Process for the separation of mixtures of aromatic hydrocarbons into
single components
    2.
    发明授权
    Process for the separation of mixtures of aromatic hydrocarbons into single components 失效
    将芳烃混合物分离成单一成分的方法

    公开(公告)号:US4542254A

    公开(公告)日:1985-09-17

    申请号:US491229

    申请日:1983-05-03

    IPC分类号: C07C7/13 C10G25/03 C07C7/12

    CPC分类号: C07C7/13

    摘要: There is provided a process for the separation of aromatic hydrocarbons mixtures into single components, in which the mixtures in vapor phase pass onto an adsorption bed formed by a potassium-exchanged Y zeolite, which is preventively saturated with desorbent vapors. According to the invention the desorbent used is isopropylbenzene in vapor phase. This facilitates the quick separation of the pure components, with the exception of the presence of desorbent. The process according to this invention is quicker in comparison to traditional ones. It requires the use of lower charges of desorbent and allows the separation of single pure components of the mixtures. It especially improves the paraxylene separation in higher concentrations with respect to the desorbent.

    摘要翻译: 提供了一种将芳族烃混合物分离成单一组分的方法,其中气相中的混合物通过由经交换的Y沸石形成的吸附床,其被解吸蒸气预防性地饱和。 根据本发明,所用的解吸剂是气相中的异丙基苯。 除了存在解吸剂之外,这有助于快速分离纯组分。 根据本发明的方法与传统方法相比更快。 它需要使用较低电荷的解吸剂,并允许分离混合物的单一纯组分。 它特别改善相对于解吸剂的较高浓度的对二甲苯分离。

    Process for the synthesis of phenol and acetone
    3.
    发明授权
    Process for the synthesis of phenol and acetone 失效
    苯酚和丙酮合成方法

    公开(公告)号:US07084309B2

    公开(公告)日:2006-08-01

    申请号:US10507225

    申请日:2002-03-14

    申请人: Franco Codignola

    发明人: Franco Codignola

    IPC分类号: C07C39/04

    摘要: This invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, and to a plant specifically developed for performing this process. More in particular, this invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, comprising the following steps: a) Pretreating of the starting cumene hydroperoxide with acidic resins, to obtain cumene hydroperoxide free of inorganic cations; b) Decomposing of the cumene hydroperoxide free of inorganic cations originating from the step (a) in the presence of acidic resins, to yield phenol and acetone.

    摘要翻译: 本发明涉及从枯烯氢过氧化物开始合成苯酚和丙酮的方法,以及专门开发用于进行该方法的工厂。 更具体地,本发明涉及从氢过氧化枯烯开始合成苯酚和丙酮的方法,其包括以下步骤:a)用酸性树脂预处理起始氢过氧化枯烯,得到不含无机阳离子的氢过氧化枯烯; b)分解在酸性树脂存在下不含源自步骤(a)的无机阳离子的氢过氧化枯烯,以产生苯酚和丙酮。

    Poly-β-carboxyacrylamide polymer, use thereof and process for preparing the same
    5.
    发明授权
    Poly-β-carboxyacrylamide polymer, use thereof and process for preparing the same 失效
    聚-β-羧基丙烯酰胺聚合物及其制备方法及其制备方法

    公开(公告)号:US07341666B2

    公开(公告)日:2008-03-11

    申请号:US10508918

    申请日:2002-03-27

    申请人: Franco Codignola

    发明人: Franco Codignola

    IPC分类号: C08F22/38

    CPC分类号: C08F22/38

    摘要: A poly-β-carboxyacrylamide polymer of formula (I) wherein X is an alkaline metal or a substituent capable of bringing about an exchange reaction with a salt of an alkaline earth metal, said polymer having a ponderal average molecular weight greater than or equal to 2,000. The use of said polymer and process for preparing the same

    摘要翻译: 式(I)的聚-β-羧基丙烯酰胺聚合物,其中X是碱金属或能够与碱土金属的盐进行交换反应的取代基,所述聚合物的平均分子量大于或等于 2,000。 使用所述聚合物及其制备方法

    Process for the synthesis of cumene hydroperoxide
    6.
    发明授权
    Process for the synthesis of cumene hydroperoxide 失效
    合成氢过氧化枯烯的方法

    公开(公告)号:US07335797B2

    公开(公告)日:2008-02-26

    申请号:US10507227

    申请日:2002-03-14

    申请人: Franco Codignola

    发明人: Franco Codignola

    IPC分类号: C07C409/00

    摘要: This invention refers to a process for the synthesis of cumene hydroperoxide and to the product thus obtained.More in particular, this invention refers to a process for the production of cumene hydroperoxide by oxidating cumene with oxygen, where this process is run in the presence of a basic medium insoluble in the reaction environment, and such as not to release inorganic cations to the reaction environment. Such a basic medium is preferably a pyridinic resin.The cumene hydroperoxide thus obtained, characterized by the fact of being free of inorganic cations, is a further object of the invention.

    摘要翻译: 本发明涉及一种合成氢过氧化枯烯的方法以及由此得到的产物。 更具体地,本发明涉及通过用氧氧化异丙基苯来生产氢过氧化枯烯的方法,其中该方法在不溶于反应环境的碱性介质存在下进行,并且例如不将无机阳离子释放到 反应环境。 这样的碱性介质优选为吡啶系树脂。 由此获得的氢过氧化枯烯的特征在于不含无机阳离子的事实是本发明的另一个目的。

    Poly-beta-carboxyacrylamide polymer, use thereof and process for preparing the same
    7.
    发明申请
    Poly-beta-carboxyacrylamide polymer, use thereof and process for preparing the same 失效
    聚-β-羧基丙烯酰胺聚合物及其制备方法及其制备方法

    公开(公告)号:US20050218079A1

    公开(公告)日:2005-10-06

    申请号:US10508918

    申请日:2002-03-27

    申请人: Franco Codignola

    发明人: Franco Codignola

    IPC分类号: C08F22/38 C02F1/42

    CPC分类号: C08F22/38

    摘要: A poly-β-carboxyacrylamide polymer of formula (I) wherein X is an alkaline metal or a substituent capable of bringing about an exchange reaction with a salt of an alkaline earth metal, said polymer having a ponderal average molecular weight greater than or equal to 2,000. The use of said polymer and process for preparing the same.

    摘要翻译: 式(I)的聚-β-羧基丙烯酰胺聚合物,其中X是碱金属或能够与碱土金属的盐进行交换反应的取代基,所述聚合物的平均分子量大于或等于 2,000。 使用所述聚合物及其制备方法。

    Process for the preparation of 1,4-butynediol and related catalyst
    8.
    发明授权
    Process for the preparation of 1,4-butynediol and related catalyst 失效
    制备1,4-丁炔二醇及相关催化剂的方法

    公开(公告)号:US4288641A

    公开(公告)日:1981-09-08

    申请号:US85792

    申请日:1979-10-17

    IPC分类号: B01J29/072 C07C33/046

    CPC分类号: B01J29/072 C07C33/046

    摘要: The process for the preparation of 1,4-butynediol through the reaction of acetylene with formaldehyde in the presence of a catalytic metal, preferably copper, is improved by using, as the support of the catalytic metal, a molecular sieve or synthetic zeolite to which the catalytic metal is chemically bonded through an ion exchange reaction.There are obtained increased production rates and selectivity and the polymer of acetylene, namely cuprene, is essentially prevented from being formed.

    摘要翻译: 通过在催化金属(优选铜)存在下通过乙炔与甲醛的反应制备1,4-丁炔二醇的方法通过使用分子筛或合成沸石作为催化金属的载体来改进,其中分子筛或合成沸石 催化金属通过离子交换反应进行化学键合。 获得了提高的生产率和选择性,并且基本上防止了形成乙炔聚合物,即乙二胺。

    Process for the synthesis of phenol and acetone
    9.
    发明申请
    Process for the synthesis of phenol and acetone 失效
    苯酚和丙酮合成方法

    公开(公告)号:US20050177004A1

    公开(公告)日:2005-08-11

    申请号:US10507225

    申请日:2002-03-14

    申请人: Franco Codignola

    发明人: Franco Codignola

    摘要: This invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, and to a plant specifically developed for performing this process. More in particular, this invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, comprising the following steps: a) Pretreating of the starting cumene hydroperoxide with acidic resins, to obtain cumene hydroperoxide free of inorganic cations; b) Decomposing of the cumene hydroperoxide free of inorganic cations originating from the step (a) in the presence of acidic resins, to yield phenol and acetone.

    摘要翻译: 本发明涉及从枯烯氢过氧化物开始合成苯酚和丙酮的方法,以及专门开发用于进行该方法的工厂。 更具体地,本发明涉及从氢过氧化枯烯开始合成苯酚和丙酮的方法,其包括以下步骤:a)用酸性树脂预处理起始氢过氧化枯烯,得到不含无机阳离子的氢过氧化枯烯; b)分解在酸性树脂存在下不含源自步骤(a)的无机阳离子的氢过氧化枯烯,以产生苯酚和丙酮。

    Process for the production of aromatic acids

    公开(公告)号:US06521786B1

    公开(公告)日:2003-02-18

    申请号:US09913080

    申请日:2001-08-08

    IPC分类号: C07C5116

    摘要: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The novel process according to the present invention comprises the steps of: a) catalytically oxidizing the corresponding aromatic precursors in liquid phase in the presence of gaseous oxygen; b) filtering the end product; c) recycling into the oxidation reactor at least part of the mother liquors resulting from the filtration stage, and is characterized by the fact that said steps from (a) to (c) are carried out in a closed and continuous cycle operating substantially under the same pressure and temperature conditions, preferably at 2-10 barg and 100-140° C.