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公开(公告)号：US20170233322A1
公开(公告)日：2017-08-17
申请号：US15114191
申请日：2015-03-10
发明人： Glenn A. Miller , Thomas C. Eisenschmid , Michael A. Brammer , Michael C. Becker , Rick B. Watson
CPC分类号： C07C45/80 , C07C45/50 , Y02P20/582 , C07C47/02
摘要： A hydroformylation process wherein a water-soluble amine is contacted with the reaction fluid, liquid from the reactor is sent to an extraction zone, and a neutralized phosphorus acidic compound is at least partially removed from the extraction zone.
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公开(公告)号：US09539566B2
公开(公告)日：2017-01-10
申请号：US14423455
申请日：2013-08-15
CPC分类号： B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/00 , C07C45/50 , C07C47/02
摘要： A process for forming a catalyst from a catalytic metal precursor, a chelating bisphosphite and a bulky monophosphite, with a slightly greater than stoichiometric amount of chelating bisphosphite relative to catalytic metal under a CO partial pressure at least 25 psig.
摘要翻译： 在催化金属前体，螯合双亚磷酸酯和大体积单亚磷酸酯上形成催化剂的方法，其在相对于催化金属的CO分压至少25psig下具有略大于化学计算量的螯合双亚磷酸酯的方法。
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公开(公告)号：US20190047930A1
公开(公告)日：2019-02-14
申请号：US16076734
申请日：2017-02-10
发明人： Michael C. Becker , Michael A. Brammer , Jason F. Giles , Glenn A. Miller , George R. Phillips , Rick B. Watson , Stephane Wambergue , Martin Lucas Smidt
IPC分类号： C07C29/141 , C07C41/01 , C07C45/50 , C10L1/182 , C10L1/185
摘要： Embodiments of the present invention relate to processes for converting olefins to alcohols, ethers, or combinations thereof that are suitable for use as a gasoline additive. In one embodiment, the process comprises (a) receiving a feed stream, wherein the feed stream comprises one or more olefins having 2 to 5 carbon atoms in an amount of up to 80% by weight based on the weight of the feed stream; (b) hydroformylating the feed stream in the presence of a catalyst to convert at least 80% of the olefins from the feed stream to oxygenates; (c) separating a product stream from step (b) into an oxygenate stream and a stream comprising unreacted olefins, inerts, the catalyst, and the remaining oxygenates; and (d) treating the oxygenate stream to convert a plurality of the oxygenates into at least one of an alcohol, an ether, or combinations thereof having at least 3 carbon atoms, wherein at least 25 weight percent of the alcohols and ethers having at least 3 carbon atoms are branched based on the total weight of the alcohols and ethers having at least 3 carbon atoms, and wherein the alcohols, ethers, or combination thereof is suitable for use as a gasoline additive.
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公开(公告)号：US09676685B2
公开(公告)日：2017-06-13
申请号：US14889350
申请日：2014-06-19
发明人： Rick B. Watson , Glenn A. Miller
CPC分类号： C07C7/163 , C07C45/50 , C10G45/32 , C10G2300/1092 , C10G2400/20 , C07C11/08
摘要： A process for reducing the diene content of an olefin by feeding hydrogen to the process in stages.
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公开(公告)号：US20150209773A1
公开(公告)日：2015-07-30
申请号：US14423455
申请日：2013-08-15
CPC分类号： B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/00 , C07C45/50 , C07C47/02
摘要： A process for forming a catalyst from a catalytic metal precursor, a chelating bisphosphite and a bulky monophosphite, with a slightly greater than stoichiometric amount of chelating bisphosphite relative to catalytic metal under a CO partial pressure at least 25 psig.
摘要翻译： 在催化金属前体，螯合双亚磷酸酯和大体积单亚磷酸酯上形成催化剂的方法，其在相对于催化金属的CO分压至少25psig下略大于化学计量量的螯合双亚磷酸酯。
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公开(公告)号：US09688598B2
公开(公告)日：2017-06-27
申请号：US15032068
申请日：2014-12-09
发明人： Thomas C. Eisenschmid , Morteza Mokhtarzadeh , Cloid R. Smith, III , Michael C. Becker , George R. Phillips , Michael A. Brammer , Glenn A. Miller , Rick B. Watson , Irvin B. Cox , Edward A. Lord , Martin Smidt
CPC分类号： C07C45/50 , B01J31/24 , B01J2231/321 , B01J2531/822 , C07C45/78 , C07C45/82 , Y02P20/582 , C07C47/02
摘要： A multi-reaction train hydroformylation process wherein a common product-catalyst separation zone is employed.
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公开(公告)号：US09328047B2
公开(公告)日：2016-05-03
申请号：US14429672
申请日：2013-09-09
CPC分类号： C07C45/505 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07F9/65744 , Y02P20/582 , C07C47/02
摘要： A process for stabilizing a phosphite ligand against degradation in a hydroformylation reaction fluid, said process comprising adding an epoxide to the reaction fluid, and further comprising separating one or more phosphorus acidic compounds from the reaction fluid by treating the reaction fluid with an aqueous buffer solution under conditions sufficient to neutralize and remove at least some amount of the phosphorus acidic compounds from the reaction fluid.
摘要翻译： 一种用于稳定亚磷酸酯配体以防止加氢甲酰化反应流体中的降解的方法，所述方法包括向反应流体中加入环氧化物，并且还包括通过用缓冲溶液水溶液处理反应流体与反应流体分离一种或多种磷酸性化合物 在足以中和并从反应流体中除去至少一定量的磷酸性化合物的条件下进行。
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公开(公告)号：US20150232403A1
公开(公告)日：2015-08-20
申请号：US14429672
申请日：2013-09-09
IPC分类号： C07C45/50
CPC分类号： C07C45/505 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07F9/65744 , Y02P20/582 , C07C47/02
摘要： A process for stabilizing a phosphite ligand against degradation in a hydroformylation reaction fluid, said process comprising adding an epoxide to the reaction fluid, and further comprising separating one or more phosphorus acidic compounds from the reaction fluid by treating the reaction fluid with an aqueous buffer solution under conditions sufficient to neutralize and remove at least some amount of the phosphorus acidic compounds from the reaction fluid.
摘要翻译： 一种用于稳定亚磷酸酯配体以防止加氢甲酰化反应流体中的降解的方法，所述方法包括向反应流体中加入环氧化物，并且还包括通过用缓冲溶液水溶液处理反应流体与反应流体分离一种或多种磷酸性化合物 在足以中和并从反应流体中除去至少一定量的磷酸性化合物的条件下进行。
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公开(公告)号：US11141719B2
公开(公告)日：2021-10-12
申请号：US16340772
申请日：2017-11-06
摘要： Disclosed herein are methods of treating a hydroformylation catalyst solution wherein the solution comprises rhodium, polyphosphoramidite ligands, and polyphosphoramidite ligand degradation products and wherein the hydroformylation catalyst solution is used to hydroformylate an olefin in an operating hydroformylation unit. In some embodiments, such methods comprise contacting the catalyst solution with a peroxide in the operating hydroformylation unit.
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公开(公告)号：US11033890B2
公开(公告)日：2021-06-15
申请号：US16638420
申请日：2018-11-02
发明人： Marinus A. Bigi , Rick B. Watson
摘要： Some embodiments of the present invention relate to processes to recover rhodium from a hydroformylation process. In some embodiments, the process to recover rhodium from the hydroformylation process comprises (a) treating a catalyst-containing stream from the hydroformylation process with 2.5 to 20 weight percent, based on the total weight of the stream, of a water-soluble organic amine of the following structure: wherein R32, R33, and R34 are each independently alkyls and ethoxylates, and wherein no more than one of R32, R33, and R34 is alkyl; (b) heating the resulting solution in the presence of syngas to a temperature of at least 65° C. to generate a rhodium-rich phase and a supernatant; and (c) removing the supernatant to recover the rhodium-rich phase.
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