公开(公告)号：US20190270687A1

公开(公告)日：2019-09-05

申请号：US16347858

申请日：2017-11-06

申请人： TOTAL RESEARCH & TECHNOLOGY FELUY ,  IFP Energies Nouvelles

发明人： Sylvie MAURY ,  Vincent COUPARD ,  Thibault HEINZ ,  Guillaume DUPLAN ,  Joseph LOPEZ ,  Nikolai NESTERENKO

IPC分类号： C07C5/27 ,  C07C1/24 ,  C07C11/09 ,  B01J29/65

摘要： A process for the isomerizing dehydration of a feedstock including a primary monoalcohol, alone or as a mixture, of formula R—CH2—OH, wherein R is a nonlinear alkyl radical of general formula CnH2n+1 where n is an integer between 3 and 20, the process taking place in the gas phase at a weighted average temperature between 275° C. and 400° C., at a pressure between 0.3 MPa and 1 MPa and at a WWH (weight per weight per hour) between 5 and 10 h−1, in the presence of a catalyst containing at least one silicic binder and at least one zeolite having at least one series of channels, the opening of which is defined by a ring of 8 oxygen atoms (8MR), process wherein vaporized feedstock entering the reactor has a weight content of water of from 4% to 35%.

公开(公告)号：US20180353941A1

公开(公告)日：2018-12-13

申请号：US16006065

申请日：2018-06-12

申请人： AXENS ,  IFP Energies nouvelles

发明人： Delphine BAZER-BACHI ,  David CHICHE ,  Joseph LOPEZ ,  Thomas SERRES ,  Tom FRISING ,  Olivier DUCREUX ,  Patrick EUZEN

IPC分类号： B01J23/72 ,  C07C29/154 ,  C10L3/10 ,  C10G25/00 ,  B01J21/16 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C01B3/16 ,  B01D15/08 ,  B01D53/02

CPC分类号： B01J23/72 ,  B01D15/08 ,  B01D53/02 ,  B01D53/04 ,  B01D53/48 ,  B01D2253/112 ,  B01D2253/1124 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/502 ,  B01D2257/553 ,  B01D2257/602 ,  B01D2258/05 ,  B01J21/16 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/04 ,  B01J37/088 ,  C01B3/16 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/1076 ,  C04B35/45 ,  C04B35/6303 ,  C04B35/632 ,  C04B2235/3217 ,  C04B2235/3418 ,  C04B2235/349 ,  C04B2235/442 ,  C04B2235/5436 ,  C04B2235/5472 ,  C04B2235/6021 ,  C07C29/154 ,  C10G25/003 ,  C10G2300/202 ,  C10G2300/207 ,  C10L3/103 ,  C10L2290/542

摘要： The invention relates to a method for preparing a solid comprising a step of mixing a set of compounds comprising at least two Cu2(OH)2CO3 powders of different particle sizes and at least one binder and the use of the solid prepared by means of this method.

公开(公告)号：US20210078919A1

公开(公告)日：2021-03-18

申请号：US17050155

申请日：2019-04-04

申请人： IFP Energies nouvelles ,  TOTAL RESEARCH & TECHNOLOGY FELUY

发明人： Sylvie MAURY ,  Vincent COUPARD ,  Delphine BAZER-BACHI ,  Joseph LOPEZ ,  Nikolai NESTERENKO ,  Guillaume DUPLAN ,  Colin DUPONT

IPC分类号： C07C1/24 ,  C07C5/27 ,  B01J21/08 ,  B01J35/10 ,  B01J35/02 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J29/65 ,  B01J37/00

摘要： A method for isomeris ng dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume Vμ, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.

公开(公告)号：US20180353929A1

公开(公告)日：2018-12-13

申请号：US16005907

申请日：2018-06-12

申请人： AXENS ,  IFP Energies Nouvelles

发明人： Delphine BAZER-BACHI ,  David CHICHE ,  Joseph LOPEZ ,  Thomas SERRES ,  Tom FRISING ,  Olivier DUCREUX ,  Patrick EUZEN

IPC分类号： B01J20/02 ,  B01J20/06 ,  B01J20/30 ,  B01D53/52

CPC分类号： B01J20/0237 ,  B01D53/02 ,  B01D53/48 ,  B01D53/52 ,  B01D2253/112 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/502 ,  B01D2257/553 ,  B01D2258/05 ,  B01J20/0277 ,  B01J20/06 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3042 ,  B01J20/3078 ,  B01J20/3085 ,  B01J2220/42

摘要： The invention relates to a method for preparing a solid comprising the mixture of a set of compounds comprising at least one Cu2(OH)2CO3 powder, one metal oxide powder selected from the group of metals consisting of copper, zinc, iron, manganese and mixtures thereof, and at least one binder as well as the use of the solid prepared by means of this method.

公开(公告)号：US20160325269A1

公开(公告)日：2016-11-10

申请号：US15148109

申请日：2016-05-06

申请人： IFP Energies Nouvelles

发明人： Delphine BAZER-BACHI ,  Christine DALMAZZONE ,  Aurelie DANDEU ,  Fabrice DIEHL ,  Vincent LE CORRE ,  Joseph LOPEZ ,  Anne Lise TALEB

IPC分类号： B01J21/04 ,  C01B3/40 ,  B01J23/42 ,  C01F7/02 ,  C01F7/24

CPC分类号： B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J27/135 ,  B01J32/00 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/0072 ,  C01B3/40 ,  C01B3/42 ,  C01B2203/0227 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1247 ,  C01B2203/148 ,  C01F7/02 ,  C01F7/24 ,  C01F7/447 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/60 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  Y02P20/52

摘要： The present invention concerns spheroidal alumina particles characterized by a BET specific surface area in the range 150 to 300 m2/g, a mean particle diameter in the range 1.2 to 3 mm and a particle diameter dispersion, expressed as the standard deviation, not exceeding 0.1, a total pore volume, measured by mercury porosimetry, in the range 0.50 to 0.85 mL/g, a degree of macroporosity within a particle of less than 30%, and in which the dispersion of the diameters of the macropores, expressed as the ratio D90/D50, does not exceed 8.The invention also concerns processes for the preparation of said particles as well as catalysts comprising said particles as a support, and their use in catalytic hydrocarbon treatment processes, in particular in a catalytic reforming process.

摘要翻译： 本发明还涉及制备所述颗粒的方法以及包含作为载体的所述颗粒的催化剂，以及它们在催化烃处理方法中的用途，特别是在催化重整过程中。

公开(公告)号：US20240050922A1

公开(公告)日：2024-02-15

申请号：US18267965

申请日：2021-12-09

申请人： IFP ENERGIES NOUVELLES

发明人： Nicolas LEGAGNEUX ,  Marie-Claire MARION ,  Karin BARTHELET ,  Patrick EUZEN ,  Joseph LOPEZ

IPC分类号： B01J20/08 ,  B01J20/32 ,  B01J20/28 ,  C10G25/05

CPC分类号： B01J20/08 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/28011 ,  B01J20/28061 ,  B01J20/28083 ,  B01J20/2809 ,  C10G25/05 ,  C10G2300/104 ,  C10G2400/02 ,  C10G2300/202

摘要： The present invention relates to a mass for trapping silicon compounds, comprising a porous alumina-based support and at least one metal chosen from the metals from groups VIB and VIIIB, and exhibiting a grain density of at least 1.20 g/ml, a specific surface of at least 300 m2/g and pores with a mean size of less than 6.5 nm, as determined by mercury porosimetry. The present invention also relates to a process for the preparation of said trapping mass and to a trapping process using said trapping mass.

公开(公告)号：US20140364672A1

公开(公告)日：2014-12-11

申请号：US14296490

申请日：2014-06-05

申请人： IFP ENERGIES NOUVELLES

发明人： Emmanuelle BRACCO ,  Delphine MARTI ,  Elsa JOLIMAITRE ,  Delphine BAZER-BACHI ,  Joseph LOPEZ

IPC分类号： B01J20/30 ,  C07C7/12 ,  B01J20/12

CPC分类号： B01J20/3078 ,  B01D53/02 ,  B01D2253/1085 ,  B01D2253/11 ,  B01D2256/24 ,  B01J20/12 ,  B01J20/183 ,  B01J20/186 ,  B01J20/2803 ,  B01J20/3007 ,  C10G25/03 ,  C10G25/05

摘要： The present invention concerns an adsorbent comprising at least one zeolite selected from a zeolite of the 12 MR, 10 MR and 8 MR type and at least one binder comprising a clay with a Si/Al weight ratio of more than 2. It also concerns its preparation process and its use in a process for purifying a hydrocarbon feed comprising unsaturated molecules and at least one impurity comprising at least one heteroatom of the O, S or N type.

摘要翻译： 本发明涉及一种吸附剂，其包含至少一种选自12MMR，10MR和8MR型沸石的沸石和至少一种含Si / Al重量比大于2的粘土的粘合剂。它还涉及其 制备方法及其在纯化包含不饱和分子和至少一种包含至少一个O，S或N型杂原子的杂质的烃进料的方法中的应用。

公开(公告)号：US20130324624A1

公开(公告)日：2013-12-05

申请号：US13905575

申请日：2013-05-30

申请人： IFP Energies nouvelles

发明人： Sylvie MAURY ,  Fabrice DIEHL ,  Adrien BERLIET ,  Joseph LOPEZ

IPC分类号： B01J23/75 ,  C10G2/00

CPC分类号： B01J23/75 ,  B01J21/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/005 ,  B01J23/462 ,  B01J23/74 ,  B01J23/745 ,  B01J23/755 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/088 ,  B01J37/18 ,  C10G2/332 ,  C10G2/333

摘要： Preparation of a catalyst comprising at least one metal from group VIII said process comprising stabilization of an oxide support, by impregnation of said oxide support, rapid drying, calcination of impregnated and dried oxide support, stabilization stage being followed at least once by impregnation of stabilized oxide support, drying of stabilized and impregnated oxide support operating in a fluidized bed in the presence of a gas, said support being subjected to a temperature rise ramp of between 0.5 and 5° C./min to attain a temperature of between 50 and 170° C., the residence time of said support once the drying temperature is reached being between 20 and 180 min, and calcination of said dried impregnated stabilized oxide support.

摘要翻译： 制备包含至少一种第VIII族金属的催化剂，所述方法包括通过浸渍所述氧化物载体来稳定氧化物载体，快速干燥，浸渍和干燥的氧化物载体的煅烧，稳定阶段至少一次通过浸渍稳定化的 氧化物载体，在气体存在下在流化床中操作的稳定和浸渍的氧化物载体的干燥，所述载体经受0.5-5℃/分钟的升温斜率以达到50至170℃的温度 一旦达到干燥温度，所述载体的停留时间为20至180分钟，并煅烧所述干燥的浸渍的稳定的氧化物载体。

公开(公告)号：US20130324623A1

公开(公告)日：2013-12-05

申请号：US13903010

申请日：2013-05-28

申请人： IFP Energies nouvelles ,  ENI S.p.A.

发明人： Sylvie MAURY ,  Fabrice DIEHL ,  Adrien BERLIET ,  Joseph LOPEZ

IPC分类号： B01J23/75 ,  C10G2/00

CPC分类号： B01J23/75 ,  B01J21/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/005 ,  B01J23/462 ,  B01J23/74 ,  B01J23/745 ,  B01J23/755 ,  B01J35/002 ,  B01J35/0053 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/18 ,  C10G2/332 ,  C10G2/333

摘要： The present invention concerns a process for the preparation of a catalyst comprising an active phase comprising at least one metal from group VIII selected from cobalt, nickel, ruthenium and iron, alone or as a mixture, and an oxide support which can be used in a Fischer-Tropsch synthesis process comprises at least once the linked sequence of a stage for impregnation of said oxide support, a drying stage in which said impregnated oxide support is entrained by means of a gas, said impregnated oxide support being subjected in said stage to a temperature rise ramp of between 250 and 600° C./min, the residence time of said impregnated oxide support in said drying stage being between 1 second and 1 minute, and a stage for calcination of said dried impregnated oxide support. The invention also concerns a Fischer-Tropsch synthesis process using the catalyst prepared according to the preparation process.

摘要翻译： 本发明涉及一种制备催化剂的方法，该催化剂包含活性相，该活性相包含选自钴，镍，钌和铁中的至少一种金属，单独或作为混合物，以及氧化物载体，其可用于 费 - 托合成方法包括至少一次用于浸渍所述氧化物载体的阶段的连接序列，其中所述浸渍的氧化物载体通过气体夹带的干燥阶段，所述浸渍的氧化物载体在所述阶段中经历 温度上升斜率为250-600℃/ min，所述浸渍的氧化物载体在所述干燥阶段的停留时间为1秒至1分钟，以及煅烧所述干燥的浸渍氧化物载体的阶段。 本发明还涉及使用根据制备方法制备的催化剂的费 - 托合成方法。