Abstract:
Process for producing a light gasoline having a sulfur content of less than 10 ppm by weight, with respect to the total weight of the light gasoline, starting from a gasoline containing sulfur compounds, olefins and diolefins, which process includes a) a stage of selective hydrogenation to hydrogenate the diolefins and a reaction for increasing the molecular weight of a part of the sulfur compounds; b) a stage separating the effluent obtained from stage a) into a gaseous fraction, a light gasoline cut and a heavy gasoline cut, stage b) being carried out in a fractionation column containing n plates, n being an integer of 20 or more, the first plate being the reboiler and the plate “n” being the condenser, wherein the light gasoline cut is withdrawn from the fractionation column at the plate “n-i”, with i being 1 to 10.
Abstract:
The present invention relates to a process for trapping silicon compounds in a gaseous or liquid feedstock, comprising bringing the feedstock into contact with a trapping mass with a liquid hourly space velocity LHSV of less than 5 h−1 or a gas hourly space velocity GHSV of less than 500 h−1.
Abstract:
A process for treating a gasoline containing sulfur compounds, olefins and diolefins comprises step a) bringing into contact the gasoline, hydrogen and a hydrodesulfurization catalyst, in at least one reactor. In step b) effluent from a), hydrogen, and a hydrodesulfurization catalyst are brought into contact in at least one reactor. In step c) effluent from b) is sent to a separation drum operating at a pressure of between 1.0 and 2.0 MPa to obtain a gaseous fraction containing H2S and hydrogen and a liquid fraction containing desulfurized gasoline and a fraction of dissolved H2S. In step d), the liquid fraction is sent to a stabilization column to obtain at the top a stream comprising residual H2S and C4- hydrocarbon compounds and at the bottom a stabilized gasoline. In step e), the gaseous fraction is recycled at least in part to at least one of steps a) and/or b).
Abstract:
The present invention relates to a mass for trapping silicon compounds, comprising a porous alumina-based support and at least one metal chosen from the metals from groups VIB and VIIIB, and exhibiting a grain density of at least 1.20 g/ml, a specific surface of at least 300 m2/g and pores with a mean size of less than 6.5 nm, as determined by mercury porosimetry. The present invention also relates to a process for the preparation of said trapping mass and to a trapping process using said trapping mass.
Abstract:
The invention concerns a process for eliminating arsenic from a hydrocarbon feed which is at least partially liquid, comprising at least the following steps: a) bringing the hydrocarbon feed and hydrogen into contact with a first capture mass comprising a support and at least one metal M1 from group VIB and at least two metals M2 and M3 from group VIII; b) bringing the hydrocarbon feed and hydrogen into contact with a second capture mass in the sulphide form comprising a support and nickel, the quantity of nickel being at least 5% by weight of NiO with respect to the total weight of the second capture mass, in which step a) is either carried out before step b) or carried out simultaneously with step b).
Abstract:
A method for continuous production of hydrocarbons from synthesis gas in the presence of a cobalt-based catalyst which comprises a step of providing synthesis gas from a source (1) of synthesis gas in a Fischer-Tropsch synthesis reactor (4). The method also includes the following steps: a) conditioning of the catalyst in reduced state in a conditioning reactor (2) by contact with a flow of reducing gas from a synthesis gas source supplying the synthesis reactor, the reducing conditioning gas comprising carbon monoxide (CO) or a mixture comprising hydrogen (H2) and carbon monoxide (CO), the H2/CO molar ratio of which is between 0.1 and 0.9, at a temperature between 200 and 500° C., and a total pressure between 0.1 and 5 MPa and under a gas flow between 1 and 20 NI/h/g of catalyst to be treated, b) supply of reduced catalyst conditioned in step a) to the synthesis reactor (4).