公开(公告)号：US10364201B2

公开(公告)日：2019-07-30

申请号：US15076191

申请日：2016-03-21

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Stephen A. Cottrell ,  John J. Senetar ,  Hsueh S. Tung ,  Daniel C. Merkel ,  Yuon Chiu ,  Haluk Kopkalli

IPC分类号： C07C17/354 ,  C07C19/08 ,  C07C17/38 ,  C07C17/383 ,  C07C17/25

摘要： In certain aspects, the present invention relates to methods for increasing the cost efficiency and safety of the hydrogenation of a fluorinated olefin by controlling the reaction conditions and parameters. In further aspects, the hydrogenation reaction is provided in a two stage reaction wherein the reactant amounts, temperature and other parameters are controlled such that the conversion percentage, selectivity, and reaction parameters are all within commercially acceptable levels.

公开(公告)号：US20170247304A1

公开(公告)日：2017-08-31

申请号：US15587824

申请日：2017-05-05

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C5/22 ,  C07B35/08 ,  C07C21/18 ,  C07C17/007

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US09586071B2

公开(公告)日：2017-03-07

申请号：US14643500

申请日：2015-03-10

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Robert C. Johnson ,  Hsueh S. Tung ,  Rajiv R. Singh ,  Ian Shankland

IPC分类号： C09K5/04 ,  A62D1/06 ,  C11D3/43 ,  C11D7/50 ,  C11D11/00 ,  G03F7/42 ,  B01F17/00 ,  C09K3/00 ,  C09K21/08 ,  C23G5/028 ,  C11D7/30 ,  C08J9/14 ,  H05K3/26

CPC分类号： C09K5/044 ,  A62D1/06 ,  B01F17/0035 ,  C08J9/144 ,  C09K3/00 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/102 ,  C09K2205/104 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/126 ,  C10M101/02 ,  C10M171/008 ,  C10M2203/003 ,  C10N2220/302 ,  C10N2240/30 ,  C11D3/43 ,  C11D7/30 ,  C11D7/5018 ,  C11D11/0047 ,  C23G5/02809 ,  C23G5/02825 ,  F25B1/00 ,  F25B31/002 ,  G03F7/426 ,  H05K3/26 ,  Y02C20/30

摘要： Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO—HF0-1233, or HF0-1354 having properties highly beneficial in foaming and blowing agent applications, articles and methods.

摘要翻译： 基于使用含有3至4个碳原子的氟代烯烃和至少一个碳 - 碳双键的组合物和方法，例如HFO-1214，HFO-HF0-1233或HF0-1354，其具有在发泡和吹塑中非常有益的性质 代理申请，文章和方法。

公开(公告)号：US20150105595A1

公开(公告)日：2015-04-16

申请号：US14570283

申请日：2014-12-15

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/06

CPC分类号： C07C17/206 ,  C07C17/06 ,  C07C17/087 ,  C07C17/20 ,  C07C17/25 ,  C07C17/42 ,  C07C21/18

摘要： The present invention relates to an improved method for manufacturing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) by reacting 1,1,2,3-tetrachloropropene, 1,1,1,2,3-pentachloropropane, and/or 2,3,3,3-tetrachloropropene with hydrogen fluoride, in a vapor phase reaction vessel in the presence of a vapor phase fluorination catalyst and stabilizer. HCFC-1233xf is an intermediate in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf) which is a refrigerant with low global warming potential.

摘要翻译： 本发明涉及一种通过使1,1,2,3-四氯丙烯，1,1,1,2,3-五氯丙烷与1,1,3,3-四氯丙烯反应制备2-氯-3,3,3-三氟丙烯（HCFC-1233xf）的改进方法 ，和/或2,3,3,3-四氯丙烯与氟化氢在气相反应容器中在气相氟化催化剂和稳定剂存在下反应。 HCFC-1233xf是生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体，它是具有低全球变暖潜能的制冷剂。

公开(公告)号：US20150005536A1

公开(公告)日：2015-01-01

申请号：US14377727

申请日：2013-02-08

申请人： Honeywell International, Inc.

发明人： Haiyou Wang ,  Hsueh S. Tung ,  Haluk Kopkalli ,  Yuon Chiu ,  Gustavo Cerri ,  Jeffrey Ball ,  Philip L. Da Prato ,  Xuehui Sun ,  Mario Joseph Nappa

IPC分类号： C07C17/395 ,  C07C17/23

CPC分类号： C07C17/395 ,  B01J27/08 ,  C07C17/06 ,  C07C17/087 ,  C07C17/23 ,  C07C17/25 ,  C07C17/386 ,  C07C17/389 ,  Y02P20/582 ,  C07C19/10 ,  C07C21/18

摘要： A method for forming 2,3,3,3-tetrafluoropropene (HFO-1234yf) comprising providing a dehydrochlorination starting material having relatively low concentrations of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), especially and preferable less than about 8.0% when the dehydrochlorination reaction utilizes no substantial amount of catalyst or catalyst comprising austenitic nickel-based materials.

摘要翻译： 一种形成2,3,3,3-四氟丙烯（HFO-1234yf）的方法，包括提供具有较低浓度的2-氯-3,3,3-三氟丙烯（HCFO-1233xf）的脱氯化氢原料，特别优选较少 当脱氯化氢反应不使用显着量的包含奥氏体镍基材料的催化剂或催化剂时，约为8.0％。

公开(公告)号：US09994504B2

公开(公告)日：2018-06-12

申请号：US15587824

申请日：2017-05-05

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C21/18 ,  C07C17/007 ,  C07B35/08 ,  C07C5/22

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US20170166500A1

公开(公告)日：2017-06-15

申请号：US15445407

申请日：2017-02-28

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Daniel C. Merkel ,  Konstantin A. Pokrovski ,  Hsueh S. Tung ,  Haiyou Wang

IPC分类号： C07C17/395 ,  B01J19/12 ,  B01J27/138 ,  B01J23/44 ,  C07C17/383 ,  C07C17/25

CPC分类号： C07C17/395 ,  B01D3/009 ,  B01D3/10 ,  B01D11/04 ,  B01J19/123 ,  B01J23/44 ,  B01J27/10 ,  B01J27/138 ,  B01J2219/1203 ,  C07C17/25 ,  C07C17/383 ,  C07C21/18 ,  Y02P20/582 ,  C07C19/10

摘要： The instant invention relates to a process and method for manufacturing 2,3,3,3-tetrafluoropropene by dehydrohalogenating a reactant stream of 2-chloro-1,1,1,2-tetrafluoropropane that is substantially free from impurities, particularly halogenated propanes, propenes, and propynes.

公开(公告)号：US09650320B2

公开(公告)日：2017-05-16

申请号：US14886628

申请日：2015-10-19

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US20170073558A1

公开(公告)日：2017-03-16

申请号：US15355649

申请日：2016-11-18

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Robert C. Johnson ,  Hsueh S. Tung ,  Rajiv R. Singh ,  Ian Shankland

IPC分类号： C09K5/04 ,  C23G5/028 ,  F25B1/00 ,  F25B31/00 ,  C10M101/02 ,  C10M171/00

CPC分类号： C09K5/044 ,  A62D1/06 ,  B01F17/0035 ,  C08J9/144 ,  C09K3/00 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/102 ,  C09K2205/104 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/126 ,  C10M101/02 ,  C10M171/008 ,  C10M2203/003 ,  C10N2220/302 ,  C10N2240/30 ,  C11D3/43 ,  C11D7/30 ,  C11D7/5018 ,  C11D11/0047 ,  C23G5/02809 ,  C23G5/02825 ,  F25B1/00 ,  F25B31/002 ,  G03F7/426 ,  H05K3/26 ,  Y02C20/30

摘要： Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO-HF0-1233, or HF0-1354 having properties highly beneficial in foaming and blowing agent applications, articles and methods.

摘要翻译： 基于使用含有3至4个碳原子的氟代烯烃和至少一个碳 - 碳双键的组合物和方法，例如HFO-1214，HFO-HF0-1233或HF0-1354，其具有在发泡和吹塑中非常有益的性质 代理申请，文章和方法。

公开(公告)号：US20160039729A1

公开(公告)日：2016-02-11

申请号：US14822497

申请日：2015-08-10

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Hsueh S. Tung ,  Sudip Mukhopadhyay ,  Michael Van Der Puy ,  Daniel C. Merkel ,  Jing Ji Ma ,  Cheryl L. Bortz ,  Barbara A. Light ,  Steven D. Phillips ,  Kim M. Fleming ,  Susan A. Ferguson

IPC分类号： C07C17/23 ,  C07C17/20

CPC分类号： C07C17/23 ,  C07C17/087 ,  C07C17/10 ,  C07C17/206 ,  C07C17/21 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C21/18

摘要： Disclosed is a process for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of Formula (I): C(X)3CF2C(X)3  (I) to at least one compound of Formula (II) CF3CF═CHZ  (II) where each X and Z is independently H, F, Cl, I or Br, said process preferably not including any substantial amount of oxygen-containing catalyst in certain embodiments.Preferably Z is H.

摘要翻译： 公开了一种制备氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：C（X）3CF 2 C（X）3（I）转化为至少一种式（II）化合物CF 3 CF ≡CHZ（II）其中每个X和Z独立地为H，F，Cl，I或Br，在某些实施方案中，所述方法优选不包括任何显着量的含氧催化剂。 Z优选为