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公开(公告)号:US20230155202A1
公开(公告)日:2023-05-18
申请号:US17906750
申请日:2021-03-23
申请人: BASF SE
发明人: Wolfgang ROHDE , Torben ADERMANN , Kerstin SCHIERLE-ARNDT , Nuria HUGUET SUBIELA , Andreas KEMPTER , Birgit GERKE
CPC分类号: H01M10/54 , C22B23/021 , C22B23/065 , C22B5/12 , C22B1/005
摘要: The present invention relates to a process for the recovery of transition metals from battery materials comprising (0.1) providing a battery material which comprises oxidic nickel and/or cobalt compounds, (1.1) heating the battery material above 350° C. to yield a reduced material which contains nickel and/or cobalt in elemental form, (2.1) carbonylating the reduced material with carbon monoxide optionally in the presence of a reactive gas to yield a solid carbonylation residue and a volatile carbonyl which comprises nickel and/or cobalt carbonyl containing compounds, and (3.1) separating the volatile carbonyl from the solid carbonylation residue by evaporation.
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公开(公告)号:US20220251681A1
公开(公告)日:2022-08-11
申请号:US17625753
申请日:2020-07-24
申请人: BASF SE
发明人: Wolfgang ROHDE , Birgit GERKE , Regina VOGELSANG , Matthias VOGES , Kerstin SCHIERLE-ARNDT , Fabian SEELER , Torben ADERMANN
摘要: A process for the recovery of one or more transition metals and lithium from waste lithium ion batteries or parts thereof is disclosed. The process comprising the steps of (a) providing a particulate material containing a transition metal compound and/or transition metal, wherein the transition metal is selected from the group consisting of Ni and Co, and wherein further at least a fraction of said Ni and/or Co, if present, are in an oxidation state lower than +2, e.g. in the metallic state; which particulate material further contains a lithium salt; (b) treating the material provided in step (a) with a polar solvent and optionally an alkaline earth hydroxide; (c) separating the solids from the liquid, optionally followed by a solid-solid separation step; and (d) treating the solids containing the transition metal in a way to dissolve at least part of the Ni and/or Co, typically using a mineral acid, provides good separation of lithium in high purity and of transition metal useful for the production of battery cathode active materials.
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公开(公告)号:US20220352570A1
公开(公告)日:2022-11-03
申请号:US17625788
申请日:2020-07-24
申请人: BASF SE
发明人: Wolfgang ROHDE , Birgit GERKE , Kerstin SCHIERLE-ARNDT , Matthias VOGES , Regina VOGELSANG , Fabian SEELER , Gareth SMITH , Torben ADERMANN
摘要: A process for the recovery of one or more transition metals and lithium from waste lithium ion batteries or parts thereof is disclosed. The process comprising the steps of (a) providing a particulate material containing a transition metal compound and/or transition metal, wherein the transition metal is selected from the group consisting of Ni and Co, and wherein further at least a fraction of said Ni and/or Co, if present, are in an oxidation state lower than +2, e.g. in the metallic state; which particulate material further contains a lithium salt; (b) treating the material provided in step (a) with a polar solvent and optionally an alkaline earth hydroxide; (c) separating the solids from the liquid, optionally followed by a solid-solid separation step; and (d) treating the solids containing the transition metal in a smelting furnace to obtain a metal melt containing Ni and/or Co provides good separation of transition metal as alloy and of lithium in high purity.
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公开(公告)号:US20220340518A1
公开(公告)日:2022-10-27
申请号:US17766035
申请日:2020-09-22
申请人: BASF SE
发明人: Frank PIEPENBREIER , Andreas KEMPTER , Chee Jian CHAN , Rosario MAZARRO BERDONCES , Kerstin SCHIERLE-ARNDT , Bjoern KAIBEL , Jan SPIELMANN , Frieder BORGMEIER , Michael ZEILINGER , Ingo BIERTUEMPEL , Timo OTT
IPC分类号: C07C303/06
摘要: The present invention relates to an improved process for manufacturing of alkanesulfonic acids.
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公开(公告)号:US20220136084A1
公开(公告)日:2022-05-05
申请号:US16956516
申请日:2018-12-10
申请人: BASF SE
发明人: Wolfgang ROHDE , Michael ZEILINGER , Torben ADERMANN , Sabine WEIGUNY , Fabian SEELER , Kerstin SCHIERLE-ARNDT , Thomas Michael RYLL
摘要: Process for the recovery of transition metal from cathode active materials containing nickel and lithium, wherein said process comprises the steps of (a) treating a lithium containing transition metal oxide material with a leaching agent (preferably an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid), (b) adjusting the pH value to 2.5 to 8, and (c) treating the solution obtained in step (b)with metallic nickel, cobalt or manganese or a combination of at least two of the foregoing.
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公开(公告)号:US20210147960A1
公开(公告)日:2021-05-20
申请号:US17046766
申请日:2019-04-01
申请人: BASF SE
发明人: Wolfgang ROHDE , Torben ADERMANN , Thomas Michael RYLL , Kerstin SCHIERLE-ARNDT , Fabian SEELER , Sabine WEIGUNY , Michael ZEILINGER
摘要: Process for the recovery of transition metal from spent lithium ion batteries containing nickel, wherein said process comprises the steps of (a) heating a lithium containing transition metal oxide material to a temperature in the range of from 400 to 1200° C., (b) treating said heat-treated material with water, (c) treating the solid residue from step (b)with an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid, (d) adjusting the pH value to 2.5 to 8, (e) removing compounds of Al, Cu, Fe, Zn or combinations of at least two of the foregoing from the solution or slurry obtained in step (d).
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公开(公告)号:US20170009749A1
公开(公告)日:2017-01-12
申请号:US15113125
申请日:2015-01-23
申请人: BASF SE
发明人: Jüergen WORTMANN , Michael LUTZ , Katharina FEDERSEL , Kerstin SCHIERLE-ARNDT , Stephan MAURER , Michael LADENBERGER
CPC分类号: F03G6/005 , F03G6/06 , F24S10/30 , F24S20/20 , F24S40/00 , F24S60/00 , F24S90/00 , Y02E10/41 , Y02E10/46
摘要: The invention relates to a pipeline system for a linearly concentrating solar power plant (1) with at least one receiver line (13), in which a heat transfer medium is heated by radiating solar energy, or with a central receiver and at least one emptying tank (21) and/or one store for the heat transfer medium, the heat transfer medium having a vapor pressure of less than 0.5 bar at the maximum operating temperature. Furthermore, a gas displacement system (31) is comprised, which connects gas spaces in the at least one emptying tank (21) and/or in the store for the heat transfer medium to one another and which has a central gas store (35) and/or a central gas connection (37) and a central exhaust gas outlet (39), through which gas can be discharged into the surroundings.
摘要翻译: 本发明涉及一种用于具有至少一个接收线(13)的线性集中太阳能发电厂(1)的管道系统,其中传热介质通过辐射太阳能加热,或与中央接收器一起加热,并且至少一个排空 罐(21)和/或用于传热介质的一个储存器,传热介质在最大工作温度下具有小于0.5巴的蒸气压。 此外,包括气体置换系统(31),其将至少一个排空罐(21)中的空间和/或用于传热介质的储存器彼此连接并具有中央气体储存器(35) 和/或中央气体连接(37)和中央排气出口(39),气体可以通过该排气口排出到周围。
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公开(公告)号:US20230046318A1
公开(公告)日:2023-02-16
申请号:US17778429
申请日:2020-11-16
申请人: BASF SE , Wayne State University
发明人: Sinja Verena KLENK , Alexander Georg HUFNNAGEL , Hagen WILMER , Daniel LÖFFLER , Sabine WEIGUNY , Kerstin SCHIERLE-ARNDT , Charles Hartger WINTER , Nilanka WEERATHUNGA SIRIKKATHUGE
IPC分类号: C23C16/455 , C23C16/18
摘要: The present invention is in the field of processes for preparing inorganic metal- or semimetal-containing films. The process for preparing inorganic metal- or semimetal-containing films comprising (a) depositing a metal- or semimetal-containing compound from the gaseous state onto a solid substrate and (b) bringing the solid substrate with the deposited metal- or semimetal-containing compound in contact with a compound of general formula (I) or (II) wherein Z is NR2, PR2, OR, SR, CR2, SiR2, X is H, R′ or NR′2, wherein at least one X is H, n is 1 or 2, and R and R′ is an alkyl group, an alkenyl group, an aryl group, or a silyl group.
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公开(公告)号:US20190198206A1
公开(公告)日:2019-06-27
申请号:US16328912
申请日:2017-08-31
申请人: BASF SE
发明人: Johan TER MAAT , Sumohan MISRA , David VAN ASTEN , Bernard REESINK , Wilfried HERMES , Michael ZEILINGER , Fabian SEELER , Kerstin SCHIERLE-ARNDT , Ekkehard BRUECK , Van Thang NGUYEN
CPC分类号: H01F1/015 , C22C30/00 , C22C2202/02 , F25B21/00 , F25B2321/002 , H01F41/00 , Y02B30/66
摘要: Described are a kit comprising at least two magnetocaloric materials having identical stoichiometry but different Curie temperature, a magnetocaloric regenerator comprising at least two magnetocaloric materials having identical stoichiometry but different Curie temperature and a process for producing at least two magnetocaloric materials having identical stoichiometry but different Curie temperature.
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公开(公告)号:US20180346501A1
公开(公告)日:2018-12-06
申请号:US15779893
申请日:2016-11-30
发明人: Torben ADERMANN , Daniel LOEFFLER , Hagen WILMER , Kerstin SCHIERLE-ARNDT , Jan GERKENS , Christian VOLKMANN , Sven SCHNEIDER
摘要: The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. The present invention relates to a process comprising bringing a compound of general formula (I) into the gaseous or aerosol state and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein M is Mn, Ni or Co, X is a ligand which coordinates M, n is 0, 1, or 2, R 1, R2 are an alkyl group, an alkenyl group, an aryl group or a silyl group, m is 1, 2, or 3, R3, R4, and R5 are an alkyl group, an alkenyl group, an aryl group, an alkoxy group, or an aryloxy group, and p is 1, 2 or 3.
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