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公开(公告)号：US20150080545A1
公开(公告)日：2015-03-19
申请号：US14480363
申请日：2014-09-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Keith H. Kuechler , Neeraj Sangar , Michael Salciccioli , Alan A. Galuska , Gary D. Mohr
IPC: C08G63/185 , C08G63/199 , C07C51/16 , C07C63/333 , C07C67/08 , C07C15/14
CPC classification number: C08G63/185 , C07C2/74 , C07C5/367 , C07C51/265 , C07C2101/14 , C07C2601/14 , C08G63/199 , C08J5/18 , C08J2327/06 , C08K2201/014 , D21H27/20 , H01B3/443 , Y10T428/2964 , C08K5/10 , C08L27/06 , C07C63/333 , C07C63/26 , C07C13/28 , C07C15/14
Abstract: In a process for producing 3,4′ and/or 4,4′ dimethyl-substituted biphenyl compounds, a feed comprising toluene is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes. At least part of the hydroalkylation reaction product is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of dimethyl-substituted biphenyl isomers. The dehydrogenation reaction product is then separated into at least a first stream containing at least 50% of 3,4′ and 4,4′ dimethylbiphenyl isomers by weight of the first stream and at least one second stream comprising one or more 2,x′ (where x′ is 2′, 3′, or 4′) and 3,3′ dimethylbiphenyl isomers.
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公开(公告)号：US20140378697A1
公开(公告)日：2014-12-25
申请号：US14314557
申请日：2014-06-25
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Emiel de Smit , Neeraj Sangar , Michael Salciccioli , Jihad M. Dakka , Lorenzo C. DeCaul , Terry E. Helton , Scott J. Weigel
IPC: C07C2/74 , C07C67/08 , C07C5/32 , C07C51/265
CPC classification number: C07C2/74 , B01J29/088 , B01J29/106 , B01J29/12 , B01J29/126 , B01J29/146 , B01J29/185 , B01J29/22 , B01J29/24 , B01J29/7057 , B01J29/7084 , B01J29/7415 , B01J29/7469 , B01J29/7615 , B01J29/7669 , B01J35/023 , B01J35/026 , B01J2029/081 , B01J2229/186 , B01J2229/42 , C07C5/367 , C07C51/265 , C07C67/08 , C07C2521/12 , C07C2529/08 , C07C2529/12 , C07C2529/22 , C07C2529/74 , C07C2529/80 , Y02P20/52 , C07C63/331 , C07C69/76 , C07C13/28 , C07C15/14
Abstract: This invention relates to process for producing biphenyl esters, the process comprising: (a) contacting a feed comprising toluene, xylene or mixtures thereof with hydrogen in the presence of a hydroalkylation catalyst to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluene, wherein the hydroalkylation catalyst comprises: 1) binder present at 40 wt % or less (based upon weight of final catalyst composition), 2) a hydrogenation component present at 0.2 wt % or less (based upon weight of final catalyst composition), and 3) an acidic component comprising a molecular sieve having a twelve membered (or larger) ring pore opening, channel or pocket and a largest pore dimension of 6.0 angstroms or more present at 60 wt % or more, (based upon weight of final catalyst composition); (b) dehydrogenating the hydroalkylation reaction product using a dehydrogenation catalyst to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds; (c) contacting at the dehydrogenation reaction product with an oxidizing gas to convert the methyl-substituted biphenyl compounds to biphenyl carboxylic acids; and (d) reacting the biphenyl carboxylic acids with one or more C1 to C14 alcohols to produce biphenyl esters.
Abstract translation: 本发明涉及生产联苯酯的方法，该方法包括：（a）在加氢烷基化催化剂存在下使包含甲苯，二甲苯或其混合物的进料与氢气接触以产生包含（甲基环己基）甲苯的加氢烷基化反应产物，其中 加氢烷基化催化剂包括：1）以40重量％或更少（基于最终催化剂组合物的重量）存在的粘合剂，2）以0.2重量％或更少（基于最终催化剂组合物的重量）存在的氢化组分，和3） 酸性组分包含具有十二元（或更大）环孔开口，通道或口袋和最大孔尺寸为6.0埃或更大的分子筛，分子筛为60重量％或更多（基于最终催化剂组合物的重量）; （b）使用脱氢催化剂使加氢烷基化反应产物脱氢以产生包含甲基取代的联苯化合物的混合物的脱氢反应产物; （c）在脱氢反应产物与氧化气体接触以将甲基取代的联苯化合物转化为联苯羧酸; 和（d）使联苯羧酸与一种或多种C1至C14醇反应以制备联苯酯。
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公开(公告)号：US10654770B2
公开(公告)日：2020-05-19
申请号：US16324634
申请日：2017-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kun Wang , Lorenzo C. DeCaul , James R. Lattner
Abstract: Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating diisobutylene to produce neopentane. The diisobutylene may be provided by the dimerization of isobutylene.
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公开(公告)号：US09856186B2
公开(公告)日：2018-01-02
申请号：US14957332
申请日：2015-12-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Michael Salciccioli , Jihad M. Dakka , Emiel de Smit , Neeraj Sangar , Scott J. Weigel , Sumathy Raman , Terry E. Helton , Lorenzo C. DeCaul , Christine N. Elia , Chuansheng Bai , Ranjita Ghose
CPC classification number: C07C5/2737 , C07C2/66 , C07C2/74 , C07C2/82 , C07C2/86 , C07C5/2735 , C07C5/367 , C07C2521/02 , C07C2521/04 , C07C2521/10 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/78 , C07C2601/14 , C07C15/14 , C07C13/28
Abstract: A process is described for converting at least one isomer of a dialkyl-substituted biphenyl compound, such as at least one 2,X′ dialkylbiphenyl isomer (where X′ is 2′, 3′ and/or 4′), into at least one different isomer, 3,3′, 3,4′ and/or 4,4′ dialkylbiphenyl isomer. The process comprises contacting a feed comprising the dialkyl-substituted biphenyl compound isomer with an acid catalyst under isomerization conditions.
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公开(公告)号：US20170305810A1
公开(公告)日：2017-10-26
申请号：US15646889
申请日：2017-07-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John S. Buchanan , Stephen H. Brown , Lorenzo C. DeCaul , Brett T. Loveless , Rohit Vijay , Stephen J. McCarthy , Michel Daage , Mayank Shekhar
CPC classification number: C07C1/20 , C07C1/2076 , C07C2529/44 , C10G3/49 , C10G2400/30 , C07C15/00
Abstract: Methods are provided for improving the yield of aromatics during conversion of oxygenate feeds. An oxygenate feed can contain a mixture of oxygenate compounds, including one or more compounds with a hydrogen index of less than 2, so that an effective hydrogen index of the mixture of oxygenates is between about 1.4 and 1.9. Methods are also provided for converting a mixture of oxygenates with an effective hydrogen index greater than about 1 with a pyrolysis oil co-feed. The difficulties in co-processing a pyrolysis oil can be reduced or minimized by staging the introduction of pyrolysis oil into a reaction system. This can allow varying mixtures of pyrolysis oil and methanol, or another oxygenate feed, to be introduced into a reaction system at various feed entry points.
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Patent Agency Ranking
公开(公告)号：US09663417B2
公开(公告)日：2017-05-30
申请号：US14201287
申请日：2014-03-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul
CPC classification number: C07C2/74 , B01J23/6527 , B01J29/126 , B01J29/7415 , B01J29/7476 , B01J2229/20 , B01J2229/42 , C07C5/367 , C07C2521/06 , C07C2523/30 , C07C2523/42 , C07C2523/62 , C07C2529/12 , C07C2529/74 , C07C2601/14 , C07C13/28 , C07C15/14
Abstract: In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes. At least part of the hydroalkylation reaction product is then dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.
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7.发明授权Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers 有权甲基取代联苯化合物，其生产及其在制造增塑剂中的应用公开(公告)号：US09556087B2
公开(公告)日：2017-01-31
申请号：US14201173
申请日：2014-03-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Victor DeFlorio
IPC: C07C69/76 , C07C5/367 , C07C67/08 , C07C2/74 , C07C51/265 , B01J29/03 , B01J29/08 , B01J29/12 , B01J29/14 , B01J29/70 , B01J29/74 , B01J29/76
CPC classification number: C07C5/367 , B01J29/0325 , B01J29/085 , B01J29/12 , B01J29/14 , B01J29/7057 , B01J29/7084 , B01J29/7415 , B01J29/7469 , B01J29/7615 , B01J29/7669 , C07C2/74 , C07C51/265 , C07C67/08 , C07C2521/04 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C15/14 , C07C63/331 , C07C69/76
Abstract: In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes together with dialkylated C21+ compounds. At least part of the dialkylated C21+ compounds is then removed from the hydroalkylation reaction product to produce a dehydrogenation feed; and at least part of the dehydrogenation feed is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.
Abstract translation: 在生产甲基取代的联苯化合物的方法中，在有效产生加氢烷基化反应的条件下，在加氢烷基化催化剂的存在下，将包含至少一种选自甲苯，二甲苯及其混合物的芳族烃的进料与氢气接触 包含（甲基环己基）甲苯和/或（二甲基环己基）二甲苯与二烷基化C21 +化合物的产物。 然后将至少部分二烷基化C21 +化合物从加氢烷基化反应产物中除去以产生脱氢进料; 并且在有效产生包含甲基取代的联苯化合物的混合物的脱氢反应产物的条件下，在脱氢催化剂存在下，将脱氢进料的至少一部分脱氢。
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公开(公告)号：US20140212666A1
公开(公告)日：2014-07-31
申请号：US14164889
申请日：2014-01-27
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre Osterrieth , Stephen Zushma , Allen D. Goodwin , Diana Smirnova , Catherine A. Faler , Victor Deflorio , Didier Naert
IPC: C08K5/101 , C08J5/18 , H01B3/44 , C08K5/12 , C09D127/06
CPC classification number: C07C69/76 , C07C2/68 , C07C2/76 , C07C51/285 , C07C67/08 , C07C67/39 , C07C69/78 , C07C2601/14 , C08J5/18 , C08J2327/06 , C08K3/10 , C08K5/10 , C08K5/101 , C08K5/103 , C08K5/12 , C08K2201/014 , C09D127/06 , D06M13/224 , D06N3/0059 , D06N5/00 , D06N7/0002 , D21H27/20 , H01B3/443 , Y10T428/2964 , Y10T428/31935 , C08K3/0033 , C08K5/0016 , C08L27/06 , C08K3/013
Abstract: Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is a C4 to C14 hydrocarbyl, preferably the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
Abstract translation: 提供以下化合物：其中R1是任选被烷基和/或OXO-酯取代的饱和或不饱和环烃，R 2是C 4至C 14烃基，优选C 4至C 14 O XO-醇的残基。 还提供了制备含有所述化合物的化合物和增塑聚合物组合物的方法。
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公开(公告)号：US20190225561A1
公开(公告)日：2019-07-25
申请号：US16324788
申请日：2017-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kun Wang , Lorenzo C. DeCaul , Steven W. Levine , Etienne Mazoyer , James R. Lattner , Helge Jaensch , Ali A. Kheir
Abstract: Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating isooctane to produce neopentane. The isooctane may be provided by the alkylation of isobutane with butylenes.
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公开(公告)号：US20190169092A1
公开(公告)日：2019-06-06
申请号：US16324722
申请日：2017-08-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kun Wang , Lorenzo C. DeCaul , Michele L. Paccagnini , Etienne Mazoyer , James R. Lattner , Helge Jaensch , Ali A. Kheir
Abstract: Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating neohexane and/or neoheptane to produce neopentane. The neohexane and/or neoheptane may be provided by the isomerization of C6-C7 paraffins.
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