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公开(公告)号：US11167273B2
公开(公告)日：2021-11-09
申请号：US16652875
申请日：2018-10-02
申请人： BASF Corporation
发明人： Xiaolai Zheng , Patrick Burk
IPC分类号： B01J23/83 , B01J23/20 , B01J23/30 , B01J23/34 , B01J23/44 , B01J23/46 , B01J35/00 , B01J35/04 , F01N3/10 , F01N3/20 , F01N3/28
摘要： The present disclosure provides SCR catalyst compositions, catalyst articles, and catalyst systems, as well as methods of reducing the amount of NOx present in an engine exhaust gas, particularly exhaust from a gasoline engine. The catalyst compositions particularly can comprise a doped ceria substrate, particularly a ceria support doped with at least a niobia component, and optionally further doped with a further material, particularly a base metal oxide (BMO).
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公开(公告)号：US20200055035A1
公开(公告)日：2020-02-20
申请号：US16487447
申请日：2018-02-21
发明人： Xiaolai Zheng , Mahmuda Choudhury , Patrick Burk , Makoto Nagata , Yasuharu Kanno , Hiroki Nakayama
摘要： The invention provides a selective catalytic reduction (SCR) catalyst effective in the abatement of nitrogen oxides (NOx), the SCR catalyst comprising a metal-promoted molecular sieve promoted with a metal selected from iron, copper, and combinations thereof, wherein the metal is present in an amount of 2.6% by weight or less on an oxide basis based on the total weight of the metal-promoted molecular sieve. A catalyst article, an exhaust gas treatment system method, and a method treating an exhaust gas stream, each comprising the SCR catalyst of the invention, are also provided. The SCR catalyst is particularly useful for treatment of exhaust from a lean burn gasoline engine.
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公开(公告)号：US20140219879A1
公开(公告)日：2014-08-07
申请号：US14245712
申请日：2014-04-04
申请人： BASF Corporation
发明人： Ivor Bull , Wen-Mei Xue , Patrick Burk , R. Samuel Boorse , William M. Jaglowski , Gerald Stephen Koermer , Ahmad Moini , Joseph A. Patchett , Joseph C. Dettling , Matthew Tyler Caudle
IPC分类号： B01J29/74
CPC分类号： B01J29/723 , B01D53/56 , B01D53/8628 , B01D53/9413 , B01D53/9418 , B01D53/9431 , B01D53/9477 , B01D2251/206 , B01D2251/2062 , B01D2251/2067 , B01D2255/20715 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9032 , B01D2255/904 , B01D2255/9155 , B01D2257/40 , B01D2257/404 , B01D2258/012 , B01J23/42 , B01J23/8926 , B01J29/061 , B01J29/068 , B01J29/072 , B01J29/743 , B01J29/76 , B01J29/763 , B01J29/80 , B01J35/0006 , B01J35/04 , B01J37/0246 , B01J2029/062 , C01B39/46 , Y02C20/10 , Y02T10/24 , Y10T428/24149
摘要： Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
摘要翻译： 公开了沸石催化剂和制备和使用具有CHA晶体结构的沸石催化剂的体系和方法。 催化剂可用于在宽温度范围内从气态介质中除去氮氧化物，并在高反应温度下表现出水热稳定性。 沸石催化剂包括具有约15:1至约256:1的二氧化硅与氧化铝的沸石载体，铜与氧化铝的比例为约0.25:1至约1:1。
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公开(公告)号：US11529619B2
公开(公告)日：2022-12-20
申请号：US16855514
申请日：2020-04-22
申请人： BASF CORPORATION
发明人： Ivor Bull , Wen-Mei Xue , Patrick Burk , R. Samuel Boorse , William M. Jaglowski , Gerald Stephen Koermer , Ahmad Moini , Joseph A. Patchett , Joseph C. Dettling , Matthew Tyler Caudle
IPC分类号： B01J29/06 , B01J29/72 , B01J29/068 , B01D53/56 , B01D53/94 , B01J23/42 , B01J23/89 , B01J29/072 , B01J29/76 , B01J35/00 , B01J35/04 , B01J37/02 , B01J29/74 , B01D53/86 , B01J29/80 , C01B39/46
摘要： Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
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公开(公告)号：US10654031B2
公开(公告)日：2020-05-19
申请号：US15806167
申请日：2017-11-07
申请人： BASF CORPORATION
发明人： Ivor Bull , Wen-Mei Xue , Patrick Burk , R. Samuel Boorse , William M. Jaglowski , Gerald Stephen Koermer , Ahmad Moini , Joseph A. Patchett , Joseph C. Dettling , Matthew Tyler Caudle
IPC分类号： B01J29/06 , B01J29/72 , B01J29/068 , B01D53/56 , B01D53/94 , B01J23/42 , B01J23/89 , B01J29/072 , B01J29/76 , B01J35/00 , B01J35/04 , B01J37/02 , B01J29/74 , B01D53/86 , B01J29/80 , C01B39/46
摘要： Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
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公开(公告)号：US09656254B2
公开(公告)日：2017-05-23
申请号：US14973353
申请日：2015-12-17
申请人： BASF CORPORATION
发明人： Ivor Bull , Wen-Mei Xue , Patrick Burk , R. Samuel Boorse , William M. Jaglowski , Gerald Stephen Koermer , Ahmad Moini , Joseph A. Patchett , Joseph C. Dettling , Matthew Tyler Caudle
IPC分类号： B01J29/06 , B01J29/72 , B01J29/068 , B01D53/94 , B01J23/42 , B01J23/89 , B01J29/072 , B01J29/76 , B01J35/00 , B01J35/04 , B01J37/02 , B01J29/74 , B01D53/86 , B01J29/80 , C01B39/46
CPC分类号： B01J29/723 , B01D53/56 , B01D53/8628 , B01D53/9413 , B01D53/9418 , B01D53/9431 , B01D53/9477 , B01D2251/206 , B01D2251/2062 , B01D2251/2067 , B01D2255/20715 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9032 , B01D2255/904 , B01D2255/9155 , B01D2257/40 , B01D2257/404 , B01D2258/012 , B01J23/42 , B01J23/8926 , B01J29/061 , B01J29/068 , B01J29/072 , B01J29/743 , B01J29/76 , B01J29/763 , B01J29/80 , B01J35/0006 , B01J35/04 , B01J37/0246 , B01J2029/062 , C01B39/46 , Y02T10/24 , Y10T428/24149
摘要： Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
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公开(公告)号：US20140360171A1
公开(公告)日：2014-12-11
申请号：US14467250
申请日：2014-08-25
申请人： BASF Corporation
发明人： Wen-Mei Xue , Xinyi Wei , Marcus Hilgendorff , Patrick Burk
CPC分类号： F01N3/2066 , B01D53/94 , B01D53/9418 , B01D53/944 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1028 , B01D2255/2042 , B01D2255/2065 , B01D2255/9022 , B01D2255/91 , B01D2258/012 , B01J23/002 , B01J23/10 , B01J23/63 , B01J27/232 , B01J35/0006 , B01J35/0013 , B01J35/002 , B01J35/023 , B01J35/04 , B01J35/1009 , B01J35/1014 , B01J37/0201 , B01J37/0248 , B01J37/10 , B01J2523/00 , F01N3/035 , F01N3/101 , F01N2250/02 , F01N2610/02 , Y02C20/10 , Y02T10/22 , B01J2523/22 , B01J2523/25 , B01J2523/31 , B01J2523/3712 , B01J2523/48 , B01J2523/824 , B01J2523/828
摘要： A catalyst for the treatment of exhaust gas emissions is disclosed. The catalyst can comprise ceria-alumina particles having a ceria phase present in a weight percent of the composite in the range of about 20% to about 80% on an oxide basis, an alkaline earth metal component supported on the ceria-alumina particles, wherein the CeO2 is present in the form of crystallites that are hydrothermally stable and have an average crystallite size less than 160 Å after aging at 950° C. for 5 hours in 2% O2 and 10% steam in N2.
摘要翻译： 公开了一种用于处理废气排放的催化剂。 该催化剂可以包括二氧化铈 - 氧化铝颗粒，二氧化铈相以氧化物为基准存在于复合材料的重量百分比范围为约20％至约80％的二氧化铈相，负载在二氧化铈 - 氧化铝颗粒上的碱土金属组分，其中 CeO 2以水热稳定的形式存在，并且在950℃下在2％O 2和10％蒸气在N 2中老化5小时后具有小于160的平均微晶尺寸。
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8.发明申请NOx Storage Catalyst with lmproved Hydrothermal Stability and NOx Conversion 有权具有改进的水热稳定性和NOx转化的NOx储存催化剂公开(公告)号：US20140260214A1
公开(公告)日：2014-09-18
申请号：US14204386
申请日：2014-03-11
申请人： BASF Corporation
发明人： Wen-Mei Xue , Xinyi Wei , Marcus Hilgendorff , Patrick Burk
IPC分类号： B01J27/232
CPC分类号： B01J23/10 , B01D53/9422 , B01D53/9481 , B01D2255/102 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1028 , B01D2255/2042 , B01D2255/2065 , B01D2255/40 , B01D2255/9022 , B01D2255/91 , B01D2258/012 , B01J23/63 , B01J35/0006 , B01J35/002 , B01J35/023 , B01J37/0201 , B01J37/0244 , B01J37/0248 , B01J37/10 , B01J2523/00 , B01J2523/22 , B01J2523/25 , B01J2523/31 , B01J2523/3712 , B01J2523/48 , B01J2523/824 , B01J2523/828
摘要： A lean NOx trap for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO), and the trapping and reduction of nitrogen oxides (NOx) is disclosed. Nitrogen oxide storage catalysts can comprise a layer on a substrate including ceria-alumina particles having a ceria phase present in a weight percent of the composite in the range of about 20% to about 80% on an oxide basis, an alkaline earth metal component supported on the ceria-alumina particles, wherein the CeO2 is present in the form of crystallites that are hydrothermally stable and have an average crystallite size less than 130 Å after aging at 950° C. for 5 hours in 2% O2 and 10% steam in N2.
摘要翻译： 公开了用于处理废气排放的贫NOx捕集器，例如未燃烧的烃（HC）和一氧化碳（CO）的氧化，以及氮氧化物（NOx）的捕获和还原。 氮氧化物储存催化剂可以包括在基底上的包括二氧化铈 - 氧化铝颗粒的二氧化铈 - 氧化铝颗粒，所述二氧化铈 - 氧化铝颗粒的二氧化铈相以所述复合材料的重量百分比存在于基于氧化物的约20％至约80％的范围内，碱土金属组分被负载 在二氧化铈 - 氧化铝颗粒上，其中CeO 2以水热稳定的形式存在，并且在950℃下在2％O 2和10％蒸汽中在950℃老化5小时后具有小于130的平均微晶尺寸 N2。
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9.发明申请公开(公告)号：US20170333883A1
公开(公告)日：2017-11-23
申请号：US15522440
申请日：2015-10-30
申请人： BASF Corporation
发明人： Jaya L. Mohanan , Jeff Yang , Patrick Burk , Kenneth E. Voss
摘要： Described are compositions and catalytic articles comprising both a first molecular sieve promoted with copper and a second molecular sieve promoted with iron, the first and second molecular sieves having a d6r unit and the first molecular sieves having cubic shaped crystals with an average crystal size of about 0.5 to about 2 microns. The weight ratio of the copper-promoted molecular sieve to the iron-promoted molecular sieve can be about 1:1 to about 4:1. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.
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公开(公告)号：US09611774B2
公开(公告)日：2017-04-04
申请号：US14467250
申请日：2014-08-25
申请人： BASF Corporation
发明人： Wen-Mei Xue , Xinyi Wei , Marcus Hilgendorff , Patrick Burk
IPC分类号： B01D50/00 , F01N3/20 , B01J27/232 , B01D53/94 , F01N3/10 , F01N3/035 , B01J37/02 , B01J35/00 , B01J23/63 , B01J35/02 , B01J23/00 , B01J23/10 , B01J37/10 , B01J35/04 , B01J35/10
CPC分类号： F01N3/2066 , B01D53/94 , B01D53/9418 , B01D53/944 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1028 , B01D2255/2042 , B01D2255/2065 , B01D2255/9022 , B01D2255/91 , B01D2258/012 , B01J23/002 , B01J23/10 , B01J23/63 , B01J27/232 , B01J35/0006 , B01J35/0013 , B01J35/002 , B01J35/023 , B01J35/04 , B01J35/1009 , B01J35/1014 , B01J37/0201 , B01J37/0248 , B01J37/10 , B01J2523/00 , F01N3/035 , F01N3/101 , F01N2250/02 , F01N2610/02 , Y02C20/10 , Y02T10/22 , B01J2523/22 , B01J2523/25 , B01J2523/31 , B01J2523/3712 , B01J2523/48 , B01J2523/824 , B01J2523/828
摘要： A catalyst for the treatment of exhaust gas emissions is disclosed. The catalyst can comprise ceria-alumina particles having a ceria phase present in a weight percent of the composite in the range of about 20% to about 80% on an oxide basis, an alkaline earth metal component supported on the ceria-alumina particles, wherein the CeO2 is present in the form of crystallites that are hydrothermally stable and have an average crystallite size less than 160 Å after aging at 950° C. for 5 hours in 2% O2 and 10% steam in N2.
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