LONG CHAIN BRANCHED (LCB), BLOCK OR INTERCONNECTED COPOLYMERS OF ETHYLENE IN COMBINATION WITH ONE OTHER POLYMER
    4.
    发明申请
    LONG CHAIN BRANCHED (LCB), BLOCK OR INTERCONNECTED COPOLYMERS OF ETHYLENE IN COMBINATION WITH ONE OTHER POLYMER 有权
    长链分支(LCB),乙烯与一种其他聚合物组合的嵌段或互连共聚物

    公开(公告)号:US20140024775A1

    公开(公告)日:2014-01-23

    申请号:US14034002

    申请日:2013-09-23

    Abstract: An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm≧(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.

    Abstract translation: 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物,峰值熔融温度Tm,℃,熔化热,Hf / J, 通过DSC结晶度测定,其中Tm和Hf的数值对应于Tm> =(0.2143×Hf)+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物,其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5,并且其中至少5%的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。

    PROCESSES TO IMPROVE REACTOR STABILITY FOR THE PREPARATION OF ETHYLENE-BASED POLYMERS USING ASYMMETRICAL POLYENES
    7.
    发明申请
    PROCESSES TO IMPROVE REACTOR STABILITY FOR THE PREPARATION OF ETHYLENE-BASED POLYMERS USING ASYMMETRICAL POLYENES 有权
    使用不对称聚酯制备基于乙烯的聚合物来提高反应器稳定性的方法

    公开(公告)号:US20160304643A1

    公开(公告)日:2016-10-20

    申请号:US15101347

    申请日:2014-12-23

    CPC classification number: C08F210/02 C08F2220/282 C08F2220/281 C08F2/38

    Abstract: The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene and at least one asymmetrical polyene, comprising an “alpha, beta unsaturated—carbonyl end” and a “C—C double bond end,” and wherein the polymerization takes place in the presence of at least one free-radical initiator, and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≧2), wherein reaction zone i is downstream from reaction zone 1; and wherein at least one chain transfer agent (CTA) is added to the polymerization, and wherein the CTA is a saturated hydrocarbon or an unsaturated hydrocarbon.

    Abstract translation: 本发明提供一种形成乙烯基聚合物的方法,所述方法包括聚合乙烯和至少一种不对称多烯,其包含“α,β不饱和羰基末端”和“C-C双键末端”,其中 在至少一种自由基引发剂的存在下进行聚合,并且其中聚合在包括至少两个反应区,反应区1和反应区i(i≥2)的反应器构型中进行,其中反应区i为 在反应区1的下游; 并且其中向所述聚合中加入至少一种链转移剂(CTA),并且其中所述CTA为饱和烃或不饱和烃。

    Inhibitor Combination for Lithium Salt-Catalyzed Transesterification Process and Method for Removing Lithium Salt
    8.
    发明申请
    Inhibitor Combination for Lithium Salt-Catalyzed Transesterification Process and Method for Removing Lithium Salt 有权
    锂盐催化酯交换反应的抑制剂组合及其脱锂方法

    公开(公告)号:US20160297736A1

    公开(公告)日:2016-10-13

    申请号:US15100759

    申请日:2014-11-21

    Abstract: A process to form a composition comprising an asymmetrical polyene, the asymmetrical polyene comprising an “α,β unsaturated-carbonyl end” and a “C—C double bond end,” the process comprising: reacting an alkene- or polyene-containing alcohol with an alkyl ester of an α,β unsaturated carboxylic acid in the presence of at least the following components A) through C) to form a solution comprising an asymmetrical polyene: A) a lithium salt; B) a component selected from the group consisting of hydroquinone, an alkyl-substituted phenol, a substituted alkyl-substituted phenol, an alkyl-substituted hydroquinone, a substituted alkyl-substituted hydroquinone, and combinations thereof; and C) an N-oxyl-containing compound; wherein the “α,β unsaturated-carbonyl end” of the asymmetrical polyene is selected from the group consisting of structures a) through c), as described herein, and wherein the “C—C double bond end” of the asymmetrical polyene is selected from the group consisting of structures 1) through 17), as described herein.

    Abstract translation: 形成包含不对称多烯的组合物的方法,所述不对称多烯包含“α,β不饱和羰基端”和“C-C双键末端”,该方法包括:使含烯烃或含多烯醇与 在至少以下组分A)至C)的存在下,α,β不饱和羧酸的烷基酯形成包含不对称多烯的溶液:A)锂盐; B)选自氢醌,烷基取代的酚,取代的烷基取代的酚,烷基取代的氢醌,取代的烷基取代的氢醌及其组合的组分; 和C)含有N-氧基的化合物; 其中不对称多烯的“α,β不饱和羰基端”选自如本文所述的结构a)至c),并且其中选择不对称多烯的“C-C双键末端” 来自由结构1)至17)组成的组,如本文所述。

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