公开(公告)号：US20230286839A1

公开(公告)日：2023-09-14

申请号：US18007066

申请日：2021-07-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Herbert Koenigsmann ,  Stefan Huber ,  Valentina Krupp ,  Scott D. Schmick ,  Zhongxing Zhang

IPC: C02F1/54 ,  C08F6/16 ,  C02F1/26

CPC classification number: C02F1/54 ,  C08F6/16 ,  C02F1/26 ,  C02F2101/36

Abstract: The present disclosure provides a process for removing fluoroorganic acidic compounds from an emulsion of fluoroorganic polymer particles, the process comprising the following steps: (i) forming a mixture of a. an emulsion comprising fluoroorganic polymer particles, at least one fluoroorganic acidic compound and at least one protic solvent, with b. at least one alkylamine; (ii) reacting the fluoroorganic acidic compound with the alkylamine to form a hydrophobic ionic compound comprising the anion of the fluoroorganic acidic compound and the cation of the alkyl amine; (iii) separating the mixture into a first phase comprising the at least one protic solvent and no greater than 80% by weight, preferably no greater than 50% by weight of the total amount of the at least one fluoroorganic acidic compound initially present in the solution in step (i); and a second phase comprising the hydrophobic ionic compound; (iva) removing the first phase from the second phase; and then (va) removing the fluoroorganic polymer particles from the second phase and/or the first phase, or (ivb) removing the fluoroorganic polymer particles from the second phase and/or the first phase, and then (vb) removing the first phase from the second phase.

公开(公告)号：US20240018084A1

公开(公告)日：2024-01-18

申请号：US18018282

申请日：2021-07-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Stefan Huber ,  Valentina Krupp ,  Herbert Koenigsmann ,  Scott D. Schmick ,  Zhongxing Zhang ,  Michael D. Barrera ,  William M. Lamanna ,  Chetan P. Jariwala ,  Markus Hirschberg

IPC: C07C51/48 ,  C02F1/26

CPC classification number: C07C51/48 ,  C02F1/26 ,  C02F2303/16 ,  C02F2101/36

Abstract: The present disclosure provides a process for removing fluoroorganic acidic compounds from a solution comprising at least one protic solvent, comprising: forming a mixture of a solution comprising at least one fluoroorganic acidic compound comprising less than 15 carbon atoms and protic solvent, wherein the solution has a pH of 4, with an extraction composition comprising at least one trialkylamine and organic solvent; reacting the fluoroorganic acidic compound with the trialkylamine to form a hydrophobic ionic compound comprising the anion of the fluoroorganic acidic compound and the cation of the trialkylamine; separating the mixture into a first phase comprising the protic solvent and at most 50 wt. % of the fluoroorganic acidic compound present in the initial solution; and a second phase comprising the organic solvent and hydrophobic ionic compound; removing the second phase from the first phase; and repeating steps aforementioned at least once more, wherein the first phase obtained in the last step is used as the initial solution.

公开(公告)号：US20230312776A1

公开(公告)日：2023-10-05

申请号：US18007062

申请日：2021-07-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Michael C. Dadalas ,  Stefan Huber ,  Valentina Krupp ,  Zhongxing Zhang

IPC: C08F6/24

CPC classification number: C08F6/24

Abstract: The present disclosure provides a process for removing fluoroorganic acidic compounds from a dispersion of fluoroorganic polymer particles in at least one protic solvent, the process comprising the following steps: (i) forming a mixture of a. a dispersion having a pH-value of less than 6 and comprising fluoroorganic polymer particles, at least one protic solvent and at least one fluoroorganic acidic compound with b. an extraction composition comprising at least one alkylamine; (ii) reacting the fluoroorganic acidic compound with the alkylamine to form a hydrophobic ionic compound comprising the anion of the fluoroorganic acidic compound and the cation of the alkyl amine; (iii) separating the mixture into a first phase comprising the at least one protic solvent, the fluoroorganic polymer particles and no greater than 50% by weight of the total amount of the at least one fluoroorganic acidic compound initially present in the dispersion in step (i); and a second phase comprising the hydrophobic ionic compound; and (iv) removing the first phase from the second phase.

公开(公告)号：US20200255714A1

公开(公告)日：2020-08-13

申请号：US16755896

申请日：2018-10-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Sean Michael Smith ,  Karl Joseph Warren ,  Zhongxing Zhang

IPC: C09K5/10 ,  C07D303/08 ,  B23K1/015

Abstract: A composition includes a hydrofluoroepoxide having Structural Formula (I). Each Rf is, independently, a linear or branched perfluoroalkyl group having 1-6 carbon atoms and optionally comprises a catenated heteroatom.

公开(公告)号：US20170369755A1

公开(公告)日：2017-12-28

申请号：US15533770

申请日：2015-12-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Zhongxing Zhang

IPC: C09K5/10 ,  C07C21/18 ,  H01L21/67 ,  B23K1/012

CPC classification number: C09K5/10 ,  B23K1/012 ,  C07C21/18 ,  C09K5/00 ,  H01L21/67109

Abstract: A composition that includes a hydrofluoroolefin represented by the following general formula (I): Rf—CH2CH—CHCH2-Rf (I). Rf is a perfluoroalkyl group having 6 carbon atoms, and the hydrofluoroolefin is a liquid at room temperature.

公开(公告)号：US20140311146A1

公开(公告)日：2014-10-23

申请号：US14007057

申请日：2012-03-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Bamidele Fayemi ,  Zhongxing Zhang ,  Michael G. Costello ,  Michael J. Bulinski ,  John G. Owens ,  Phillip E. Tuma ,  Richard M. Minday ,  Richard M. Flynn

IPC: F01K25/08

CPC classification number: F01K25/08 ,  C07D303/08 ,  C07D303/48 ,  C09K5/04 ,  F01K25/10

Abstract: A process and an apparatus for converting thermal energy into mechanical energy in a Rankine cycle is provided. The process and apparatus include a working fluid that comprises a fluorinated oxirane. The fluorinated oxirane can contain substantially no hydrogen atoms bonded to carbon atoms and can have from about 4 to about 9 carbon atoms. The process can drive a turbine and, in some embodiments, generate electricity.

Abstract translation: 提供了一种在兰金循环中将热能转换为机械能的方法和装置。 该方法和装置包括包含氟化环氧乙烷的工作流体。 氟化环氧乙烷可以基本上不含有与碳原子键合的氢原子，并且可以具有约4-约9个碳原子。 该过程可以驱动涡轮机，并且在一些实施例中，发电。