摘要:
An exhaust gas purifying system (100) includes: a NOx purifying catalyst (34) that is disposed in an exhaust gas flow path (3) to purify nitrogen oxide; and an HC generator (33, 133) that is disposed upstream of the NOx purifying catalyst (34) in the exhaust gas flow path (3) to generate at least one of acetylene, a hydrocarbon with a carbon number of 2 to 5 other than acetylene, and an aromatic hydrocarbon from a hydrocarbon contained in an exhaust gas. In addition, an exhaust gas purifying method using the exhaust gas purifying system includes the step of adjusting an oxygen concentration in the exhaust gas supplied to the HC generation catalyst (33A, 133A) to 0.8 to 1.5 vol % when an air-fuel ratio is stoichiometric or rich.
摘要:
An exhaust gas purifying method for a fuel cell vehicle comprises preparing an exhaust gas purifying system for the fuel cell vehicle, the exhaust gas purifying system including a methane removal catalyst for accelerating the conversion of methane into hydrogen and carbon monoxide. The methane removal catalyst comprises a catalytic ingredient including at least one of rhodium, platinum and palladium.
摘要:
An exhaust gas purifying system for an internal combustion engine mounted on an automotive vehicle. The exhaust gas purifying system includes an exhaust gas component concentration regulating device disposed in an exhaust gas passageway of the engine, for regulating concentrations of gas components in exhaust gas discharged from the engine such that the concentrations of carbon monoxide and hydrogen are respectively not more than 2.0% by volume and not less than 0.5% by volume and such that a volume concentration ratio of [hydrogen/carbon monoxide] is not smaller than 0.5, in rich and stoichiometric conditions of exhaust gas. Additionally, a NOx adsorbing and reducing catalyst is disposed in the exhaust gas passageway downstream of the exhaust gas component concentration regulating device, for adsorbing nitrogen oxides in a lean condition of the exhaust gas and reducing the nitrogen oxides into nitrogen in the rich and stoichiometric conditions.
摘要:
A catalyst for removing nitrogen oxides contained in exhaust gases, particularly those containing vapor-form catalyst poisons, by catalytic reduction with ammonia, while retaining a high denitration performance for a long time, which catalyst comprises titanium oxide as a first component, molybdenum oxide and/or tungsten oxide as a second component and vanadium oxide and/or sulfate as a third component, the atomic ratio of the respective elements being Ti:Mo and/or W:V=80-96.6:3-15:0.5-5, and the size of the crystallite of the titanium oxide according to Sherrer's equation being in the range of 185 .ANG. to 300 .ANG. in the direction of a plane (101) (interplanar spacing: d=3.52 .ANG.).
摘要:
A fuel vapor treatment or recovery system for an automotive internal combustion engine. The system comprises a canister containing a fuel vapor adsorbing material. A membrane separation module is provided to be connected to the canister and including a separation membrane for separating a mixture gas into an air-rich component and a fuel vapor-rich component. The separation membrane has an air-selective permeability so that the air-rich component is be able to pass through the separation membrane, the mixture gas containing air and fuel vapor. Additionally, a gas transporting device is provided to be connected to the canister, for causing purge gas to be introduced into the canister to purge fuel vapor from the fuel vapor adsorbing material and causing fuel vapor purged from the canister to be fed to the membrane separation module. Here, the fuel vapor-rich component is fed to an intake air passageway of an engine so that vacuum generated by the engine acts on the separation membrane so as to serve as a driving force for membrane separation. Further, the air-rich component from the membrane separation module is returned to the fuel tank so that fuel vapor component contained in the fuel vapor-rich component is recovered to the fuel tank upon being subjected to at least one of liquefaction and absorption to liquid fuel in the fuel tank.
摘要:
A nitrogen oxide absorbing material (38) which absorbs nitrogen oxide when the reduction component concentration of exhaust gas in the exhaust passage (31) of an engine (1) is lower than a predetermined concentration, and discharges nitrogen oxide when the reduction component concentration of exhaust gas in the exhaust passage (31) of the engine (1) is higher than the predetermined concentration, and a catalyst (38) which promotes reduction of the discharged nitrogen oxides by a reduction component are provided. A controller (40) first reduces the reduction component concentration of the exhaust gas over a first predetermined time period by, for example, advancing the fuel injection timing. The controller (40) then increases the reduction component concentration of the exhaust gas over a second predetermined time period by, for example, retarding the fuel injection timing.
摘要:
A catalyst for the purification of exhaust gas comprises a first coat layer of a palladium-carried activated alumina containing Ce, Zr and La formed on a honeycomb carrier, a second coat layer of an activated alumina containing Ce, Zr and La formed on the first coat layer, and a third coat layer of copper ion-exchanged zeolite powder formed on the second coat layer and efficiently purifies NOx, HC and CO in the exhaust gas under conditions from theoretical air-fuel ratio to excessive oxygen atmosphere.
摘要:
A catalyst for removing nitrogen oxides whose activity deterioration due to volatile poisons contained in exhaust gases is prevented and which has a superior endurance, and a process for producing the catalyst are provided, which catalyst comprises a titania having a surface area of 20 m.sup.2 /g or less and a zeolite having 0.01 to 20% by weight of copper supported thereon; having an average pore diameter of 10 .ANG. or less; and having a silica/alumina molar ratio of 10 or more, and which process comprises mixing powder of the zeolite with the titania or its precursor, followed by molding the mixture into a predetermined shape, followed by calcining the resulting material at 800.degree. C. or higher.
摘要:
A particulate matter purifying material is used for a filter catalyst for purifying particulate matter that is disposed in an exhaust gas flow path of an internal combustion engine, traps the particulate matter in exhaust gas generated in the internal combustion engine, and burns the particulate matter to be deposited, so as to be regenerated. The particulate matter purifying material includes an oxide containing cerium (Ce) having an oxygen storage-release capacity, and at least one metal (Me) selected from the group consisting of Zr, Y, La, Pr, Sr, Nb and Nd, wherein a content ratio (Ce:Me) of cerium to the metal is 6:4 to 9:1 in terms of an atomic ratio, and a degree of crystallinity (CR) represented by the following formula (1) is within a range of 25 to 60%: Degree of crystallinity(CR)=I/I0×100(%) (1) wherein I represents an X-ray diffraction peak intensity with regard to a (111) plane of a CeO2 phase in the particulate matter purifying material, and I0 represents the X-ray diffraction peak intensity with regard to the (111) plane of the CeO2 phase after the particulate matter purifying material is baked in air at 1000° C.
摘要:
An exhaust gas purifying system (100) includes: a NOx purifying catalyst (34) that is disposed in an exhaust gas flow path (3) to purify nitrogen oxide; and an HC generator (33, 133) that is disposed upstream of the NOx purifying catalyst (34) in the exhaust gas flow path (3) to generate at least one of acetylene, a hydrocarbon with a carbon number of 2 to 5 other than acetylene, and an aromatic hydrocarbon from a hydrocarbon contained in an exhaust gas. In addition, an exhaust gas purifying method using the exhaust gas purifying system includes the step of adjusting an oxygen concentration in the exhaust gas supplied to the HC generation catalyst (33A, 133A) to 0.8 to 1.5 vol % when an air-fuel ratio is stoichiometric or rich.