Process for improving production of Fischer-Tropsch distillate fuels
    3.
    发明授权
    Process for improving production of Fischer-Tropsch distillate fuels 有权
    改进费 - 托馏分燃料生产的方法

    公开(公告)号:US06824574B2

    公开(公告)日:2004-11-30

    申请号:US10267444

    申请日:2002-10-09

    IPC分类号: C10L118

    CPC分类号: C10L1/026

    摘要: Olefins and alcohols present in Fischer-Tropsch light naphthas are converted to dialkyl ethers of the formula: R—O—R′ where R and R′ are each primarily non-tertiary alkyl groups of more than four carbon atoms, via hydration of the olefins to alcohols followed by dehydration of the alcohols. Ethers may also form by direct reaction of olefins and alcohols. The ethers are separated from the remaining paraffins in the naphtha by distillation and added in an amount of 1-25 wt. % to paraffinic mid-distillate fuel components obtained by hydrotreating a Fischer-Tropsch product. The properties of the distillate fuel components such as lubricity and seal swell are improved by the dialkyl ethers. The removal of olefins and alcohols from the naphthas reduces refining and lead to a more salable product.

    摘要翻译: 存在于费 - 托轻石脑油中的烯烃和醇转化为下式的二烷基醚:ROR',其中R和R'各自主要是具有四个以上碳原子的非叔烷基,通过将烯烃水合成醇, 醇的脱水。 醚也可以通过烯烃和醇的直接反应形成。 通过蒸馏将醚与石脑油中的剩余链烷烃分离,并以1-25重量%的量加入。 %对通过加氢处理费 - 托产物而获得的链烷烃中间馏分燃料组分。 通过二烷基醚改善馏出物燃料组分的性质,如润滑性和密封膨胀。 从石脑油中除去烯烃和醇可以减少精炼并导致更可销售的产品。

    Process for converting heavy hydrocarbon feeds to high octane gasoline, BTX and other valuable aromatics
    4.
    发明授权
    Process for converting heavy hydrocarbon feeds to high octane gasoline, BTX and other valuable aromatics 有权
    将重质烃进料转化为高辛烷值汽油,BTX和其他有价值芳烃的方法

    公开(公告)号:US06900365B2

    公开(公告)日:2005-05-31

    申请号:US10011811

    申请日:2001-12-11

    IPC分类号: C10G35/06 C07C4/18

    CPC分类号: C10G35/065

    摘要: A catalytic hydrodealkylation/reforming process which comprises contacting a heavy hydrocarbon feedstream under catalytic hydrodealkylation/reforming conditions with a composition comprising borosilicate molecular sieves having a pore size greater than about 5.0 Angstroms and a Constraint Index smaller than about 1.0; further containing a hydrogenation/dehydrogenation component; wherein at least a portion of the heavy hydrocarbon feedstream is converted to a product comprising benzene, toluene, xylenes and ethylbenzene.

    摘要翻译: 催化加氢脱烷基/重整方法,其包括使催化加氢脱烷基/重整条件下的重烃进料流与包含孔径大于约5.0埃的硼硅酸盐分子筛和小于约1.0的约束指数的组合物接触; 还含有氢化/脱氢组分; 其中至少一部分重烃进料流转化成包含苯,甲苯,二甲苯和乙苯的产物。

    Ethylene manufacture by use of molecular redistribution on feedstock C3-5 components
    5.
    发明授权
    Ethylene manufacture by use of molecular redistribution on feedstock C3-5 components 有权
    通过在原料C3-5组分上使用分子重新分配来制备乙烯

    公开(公告)号:US06441263B1

    公开(公告)日:2002-08-27

    申请号:US09612045

    申请日:2000-07-07

    IPC分类号: C07C402

    摘要: A process for preparing an ethylene-rich composition from a C3-5 paraffinic feedstock is described. The C3-5 paraffinic feedstock is subjected to molecular redistribution via dehydrogenation to form olefins, metathesis of the olefins, and rehydrogenation of the olefins to form paraffins. The product stream includes ethane, which is isolated and sent to an ethane or ethane/propane cracker (or, alternatively, a flexi-cracker, although this is less cost effective) to yield an ethylene-rich composition. The product stream also includes C3-5 paraffins, which can be recycled, and C6+paraffins, which can be used, for example, as solvents. Alternatively, they can be isomerized to form gasoline additives, or can be converted to aromatic compounds by subjecting them to reforming conditions, for example using the AROMAX™ process or platforming or rheniforming conditions.

    摘要翻译: 描述了从C3-5石蜡原料制备富含乙烯的组合物的方法。 C3-5石蜡原料通过脱氢进行分子重新分配以形成烯烃,烯烃的复分解和烯烃的再氢化形成链烷烃。 产物流包括乙烷,其被分离并送入乙烷或乙烷/丙烷裂解器(或者可选地,柔性裂化器,尽管这样的成本效益较低)以产生富含乙烯的组合物。 产物流还包括可再循环的C3-5石蜡,以及可用作例如溶剂的C6 +石蜡。 或者,它们可以被异构化以形成汽油添加剂,或者可以通过使其转化为重整条件,例如使用AROMAX TM方法或平台化或浓缩条件,将其转化为芳族化合物。

    PROCESS AND CATALYSTS FOR REFORMING FISHER TROPSCH NAPHTHAS TO AROMATICS
    6.
    发明申请
    PROCESS AND CATALYSTS FOR REFORMING FISHER TROPSCH NAPHTHAS TO AROMATICS 审中-公开
    将渔船运送到芳香族的工艺和催化剂

    公开(公告)号:US20100160700A1

    公开(公告)日:2010-06-24

    申请号:US12338436

    申请日:2008-12-18

    IPC分类号: C07C2/00

    CPC分类号: C07C15/00 C07C2/76 C07C15/02

    摘要: Improved processes and catalysts are described for the conversion of oxygenate-containing olefinic Fischer Tropsch naphtha into aromatics. This involves removal of the oxygenates without complete saturation of the olefins followed by aromatization of the oxygenate-depleted olefinic naphtha preferably over a catalyst that is tolerant to oxygenates.

    摘要翻译: 描述了改进的方法和催化剂用于将含氧化合物的烯属费 - 托石脑油转化成芳族化合物。 这涉及去除含氧化合物而不完全饱和烯烃,然后优选在含氧化合物的烯烃石脑油的芳构化的范围内对耐受含氧化合物的催化剂进行芳族化。

    Conversion of refinery C5 paraffins into C4 and C6 paraffins
    7.
    发明授权
    Conversion of refinery C5 paraffins into C4 and C6 paraffins 失效
    炼油厂C5石蜡转化为C4和C6链烷烃

    公开(公告)号:US06566569B1

    公开(公告)日:2003-05-20

    申请号:US09603489

    申请日:2000-06-23

    IPC分类号: C07C500

    摘要: A process for preparing a C4- product stream and a C6+ product stream is disclosed. The process involves contacting a C5 containing paraffinic feedstock with a catalyst that includes a hydrogenation/dehydrogenation catalyst and an olefin metathesis catalyst under conditions which dehydrogenate the paraffins to olefins. The olefins are then metathesized and rehydrogenated to provide a product stream. A C4- fraction and a C6+ fraction can each be isolated from the product stream. The C4- fraction can be used, for example, in an alkylation reaction to provide compounds useful in gasoline compositions. Unconverted C5 paraffins can be recycled. The C6+ fraction can be used, for example, as solvents. Alternatively, they can be isomerized to form gasoline additives, or can be converted to aromatic compounds via reforming, for example, using conventional reforming techniques, preferably using the AROMAX™ process or traditional rheniforming conditions.

    摘要翻译: 公开了一种制备C4-产物流和C6 +产物流的方法。 该方法包括使含有C5的石蜡原料与包含氢化/脱氢催化剂和烯烃复分解催化剂的催化剂在使链烷烃脱氢成烯烃的条件下接触。 然后将烯烃进行复合和再氢化以提供产物流。 可以从产物流中分离出C4馏分和C6 +馏分。 C4馏分可用于例如烷基化反应以提供可用于汽油组合物中的化合物。 未转化的C5石蜡可以回收利用。 C6 +馏分可以用作例如溶剂。 或者,它们可以被异构化以形成汽油添加剂,或者可以通过重整转化为芳族化合物,例如使用常规的重整技术,优选使用AROMAX TM方法或传统的强化条件。

    Hydroconversion of renewable feedstocks
    9.
    发明授权
    Hydroconversion of renewable feedstocks 有权
    可再生原料的加氢转化

    公开(公告)号:US09199909B2

    公开(公告)日:2015-12-01

    申请号:US13315729

    申请日:2011-12-09

    申请人: Cong-Yan Chen

    发明人: Cong-Yan Chen

    摘要: A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with supported catalyst comprising at least one metal selected from the group consisting of Group VIII metals, Group VIB metals to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s).

    摘要翻译: 烃转化方法包括在加氢处理条件下使可再生原料与包含至少一种选自第Ⅷ族金属,第ⅥB族金属的金属的载体催化剂接触,以形成油化学物质如脂肪醇,酯和正链烷烃。 有利地,可以选择反应条件以将可再生原料直接转化为所需的产物。