-
1.发明授权Intermediates and colorants having primary hydroxyl enriched poly (oxyalkylene) moieties and their preparation 失效具有伯羟基富集聚（氧化烯）部分的中间体和着色剂及其制备
公开(公告)号：US5290921A
公开(公告)日：1994-03-01
申请号：US461852
申请日：1990-01-08
Applicant: David J. Moody , Edward W. Kluger , John W. Rekers
Inventor： David J. Moody , Edward W. Kluger , John W. Rekers
IPC: C08G65/26 , C09B69/00 , C09B29/033 , C09B29/09 , D06P3/24
CPC classification number: C09B69/00 , C08G65/2627 , Y10S534/01
Abstract: The present invention provides primary hydroxyl enhanced colorants having markedly improved reactivities in e.g., polyurethane foams for imparting permanent coloring thereto, the colorants having the formulaC--(Z).sub.1-4are provided wherein C is an azo, methine, or azamethine chromogen and Z is a poly(oxyalkylene) moiety comprised of (1) at least two (A) units independently selected from those of the formulae--CH.sub.2 CH(O--T)CH.sub.2 O-- or --CH.sub.2 CH(O--T)CH.sub.2 O--Tand (2) from none to about 200 (B) units of the formula (--RO--) wherein R is straight or branched chain hydrocarbon of 2-4 carbons, T is a moiety of the formula--CH.sub.2 CH(R.sub.1)--O--(RO).sub.0-40 --CH.sub.2 CH.sub.2 OHwherein R.sub.1 is selected from unsubstituted or substituted alkyl, aryl, alkenyloxyalkyl, alkoxyalkyl or aryloxyalkyl, and wherein the A units comprise at least 0.5 percent of the total A+B units.
Abstract translation: 本发明提供具有明显改善的反应性的主要羟基增强着色剂，例如用于赋予永久性着色的聚氨酯泡沫，提供了具有式C-（Z）1-4的着色剂，其中C是偶氮，次甲基或氮杂酮色原体， Z是由（1）独立地选自式-CH 2 CH（OT）CH 2 O-或-CH 2 CH（OT）CH 2 O-T的单元中的至少两个（A）单元组成的聚（氧化烯）部分，（2） 约200（B）单位的式（-RO-）其中R是2-4个碳的直链或支链烃，T是式-CH 2 CH（R 1）-O-（RO）0-40- 其中R 1选自未取代或取代的烷基，芳基，烯氧基烷基，烷氧基烷基或芳氧基烷基，其中A单元占总A + B单元的至少0.5％。
-
公开(公告)号：US5177200A
公开(公告)日：1993-01-05
申请号：US354184
申请日：1989-05-19
Applicant: Edward W. Kluger , John W. Rekers , David J. Moody
Inventor： Edward W. Kluger , John W. Rekers , David J. Moody
Abstract: A colorant for natural or synthetic resinous or polymeric materials, having the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 ; wherein: R.sub.2 is selected for example from hydrogen, methyl, cyclohexyl, phenyl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted for example with halogen, alkyl, alkoxy, alkylthio, or aryloxy; Y is a poly(oxyalkylene) moiety containing at least three monomeric units or mixtures thereof of the formula (--RO--) wherein each R is straight or branched alkylene of 2-4 carbons or mixtures thereof, up to about 20 mole percent of said monomeric units may be connected by one or more linking groups such as alkyleneoxy, --NH--, or --NHCONH--, and wherein Y can be terminated by hydrogen, or by at branch subsituents, containing 1-3 groups or moieties selected from alkyl, cycloalkyl, acyl, or aryl; wherein any of the above recited hydrocarbon groups, moieties or substituents may themselves be substituted with up to four substituents selected, for example, from alkyl, halogen, mercapto, alkoxycarbonyl, hydroxy, alkoxy, or the like; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contains from 1-20 carbons.
Abstract translation: 具有式A- [SO 2 -N（R 2）-Y] 1-4的天然或合成树脂或聚合物材料的着色剂; 其中：R2选自例如氢，甲基，环己基，苯基或Y; A是非离子金属酞菁发色团，其可以被卤素，烷基，烷氧基，烷硫基或芳氧基取代; Y是含有至少三个单体单元的聚（氧化烯）部分或其混合物（-RO-），其中每个R是2-4个碳原子的直链或支链亚烷基或其混合物，最多约20摩尔％ 单体单元可以通过一个或多个连接基团例如亚烷基氧基，-NH-或-NHCONH-连接，并且其中Y可以被氢封端，或者在支链取代基处含有1-3个选自烷基， 环烷基，酰基或芳基; 其中任何上述烃基，部分或取代基本身可以被至多四个选自例如烷基，卤素，巯基，烷氧基羰基，羟基，烷氧基等的取代基取代; 并且其中上述基团，部分或取代基的每个脂族烃部分或部分含有1-20个碳。
-
公开(公告)号：US5270363A
公开(公告)日：1993-12-14
申请号：US935567
申请日：1992-08-24
Applicant: Edward W. Kluger , John W. Rekers , David J. Moody
Inventor： Edward W. Kluger , John W. Rekers , David J. Moody
IPC: C08K5/43 , C09B47/18 , C09B47/20 , C09B47/22 , C09B47/26 , C09B69/00 , C08K5/3417 , C08K5/04 , C08K5/41
Abstract: A colorant for natural or synthetic resinous or polymeric materials, having the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 ; wherein: R.sub.2 is selected for example from hydrogen, methyl, cyclohexyl, phenyl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted for example with halogen, alkyl. alkoxy, alkylthio, or aryloxy; Y is a poly(oxyalkylene) moiety containing at least three monomeric units or mixtures thereof of the formula (--RO--) wherein each R is straight or branched alkylene of 1-4 carbons or mixtures thereof, up to about 20 mole percent of said monomeric units may be connected by one or more linking groups such as alkyleneoxy, --NH--, or --NHCONH--, and wherein Y can be terminated by hydrogen, or by at branch substituents, containing 1--3 groups or moieties selected from alkyl, cycloalkyl, acyl, or aryl; wherein any of the above recited hydrocarbon groups, moieties or substitutents may themselves be substituted with up to four substitutents selected, for example, from alkyl, halogen, mercapto, alkoxycarbonyl, hydroxy, alkoxy, or the like; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contains from 1-20 carbons.
Abstract translation: 具有式A- [SO 2 -N（R 2）-Y] 1-4的天然或合成树脂或聚合物材料的着色剂; 其中：R2选自例如氢，甲基，环己基，苯基或Y; A是非离子金属酞菁发色团，其可以被卤素，烷基取代。 烷氧基，烷硫基或芳氧基; Y是包含式（-RO-）的至少三个单体单元或其混合物的聚（氧化烯）部分，其中每个R是1-4个碳的直链或支链亚烷基或其混合物，最多约20摩尔％ 单体单元可以通过一个或多个连接基团例如亚烷基氧基，-NH-或-NHCONH-连接，并且其中Y可以被氢封端，或者通过分支取代基连接，所述分支取代基包含1-3个选自烷基， 环烷基，酰基或芳基; 其中任何上述烃基，部分或取代基本身可以被至多四个选自例如烷基，卤素，巯基，烷氧基羰基，羟基，烷氧基等的取代基取代; 并且其中上述基团，部分或取代基的每个脂族烃部分或部分含有1-20个碳。
-
公开(公告)号：US4624980A
公开(公告)日：1986-11-25
申请号：US717049
申请日：1985-03-28
Applicant: John W. Rekers , Edward W. Kluger
Inventor： John W. Rekers , Edward W. Kluger
CPC classification number: C08K5/17
Abstract: An N-t-alkyl-N-sec-alkyl secondary amine compound of the formula: ##STR1## wherein X, Y and Z are each independently selected from --H, --OH, or an alkyl group having from 1 to about 15 carbon atoms; and n is an integer of from 3 to about 6.
Abstract translation: 具有下式的N-t-烷基-N-仲烷基仲胺化合物：其中X，Y和Z各自独立地选自-H，-OH或具有1至约15个碳原子的烷基; n为3〜6的整数。
-
5.发明授权Thermoplastic resin composition containing polyalkyleneoxy-substituted azo coloring agents having trifluoromethyl substituents 失效含有具有三氟甲基取代基的聚亚烷基氧基取代偶氮着色剂的热塑性树脂组合物
公开(公告)号：US4978362A
公开(公告)日：1990-12-18
申请号：US256270
申请日：1988-10-11
Applicant: Edward W. Kluger , John W. Rekers
Inventor： Edward W. Kluger , John W. Rekers
CPC classification number: C09B69/00 , D06P1/0052 , D06P3/246 , D06P3/406 , D06P3/526 , D06P3/705 , D06P3/796 , Y10S534/02
Abstract: A thermoplastic resin composition is provided which contains a thermoplastic resin and a colorant in the form of a polyalkyleneoxy-trifluoromethyl aniline colorant provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said resin, said colorant having the formula: ##STR1## wherein R.sub.1 is selected from H, a lower alkyl group containing from 1 to about 10 carbon atoms, CH.sub.2 Cl, CH.sub.2 Br, CH.sub.2 OH, phenyl or ##STR2## wherein R.sub.4 is H or a lower alkyl group containing from 1 to about 9 carbon atoms; R.sub.2 is H, CF.sub.3, a lower alkyl group containing from 1 to about 9 carbon atoms, Cl or Br; R.sub.3 is an aromatic or heteroaromatic containing group, and n is an integer from 2 to about 75.
Abstract translation: 提供一种热塑性树脂组合物，其包含热塑性树脂和以所述热塑性树脂中提供的聚亚烷基氧基 - 三氟甲基苯胺着色剂形式的着色剂，其量足以提供所述树脂的着色，所述着色剂具有下式： 其中R 1选自H，含1至约10个碳原子的低级烷基，CH 2 Cl，CH 2 Br，CH 2 OH，苯基或其中R 4为H或含有1至约9个碳原子的低级烷基; R2是H，CF3，含有1至约9个碳原子的低级烷基，Cl或Br; R3是含芳基或含杂芳基的基团，n是2至约75的整数。
-
Patent Agency Ranking
公开(公告)号：US5135972A
公开(公告)日：1992-08-04
申请号：US732421
申请日：1991-07-15
Applicant: Edward W. Kluger , John W. Rekers , Max A. Weaver
Inventor： Edward W. Kluger , John W. Rekers , Max A. Weaver
Abstract: Colorants and compositions containing the same, including polymeric substrates, especially polyurethane foams which are tinted or deeper colored with the colorants which have the general formula: ##STR1## wherein R.sub.2 is selected from hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted or unsubstituted; Z is an arylene moiety; each D or D' is selected from a covalent bond or a linking group consisting of or containing at least one of --O--, --S--, --N(R.sub.3)--, or --N(SO.sub.2 R.sub.4)-- as the linking moiety, wherein R.sub.4 is unsubstituted or substituted alkyl, cycloaliphatic or aryl, and R.sub.3 is R.sub.4 or hydrogen; D in combination with Z can also be a covalent bond; Y is a poly(oxyalkylene) moiety containing at least about 50 mole percent of monomeric units or mixture thereof of the formula (--RO--) wherein each R is substituted or unsubstituted straight or branched alkylene of 1-4 carbons or mixtures thereof; wherein ring P can be unsubstituted or substituted in addition to the --(D'--Y) moieties; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contain from 1-20 carbons and wherein n is 1- 16, except when --D--Z-- is a covalent bond then n is equal to 1-4.
Abstract translation: 着色剂和含有它们的组合物，包括聚合物基质，特别是用着色剂着色或深色着色的聚氨酯泡沫，其具有以下通式：其中R 2选自氢或未取代或取代的烷基，环烷基，芳基或Y; A是可以被取代或未取代的非离子金属酞菁发色团; Z是亚芳基; 每个D或D'选自共价键或由-O，-S-，-N（R 3） - 或-N（SO 2 R 4） - 中的至少一个组成或含有连接基团的连接基团， 其中R4是未取代或取代的烷基，脂环族或芳基，R3是R4或氢; D与Z组合也可以是共价键; Y是含有至少约50摩尔％的式（-RO-）的单体单元或其混合物的聚（氧化烯）部分，其中每个R是1-4个碳原子的取代或未取代的直链或支链亚烷基或其混合物; 其中除了 - （D'-Y）部分之外，环P可以是未取代的或取代的; 并且其中上述基团，部分或取代基的每个脂族烃部分或部分含有1-20个碳，并且其中n为1-16，但当-D-Z-为共价键时，n等于1-4。
-
7.发明授权Methine colorants and washable ink compositions containing methine colorants 失效含有次甲基着色剂的甲基染料和可洗墨水组合物
公开(公告)号：US4981516A
公开(公告)日：1991-01-01
申请号：US410207
申请日：1989-09-21
Applicant: Edward W. Kluger , John W. Rekers , Judy A. Wagner
Inventor： Edward W. Kluger , John W. Rekers , Judy A. Wagner
Abstract: A washable ink composition is provided which is an aqueous mixture containing water soluble, ester-terminated, poly(alkyleneoxy)-substituted methine colorant of the formula: ##STR1## wherein: AR is an unsubstituted or substituted aromatic or hetero-aromatic group; X is nitrogen or oxygen; R is unsubstituted or substituted straight or branched alkylene of 2-4 carbons or mixtures thereof; R.sub.1 is H or an unsubstituted or substituted alkyl, cycloalkyl or phenyl moiety containing one to about 10 carbons, or a group of the formula: ##STR2## wherein: R.sub.3 is H or alkyl of one to about ten carbons, and d is zero when X is oxygen and one when X is nitrogen; R.sub.2 is hydrogen or alkyl of one to about five carbons; a and b are each an integer independently selected from one to about forty wherein a+b is an integer of from about 6 to about 80; and Z is a divalent vinylic carbon atom which is covalently bonded to a group or moiety including any of cyano, vinyl carbon, sulfide, sulfoxide, sulfone, allylic oxygen, thiocyano, or carbonyl which is not part of an amide, carboxylic acid or carboxylic acid salt moiety.
Abstract translation: 提供了一种可洗涤的油墨组合物，其是含有下式的水溶性酯酯封端的聚（亚烷氧基） - 取代的次甲基着色剂的水性混合物，其中：AR是未取代或取代的芳族或杂芳族基团; X是氮或氧; R是2-4个碳原子的未取代或取代的直链或支链亚烷基或其混合物; R1是H或含有1至约10个碳的未取代或取代的烷基，环烷基或苯基部分，或下式的基团：其中：R 3为H或1至约10个碳的烷基，d为0 X为氧，X为氮时为氧; R2是氢或一至五个碳的烷基; a和b各自为独立选自1至约40的整数，其中a + b为约6至约80的整数; Z是与不是酰胺，羧酸或羧酸的一部分的氰基，乙烯基碳，硫醚，亚砜，砜，烯丙氧，硫氰酸或羰基中的任何一个或多个基团共价结合的二价乙烯基碳原子 酸盐部分。
-
公开(公告)号：US5240980A
公开(公告)日：1993-08-31
申请号：US890353
申请日：1992-05-22
Applicant: Todd D. Danielson , David J. Moody , John W. Rekers
Inventor： Todd D. Danielson , David J. Moody , John W. Rekers
CPC classification number: C09B69/00 , C08K5/0041 , C08K9/08
Abstract: An opacified, semi-crystalline thermoplastic resin composition is provided having a poly(alkyleneoxy) substituted organic chromophore distributed throughout in an amount sufficient to color the resin. The resin composition is particularly useful for molding parts with strict dimensional tolerances as shrinkage of the molded part is minimal.
Abstract translation: 提供了一种不透明的半结晶热塑性树脂组合物，其具有遍布全部的聚（亚烷氧基）取代的有机发色团，其量足以使树脂着色。 树脂组合物特别适用于具有严格的尺寸公差的模制件，因为模制件的收缩是最小的。
-
公开(公告)号：US4985546A
公开(公告)日：1991-01-15
申请号：US371907
申请日：1989-06-19
Applicant: John W. Miley , John W. Rekers
Inventor： John W. Miley , John W. Rekers
IPC: C07C217/08 , C07D317/22 , C07D319/06 , C08G18/50 , C08G59/50 , C08G65/26 , C08G65/322 , C08G65/325 , C08G65/338 , C09B69/00
CPC classification number: C07C217/08 , C07D317/22 , C07D319/06 , C08G18/5021 , C08G59/504 , C08G65/2606 , C08G65/322 , C08G65/3255 , C08G65/338 , C09B69/00 , Y10S534/03
Abstract: A substituted colorant which may be copolymerized with a condensation polymer to provide a covalently bound, nonextractable coloring, having the formula ##STR1## wherein R and R.sub.1 are independently selected from hydrogen or lower alkyl; R.sub.4 is selected from hydrogen or lower alkyl; x is 0 or 1; N and M are each integers of from 1 to about 100 and the sum of N and M is from 3 to about 100. The hydroxyl groups are protected by formation of a ring structure during alkoxylation and amination of the substituent.
Abstract translation: 可以与缩聚物共聚以提供共价结合的不可萃取着色的取代的着色剂，其具有下式：其中R和R 1独立地选自氢或低级烷基; R4选自氢或低级烷基; x为0或1; N和M各自为1至约100的整数，N和M的总和为3至约100.羟基在取代基的烷氧基化和胺化期间通过形成环结构来保护。
-
10.发明授权Process for preparing polyurethane resins colored with anthraquinone colorants and products produced thereby 失效制备用蒽醌着色剂着色的聚氨酯树脂和由此生产的产品的方法
公开(公告)号：US4846846A
公开(公告)日：1989-07-11
申请号：US210887
申请日：1988-06-20
Applicant: John W. Rekers , John W. Miley
Inventor： John W. Rekers , John W. Miley
Abstract: A process for coloring polyurethane resins made by a polyaddition reaction of a polyol and an isocyanate is provided, which comprises adding to the reaction mixture before or during the polyaddition reaction a reactive coloring agent suitable for incorporation in the resin with the formation of covalent bonds, said coloring agent having the formula: ##STR1## in which R.sub.1 and R.sub.2 are independently selected from an alkyl group having from 1 to about 12 carbon atoms, X is --CH.sub.2 --, a and a' are integers from 1 to about 6, and Y and Y' are independently selected from polymeric units of hydroxy alkylenes or alkylene oxide monomers selected from ethylene oxide, propylene oxide, butylene oxide, cyclohexene oxide, or glycidol, b and b' are independently either 0 or 1, and Z and Z' are reactive groups independently selected from --OH, --NH.sub.2, or --SH.
-
-
-
-
-
-
-
-
-
Search Results
20
records
(took 0.019 seconds)
