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公开(公告)号:US20200161652A1
公开(公告)日:2020-05-21
申请号:US16627884
申请日:2018-07-05
申请人: BASF SE
IPC分类号: H01M4/525 , H01M4/505 , H01M10/052 , C01G53/00
摘要: Process for making an electrode active material according to general formula Li1+χTM1−χO2, wherein TM is a combination of Mn, Co and Ni in combination with at least one more metal selected from Al, Ti, and W, wherein at least 60 mole-% of TM is Ni, the percentage referring to the sum of Ni, Co and Mn, and x is in the range of from zero to 0.2, said process comprising the following steps: (a) mixing (A) a mixed oxide or oxyhydroxide of Mn, Co and Ni, (B) at least one lithium compound selected from lithium hydroxide, lithium oxide and lithium carbonate, and (C) an oxide, hydroxide or oxyhydroxide of Al, Ti or W, (b) Subjecting said mixture to heat treatment at a temperature in the range of from 700 to 1000° C.
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公开(公告)号:US20200303735A1
公开(公告)日:2020-09-24
申请号:US16652188
申请日:2018-09-18
摘要: The present invention is related to an electrode active material for a lithium-ion battery of general formula (I): Li1+x(NiaCobMncMd)1−xO2 wherein x is in the range of from zero to 0.1, a is in the range of from 0.1 to 0.5, b is in the range of from 0.4 to 0.9, c is in the range of from zero to 0.3, d is in the range of from zero to 0.1, M is selected from Al, B, Mg, W, Mo, Ti, Si and Zr, with a+b+c+d=1 and a>c. In addition, the present invention is related to a method of manufacture of electrode active materials and to their use.
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3.
公开(公告)号:US20180358615A1
公开(公告)日:2018-12-13
申请号:US15751308
申请日:2016-08-10
申请人: BASF SE
IPC分类号: H01M4/525 , H01M10/0525 , H01M4/505 , C01G53/00 , C01G53/04
摘要: The present invention is directed towards a process for making a particulate material according to the general formula (I): NiaCObMncMd(O)x(OH)y, wherein M is selected from Al and Ti, x is in the range of from 0.01 to 0.9, y is in the range of from 1.1 to 1.99, a is in the range of from 0.3 to 0.85, b is in the range of from 0.05 to 0.4, c is in the range of from 0.1 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) providing an aqueous slurry of particles of aluminum hydroxide or titanium dioxide, (b) adding an aqueous solution of water-soluble salts of nickel, cobalt and manganese and a solution of alkali metal hydroxide to the slurry according to step (a), thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese hydroxide on the particles according to step (a), (c) removing particles of (NiaCObMncAld)(OH)2+d or (NiaCObMncTid)(OH)2+2d so obtained and drying them in the presence of oxygen.
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公开(公告)号:US20170355614A1
公开(公告)日:2017-12-14
申请号:US15524898
申请日:2015-10-30
申请人: BASF SE
IPC分类号: C01G53/00 , H01M4/525 , H01M4/485 , H01M4/505 , H01M10/0525
CPC分类号: C01G53/006 , C01G53/44 , C01P2004/03 , C01P2004/61 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0525
摘要: A process is described for producing mixed oxide in particulate form, comprising cations of lithium and cations of at least two transition metals selected from the group consisting of nickel, cobalt, manganese, titanium, vanadium, chromium and iron, as are mixed oxides produced by this process.
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公开(公告)号:US20220136084A1
公开(公告)日:2022-05-05
申请号:US16956516
申请日:2018-12-10
申请人: BASF SE
发明人: Wolfgang ROHDE , Michael ZEILINGER , Torben ADERMANN , Sabine WEIGUNY , Fabian SEELER , Kerstin SCHIERLE-ARNDT , Thomas Michael RYLL
摘要: Process for the recovery of transition metal from cathode active materials containing nickel and lithium, wherein said process comprises the steps of (a) treating a lithium containing transition metal oxide material with a leaching agent (preferably an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid), (b) adjusting the pH value to 2.5 to 8, and (c) treating the solution obtained in step (b)with metallic nickel, cobalt or manganese or a combination of at least two of the foregoing.
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公开(公告)号:US20210147960A1
公开(公告)日:2021-05-20
申请号:US17046766
申请日:2019-04-01
申请人: BASF SE
发明人: Wolfgang ROHDE , Torben ADERMANN , Thomas Michael RYLL , Kerstin SCHIERLE-ARNDT , Fabian SEELER , Sabine WEIGUNY , Michael ZEILINGER
摘要: Process for the recovery of transition metal from spent lithium ion batteries containing nickel, wherein said process comprises the steps of (a) heating a lithium containing transition metal oxide material to a temperature in the range of from 400 to 1200° C., (b) treating said heat-treated material with water, (c) treating the solid residue from step (b)with an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid, (d) adjusting the pH value to 2.5 to 8, (e) removing compounds of Al, Cu, Fe, Zn or combinations of at least two of the foregoing from the solution or slurry obtained in step (d).
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公开(公告)号:US20190386305A1
公开(公告)日:2019-12-19
申请号:US16509749
申请日:2019-07-12
申请人: BASF SE
发明人: Aleksei VOLKOV , Jordan LAMPERT , Thomas Michael RYLL , Ji-Yong SHIN , Markus HOELZLE , Michael EDER
IPC分类号: H01M4/525 , H01M10/0567 , H01M10/42 , C01G53/00 , H01M4/505 , H01M10/0525
摘要: Process for making a particulate material of general formula (I), Li1+x(NiaCobMncMd)1−xO2 (I) wherein the integers are defined as follows: M is selected from Al and Ti, x is in the range of from 0.015 to 0.03, a is in the range of from 0.3 to 0.6, b is in the range of from 0.05 to 0.35, c is in the range of from 0.2 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) co-precipitating a mixed hydroxide of nickel, cobalt and manganese from a solution of water-soluble salts of nickel, cobalt and manganese by contacting such solution with a solution of alkali metal hydroxide, (b) adding an aqueous solution of an aluminate or titanate and thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese and aluminium or titanium on the particles formed in step (a), (c) removing particles of (NiaCobMncAld)(OH)2+d or (NiaCobMncTid)(OH)2+2d so obtained and drying them in the presence of oxygen, (d) mixing the particles obtained in step (c) with at least one Li compound selected from Li2O, LiOH and Li2CO3, (e) calcining the mixture obtained according to step (d) at a temperature in the range of from 920 to 950° C.
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公开(公告)号:US20180114985A1
公开(公告)日:2018-04-26
申请号:US15318887
申请日:2015-06-19
申请人: BASF SE
发明人: Aleksei VOLKOV , Jordan LAMPERT , Thomas Michael RYLL , Ji-Yong SHIN , Markus HOELZLE , Michael EDER
IPC分类号: H01M4/525 , H01M10/0525 , H01M10/0567 , H01M4/505 , H01M10/42 , C01G53/00
CPC分类号: H01M4/525 , C01G53/006 , C01G53/50 , C01P2002/50 , C01P2002/88 , C01P2004/32 , C01P2004/51 , C01P2004/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/131 , H01M4/505 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/4235 , H01M2004/028 , H01M2300/0025
摘要: Li1+x(NiaCobMncMd)1−xO2 (I) Process for making a particulate material of general formula (I), wherein the integers are defined as follows: M is selected from Al and Ti, x is in the range of from 0.015 to 0.03, a is in the range of from 0.3 to 0.6, b is in the range of from 0.05 to 0.35, c is in the range of from 0.2 to 0.5, d is in the range of from 0.001 to 0.03, with a+b+c+d=1 said process comprising the following steps: (a) co-precipitating a mixed hydroxide of nickel, cobalt and manganese from a solution of water-soluble salts of nickel, cobalt and manganese by contacting such solution with a solution of alkali metal hydroxide, (b) adding an aqueous solution of an aluminate or titanate and thereby co-precipitating a layer of a mixed hydroxide of nickel and cobalt and manganese and aluminium or titanium on the particles formed in step (a), (c)removing particles of (Nia Cob Mnc Ald)(OH)2+d or (Nia Cob Mnc Tid)(OH)2−2d so obtained and drying them in the presence of oxygen, (d) mixing the particles obtained in step (c) with at least one Li compound selected from Li2O, LiOH and Li2CO3, (e) calcining the mixture obtained according to step (d) at a temperature in the range of from 920 to 950° C.
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