel Hallinan
IPC分类号： C07C51/12
CPC分类号： C07C51/12
摘要： Methanol is converted to acetic acid by reaction with carbon monoxide in the presence of an improved carbonylation system which comprises a rhodium catalyst component and a liquid reaction medium containing water in low levels, acetic acid, methyl iodide, methyl acetate, and at least one pentavalent Group VA oxide wherein the concentration of pentavalent Group VA oxide to rhodium is greater than about 60:1. The present carbonylation system not only increases the yields and reaction rates but also serves to stabilize the rhodium catalyst component in an active form.
摘要翻译： 在改进的羰基化体系的存在下，甲醇通过与一氧化碳反应而转化为乙酸，其包括铑催化剂组分和含有低含量水的液体反应介质，乙酸，甲基碘，乙酸甲酯和至少一种五价 VA族氧化物，其中五价VA族氧化物与铑的浓度大于约60:1。 本发明的羰基化体系不仅提高了产率和反应速度，而且还用于使铑催化剂组分以活性形式稳定。
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公开(公告)号：US5817869A
公开(公告)日：1998-10-06
申请号：US720831
申请日：1996-10-03
申请人： James A. Hinnenkamp , Noel Hallinan
发明人： James A. Hinnenkamp , Noel Hallinan
CPC分类号： C07C51/12
摘要： Methanol is converted to acetic acid by reaction with carbon monoxide in the presence of an carbonylation system which comprises a rhodium catalyst component and a liquid reaction medium containing acetic acid, methyl iodide, methyl acetate, and at least one pentavalent Group VA oxide and water in specific concentrations. The present carbonylation system not only increases the yields and reaction rates but also serves to stabilize the rhodium catalyst component in an active form.
摘要翻译： 在包含铑催化剂组分和含有乙酸，甲基碘，乙酸甲酯和至少一种五价VA族氧化物和水的液体反应介质的羰基化系统存在下，甲醇通过与一氧化碳反应而转化为乙酸 特异性浓度。 本发明的羰基化体系不仅提高了产率和反应速度，而且还用于使铑催化剂组分以活性形式稳定。
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4.发明授权
公开(公告)号：US4331641A
公开(公告)日：1982-05-25
申请号：US92127
申请日：1979-11-07
IPC分类号： B01J21/02 , B01J29/035 , B01J29/86 , C01B33/20 , C01B35/10
CPC分类号： B01J29/035 , B01J29/86 , C01B35/1009
摘要： Crystalline metal silicate compositions are prepared from a silica containing mixture which is substantially free of aluminum ions and which contains a chelating agent by digesting a reaction mixture comprising, a tetraalkylammonium compound, sodium hydroxide, a metal compound, an oxide of silicon, a chelating agent and water, with the reaction mixture containing less than about 100 ppm aluminum. Crystalline borosilicate compositions are of special interest. A method for activating the new crystalline compositions to enhance their usefulness for certain conversion processes is also disclosed.
摘要翻译： 结晶金属硅酸盐组合物由基本上不含铝离子的含二氧化硅的混合物制备，并含有螯合剂，通过消化包含四烷基铵化合物，氢氧化钠，金属化合物，硅氧化物，螯合剂的反应混合物 和水，反应混合物含有少于约100ppm的铝。 结晶硼硅酸盐组合物是特别有意义的。 还公开了一种用于激活新的结晶组合物以增强其对某些转化方法的用途的方法。
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公开(公告)号：US5037787A
公开(公告)日：1991-08-06
申请号：US379515
申请日：1989-07-13
CPC分类号： B01J29/049
摘要： The present disclosure is directed to a nickel pillared interlayered clay characterized by a temperature program reductin maxima of less than 500.degree. C., a Type V adsorption/desorption isotherm and a bimodal pore size distribution. This clay has particular application in the catalytic hydrogenation of an unsaturated edible oil wherein an edible oil is contacted with catalytically effective amount of the clay.
摘要翻译： 本发明涉及一种镍柱状中间层间粘土，其特征在于温度程序还原最大值小于500℃，V型吸附/解吸附等温线和双峰孔径分布。 该粘土特别适用于不饱和食用油的催化加氢，其中食用油与催化有效量的粘土接触。
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6.发明授权
公开(公告)号：US4707500A
公开(公告)日：1987-11-17
申请号：US947132
申请日：1986-12-29
IPC分类号： B01J29/035 , B01J29/86 , C07C2/08 , C07C1/04
CPC分类号： B01J29/035 , B01J29/86 , C01B35/1009
摘要： Crystalline ferroborosilicate compositions are prepared from a silica containing mixture by digesting a reaction mixture comprising a tetraalkylammonium compound, a sodium hydroxide, a boron compound, an oxide of silicon, an iron ion source, an optional chelating agent and water to provide the crystalline ferroborosilicate which is then palladium ion-exchanged. This composition may be used alone or physically mixed with a methanol catalyst. Conversion of synthesis gas, dimethylether, ethylene and methanol to low molecular hydrocarbons employing these new ferroborosilicates as catalysts is also disclosed.
摘要翻译： 通过消化包含四烷基铵化合物，氢氧化钠，硼化合物，硅氧化物，铁离子源，任选的螯合剂和水的反应混合物，由含二氧化硅的混合物制备结晶的铁硼硅酸盐组合物，以提供结晶性的硼硅酸盐， 然后进行钯离子交换。 该组合物可以单独使用或与甲醇催化剂物理混合使用。 还公开了使用这些新型的硼硅酸盐作为催化剂将合成气，二甲醚，乙烯和甲醇转化为低分子量烃。
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7.发明授权
公开(公告)号：US4670474A
公开(公告)日：1987-06-02
申请号：US750219
申请日：1985-07-01
IPC分类号： B01J29/04 , C07C1/04 , C07C1/20 , C07C29/156 , C07C29/157 , C07C29/158 , C07C45/68 , C08F10/02 , C10G3/00
CPC分类号： C07C29/156 , B01J29/04 , C01B35/1009 , C07C1/0435 , C07C1/20 , C07C29/157 , C07C29/158 , C07C45/68 , C08F10/02 , C10G3/45 , C10G3/47 , C10G3/49 , C07C2529/068 , C07C2529/072 , C07C2529/86 , C10G2300/1022 , Y02P20/52 , Y02P30/20
摘要： Crystalline palladium or platinum ferrometallosilicate compositions are prepared from a silica-containing mixture by digesting a reaction mixture comprising (a) a tetraalkylammonium compound, (b) a sodium hydroxide, (c) a titanium compound, an aluminum compound, or a manganese compound, (d) an oxide of silicon, (e) an iron ion source, (f) optionally, a chelating agent and (g) water to provide a crystalline ferrometallosilicate which is then palladium or platinum ion-exchanged. Conversion of synthesis gas to low molecular hydrocarbons with high C.sub.2 -C.sub.3 alkanes selectivity employing these new ferrometallosilicates as catalysts is also disclosed.
摘要翻译： 通过消化含有（a）四烷基铵化合物，（b）氢氧化钠，（c）钛化合物，铝化合物或锰化合物的反应混合物的反应混合物，由含二氧化硅的混合物制备结晶钯或铂硅酸钼酸盐组合物， （d）硅的氧化物，（e）铁离子源，（f）任选的螯合剂和（g）水以提供结晶的硅酸铝硅酸盐，然后进行钯或铂离子交换。 还公开了使用这些新的硫酸铁酸盐作为催化剂将合成气转化为具有高C2-C3烷烃选择性的低分子烃。
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公开(公告)号：US4499298A
公开(公告)日：1985-02-12
申请号：US105444
申请日：1979-12-20
IPC分类号： C07C67/00 , C07C69/157 , C07C67/055 , C07C69/007
CPC分类号： C07C67/035
摘要： A process is described for the preparation of aryl esters such as benzyl acetate by reacting an aryl alkyl compound such as toluene with a carboxylic acid such as acetic acid and oxygen in the presence of a catalytically effective amount of a catalyst comprising palladium metal, gold metal and a metal of Group VA of the Periodic Table of the Elements such as bismuth.
摘要翻译： 描述了通过使芳基烷基化合物如甲苯与羧酸如乙酸和氧在催化有效量的催化剂的存在下反应制备芳基酯如乙酸苄酯的方法，所述催化剂包括钯金属，金属金属 和元素周期表第VA族金属如铋。
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9.发明授权Catalytic oxidation of ethylene to mixtures of acetic acid and vinyl acetate 失效将乙烯催化氧化成乙酸和乙酸乙烯酯的混合物
公开(公告)号：US4188490A
公开(公告)日：1980-02-12
申请号：US801282
申请日：1977-05-27
IPC分类号： B01J23/60 , C07C51/25 , C07C67/055 , C07C53/08 , C07C67/00
CPC分类号： C07C51/25 , C07C67/055 , B01J23/60
摘要： Ethylene and oxygen are reacted in the presence of steam in the vapor phase within the temperature range of from about 150.degree. C. to about 250.degree. C. in contact with a catalytically effective amount of palladium metal on a zinc oxide support in the presence of a sulfur modifier to provide mixtures of acetic acid and vinyl acetate.
摘要翻译： 乙烯和氧气在汽相存在下在约150℃至约250℃的温度范围内与催化有效量的钯金属在氧化锌载体上接触，在存在下在 硫改性剂以提供乙酸和乙酸乙烯酯的混合物。
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公开(公告)号：US3970697A
公开(公告)日：1976-07-20
申请号：US485046
申请日：1974-07-01
IPC分类号： B01J23/00 , B01J23/44 , B01J23/52 , B01J23/68 , B01J37/20 , C07B61/00 , C07C45/00 , C07C47/07 , C07C51/00 , C07C51/25 , C07C53/08 , C07C67/00 , C07C51/32
摘要： A process for the selective production of acetic acid from ethylene with co-production in minor amounts of carbon oxides, by reaction of ethylene and oxygen in the presence of water and a catalyst composition contaning a catalytically effective amount of palladium metal and a sulfur modifier.
摘要翻译： 通过乙烯和氧在水的存在下的反应和催化有效量的钯金属和硫改性剂的催化剂组合物，在少量的碳氧化物中共同生产乙烯选择性生产乙酸的方法。
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