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18 条记录 (耗时 0.02 秒)

    Process for selectively producing para-substituted derivatives of phenols
    2.
    发明授权
    Process for selectively producing para-substituted derivatives of phenols 失效
    选择性生产酚取代对位取代基的方法

    公开(公告)号：US4523037A

    公开(公告)日：1985-06-11

    申请号：US530157

    申请日：1983-09-07

    申请人： Hidefumi Hirai ,  Makoto Komiyama

    发明人： Hidefumi Hirai ,  Makoto Komiyama

    IPC分类号： C07C37/18 ,  C07C39/19 ,  C07C41/16 ,  C07C43/215 ,  C07C45/00 ,  C07C45/51 ,  C07C5/393

    CPC分类号： C07C45/008 ,  C07C45/512

    摘要： By reacting, using as a catalyst a modified or unmodified cyclodextrin, a phenol compound with a haloform in the presence of an alkali metal hydroxide, while maintaining the molar ratio of the cyclodextrin to the haloform at 0.5 to 10, a substituent group derived from the haloform can be introduced to the para-position of the phenol compound with high selectivity, whereby useful para-substituted phenol derivatives can be advantageously obtained.

    摘要翻译： 通过在碱金属氢氧化物存在下使用改性或未改性的环糊精作为催化剂与卤代甲酰胺反应，同时将环糊精与卤素的摩尔比保持在0.5至10，将衍生自 可以高选择性地将卤代甲酚引入酚化合物的对位，由此可以有利地获得有用的对位取代的苯酚衍生物。

    Process for separating carbon monoxide from a gas mixture
    4.
    发明授权
    Process for separating carbon monoxide from a gas mixture 失效
    从气体混合物中分离一氧化碳的方法

    公开(公告)号：US4460384A

    公开(公告)日：1984-07-17

    申请号：US373241

    申请日：1982-04-29

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    IPC分类号： B01D53/14 ,  C01B32/40 ,  B01D19/00

    CPC分类号： C01B31/18 ,  B01D53/1493

    摘要： A process for separating carbon monoxide from a gas mixture is presented. In this process carbon monoxide contained in the gas mixture containing carbon monoxide and up to approximately 40,000 ppm of water can be effectively separated by contacting the gas mixture with an absorbing solution containing (a) at least one copper(I) halide, (b) at least one aluminum(III) halide and (c) at least one compound having at least two benzene nuclei in one molecule thereof. The component (c) is selected from the group consisting of (A) the compounds having the general formula (I): ##STR1## wherein R.sub.1 is hydrogen or an alkyl group, R.sub.2 and R.sub.3 are independently hydrogen, an alkyl group, or an aryl group, i is 0, 1, 2, 3, or 4, and m and n are independently 0, 1, 2, or 3, (B) the oligomers styrene or the derivatives thereof, (C) the polymers of styrene or the derivatives thereof and (D) copolymers of (i) styrene or the derivatives thereof and (ii) ethylene or the derivatives thereof and, optionally, an aromatic solvent, without causing the decrease in the carbon monoxide absorbing and releasing capacities of the absorbing solution.

    摘要翻译： 提出了从气体混合物中分离一氧化碳的方法。 在该方法中，通过使气体混合物与含有（a）至少一种卤化铜（I）的吸收溶液接触，（b）将含有一氧化碳和高达约40,000ppm水的气体混合物中所含的一氧化碳， 至少一种卤化铝（III）和（c）至少一种在其一个分子中具有至少两个苯核的化合物。 组分（c）选自（A）具有通式（I）的化合物：其中R 1是氢或烷基，R 2和R 3独立地是氢，烷基 ，或芳基，i为0,1,2,3或4，m和n分别为0,1,2或3，（B）低聚物苯乙烯或其衍生物，（C）聚合物 的苯乙烯或其衍生物，和（D）（i）苯乙烯或其衍生物和（ii）乙烯或其衍生物和任选的芳族溶剂的共聚物，而不会导致一氧化碳吸收和释放能力的降低 吸收溶液。

    Method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound
    5.
    发明授权
    Method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound 失效
    制备金属和/或金属化合物颗粒的非水分散体的方法

    公开(公告)号：US6051614A

    公开(公告)日：2000-04-18

    申请号：US997169

    申请日：1992-12-28

    申请人： Hidefumi Hirai ,  Hyoya Shiozaki ,  Hotaka Aizawa

    发明人： Hidefumi Hirai ,  Hyoya Shiozaki ,  Hotaka Aizawa

    IPC分类号： B01J37/03 ,  H01B1/20 ,  H01B1/22 ,  B01D12/00 ,  B01F3/00

    CPC分类号： B01J37/038 ,  H01B1/20 ,  H01B1/22

    摘要： Disclosed is a method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound, which comprises contacting an aqueous dispersion of particles of a metal and/or a metal compound with a water-immiscible, non-aqueous liquid in the presence of a surfactant and in the presence or absence of a water-soluble inorganic acid salt and/or a water-soluble organic acid salt exhibiting substantially no surface activity, wherein when the contacting of the aqueous dispersion with the non-aqueous liquid is conducted in the absence of the salt, the salt is added after the contacting, thereby causing the particles to be migrated from the aqueous dispersion into the non-aqueous liquid.

    摘要翻译： 公开了一种制备金属和/或金属化合物颗粒的非水分散体的方法，其包括使金属和/或金属化合物的颗粒的水分散体与水不混溶的非水性液体 在表面活性剂的存在下，在存在或不存在表现出基本上没有表面活性的水溶性无机酸盐和/或水溶性有机酸盐的情况下，其中当水分散体与非水性液体接触时 在不存在盐的情况下进行，在接触之后加入盐，从而使颗粒从水性分散体迁移到非水性液体中。

    Solid absorbent for unsaturated hydrocarbon and process for separation of unsaturated hydrocarbon from gas mixture
    6.
    发明授权
    Solid absorbent for unsaturated hydrocarbon and process for separation of unsaturated hydrocarbon from gas mixture 失效
    不饱和烃的固体吸收剂和不饱和烃与气体混合物的分离方法

    公开(公告)号：US4747855A

    公开(公告)日：1988-05-31

    申请号：US6343

    申请日：1987-01-21

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    IPC分类号： B01J20/20 ,  C07C7/12 ,  B01D53/04

    CPC分类号： B01J20/20 ,  C07C7/12

    摘要： A solid adsorbent for an unsaturated hydrocarbon including (a) (i) a copper(I) halide or oxide or (ii) a halide, carboxylate, sulfate, basic salt, oxide, or amine complex salt of copper(II) and (b) activated carbon or graphite is described.This solid adsorbent can effectively adsorb an unsaturated hydrocarbon such as ethylene from a gas mixture by being placed in contact with the gas mixture at a temperature of -40.degree. C. to 90.degree. C. under normal pressure.

    摘要翻译： 包括（a）（i）卤化铜（I）或氧化物的铜（I）或（ii）铜（II）和（b）的卤化物，羧酸盐，硫酸盐，碱性盐，氧化物或胺络合物的固体吸附剂 ）活性炭或石墨。 这种固体吸附剂可以在常压下在-40℃至90℃的温度下与气体混合物接触，从气体混合物中有效吸附不饱和烃如乙烯。

    Process for recovery of ethylene from gaseous mixture
    8.
    发明授权
    Process for recovery of ethylene from gaseous mixture 失效
    从气体混合物中回收乙烯的方法

    公开(公告)号：US4525180A

    公开(公告)日：1985-06-25

    申请号：US590417

    申请日：1984-03-15

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    IPC分类号： C07C7/11 ,  B01D19/00

    CPC分类号： C07C7/11

    摘要： With application of new liquid absorbent, comprised of a compound selected from a group composed of silver halide and cuprous halide, an aluminium halide, a polymer selected from a group composed of styrene and styrene derivatives, and an aromatic hydrocarbon, it is possible to recover ethylene by absorbing ethylene from gaseous mixture containing ethylene such as FCC off gas, ethylene plant off gas and coke oven gas. In particular, said liquid absorbent is neither diluted nor reduced its capability to absorb ethylene by water or its vapor contained in the said gaseous mixture, so the liquid absorbent can be used repeatedly for the recovery of ethylene from gaseous mixture containing ethylene and water or its vapor, without any pretreatment to reduce the water content of said gaseous mixture.

    摘要翻译： 使用由选自卤化银和卤化亚铜组成的组中的化合物，卤化铝，选自苯乙烯和苯乙烯衍生物的组分的聚合物和芳族烃构成的新的液体吸收剂的应用，可以回收 乙烯通过从含有乙烯的气体混合物如FCC废气，乙烯装置废气和焦炉气体中吸收乙烯。 特别地，所述液体吸收剂既不稀释也不降低其吸收所述气体混合物中所含的水或其蒸汽的乙烯的能力，因此可以重复使用液体吸收剂以从含有乙烯和水的气体混合物回收乙烯或其 蒸气，没有任何预处理以减少所述气体混合物的水含量。

    Adsorbent for carbon monoxide
    9.
    发明授权
    Adsorbent for carbon monoxide 失效
    一氧化碳吸附剂

    公开(公告)号：US5922640A

    公开(公告)日：1999-07-13

    申请号：US807369

    申请日：1997-02-27

    申请人： Hidefumi Hirai ,  Nobutoshi Ootsuka ,  Kenji Sakai ,  Toshiyuki Shimazawa

    发明人： Hidefumi Hirai ,  Nobutoshi Ootsuka ,  Kenji Sakai ,  Toshiyuki Shimazawa

    IPC分类号： B01J20/32 ,  B01J20/34 ,  B01J20/10 ,  B01J20/20 ,  B01J20/22

    CPC分类号： B01J20/20 ,  B01J20/103 ,  B01J20/223 ,  B01J20/3204 ,  B01J20/3265 ,  B01J20/3425 ,  B01J20/3433 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/56 ,  B01J2220/58

    摘要： Disclosed are an adsorbent for CO, comprising a composite comprised of a porous inorganic carrier and, carried thereon, a binary complex of a nitrogen-containing compound and a copper(I) halide, the nitrogen-containing compound being at least one member selected from at least one pyridine compound and a diamine represented by R.sup.1 R.sup.2 N(CH.sub.2).sub.n --NR.sup.3 R.sup.4, wherein n is 2 or 3 and each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, with the proviso that when n is 2, each of at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group atoms and that when n is 3, at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group, and a method for separating carbon monoxide by adsorption using the adsorbent. The adsorbent is advantageous in that the adsorbent can adsorb CO with high selectivity and has high adsorptive and desorptive ability for CO, that the adsorbent can be produced using a conventional carrier and without using hydrochloric acid, with economical advantages, and that since the adsorbent is a solid, it can be handled with ease.

    摘要翻译： 公开了一种用于CO的吸附剂，其包含由多孔无机载体组成的复合体，并在其上承载含氮化合物和卤化铜（I）的二元配合物，所述含氮化合物为选自以下的至少一种： 由R1R2N（CH2）n-NR3R4表示的至少一种吡啶化合物和二胺，其中n为2或3，R1，R2，R3和R4各自独立地表示氢原子或C1-C4烷基，条件是 当n为2时，R 1，R 2，R 3和R 4中的至少两个表示C1-C4烷基原子，当n为3时，R 1，R 2，R 3和R 4中的至少一个表示C 1 -C 4 烷基，以及使用吸附剂通过吸附分离一氧化碳的方法。 吸附剂的优点在于吸附剂可以高选择性吸附CO并且对CO具有高吸附和解吸能力，吸附剂可以使用常规载体并且不使用盐酸生产，具有经济优势，并且由于吸附剂是 坚实，可以轻松处理。

    Method for separating carbon dioxide from mixed gas
    10.
    发明授权
    Method for separating carbon dioxide from mixed gas 失效
    从混合气体中分离二氧化碳的方法

    公开(公告)号：US4587114A

    公开(公告)日：1986-05-06

    申请号：US475258

    申请日：1983-03-14

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    IPC分类号： B01J20/20 ,  C01B32/40 ,  B01J21/18

    CPC分类号： C01B31/18 ,  B01J20/20

    摘要： A solid form adsorbent of carbon monoxide, that is obtained by the process including the following steps. First, copper salts or copper oxide is stirred in a solvent. Then, into the solution or suspension thus obtained, active carbon is added. Finally, the solvent is removed by means of pressure reduction, distillation, etc. The carbon monoxide adsorbent produced according to this invention adsorbs carbon monoxide rapidly when it is brought into contact with a mixed gas. The adsorbed carbon monoxide can be readily separated and discharged through either heating the carbon monoxide adsorbent to above 60.degree. C. or reducing the partial pressure of carbon monoxide. The carbon monoxide obtained in accordance with the present invention is stable relative to the water content in the mixed gas, and it is capable of separating carbon monoxide directly from the mixed gas containing the water. Also, the separated carbon monoxide does not contain the vapor of the solvent from the carbon monoxide adsorbent. Therefore, it is not necessary to provide equipment to collect the solvent vapor. Furthermore, this carbon monoxide adsorbent does not produce corrosive gases, etc. The carbon monoxide adsorbent obtained by using copper (II) salts or copper (II) oxide is also stable relative to sulfur content in the mixed gas.

    摘要翻译： 一氧化碳的固体形式吸附剂，其通过包括以下步骤的方法获得。 首先，将铜盐或氧化铜在溶剂中搅拌。 然后，加入如此获得的溶液或悬浮液中，加入活性炭。 最后，通过减压，蒸馏等除去溶剂。根据本发明生产的一氧化碳吸附剂在与混合气体接触时迅速吸附一氧化碳。 吸附的一氧化碳可以通过将一氧化碳吸附剂加热至60℃以上或者降低一氧化碳的分压来容易地分离和排出。 根据本发明获得的一氧化碳相对于混合气体中的含水量是稳定的，并且能够直接从含有水的混合气体中分离一氧化碳。 此外，分离的一氧化碳不含来自一氧化碳吸附剂的溶剂的蒸气。 因此，不需要提供收集溶剂蒸汽的设备。 此外，该一氧化碳吸附剂不产生腐蚀性气体等。使用铜（II）盐或氧化铜（II））得到的一氧化碳吸附剂相对于混合气体中的硫含量也是稳定的。