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公开(公告)号:US11793731B2
公开(公告)日:2023-10-24
申请号:US16954726
申请日:2018-12-19
发明人: Gregory A. Kobussen , Ahmed S. Abuelyaman , Paul J. Homnick , Bradley D. Craig , Ying Lin , Hassan Sahouani , Chuntao Cao , William H. Moser , Kolby L. White , Joseph D. Rule , Joachim Zech
IPC分类号: A61K6/30 , A61K6/77 , A61K6/887 , A61K6/76 , A61K6/62 , C08K3/22 , C08K3/40 , C08K9/06 , C08L33/10 , C08L33/14
CPC分类号: A61K6/30 , A61K6/62 , A61K6/76 , A61K6/77 , A61K6/887 , C08K3/22 , C08K3/40 , C08K9/06 , C08L33/10 , C08L33/14
摘要: Disclosed herein are non-aqueous compositions including: a flowable Part A including at least one resin and Reactant A; and a flowable Part B including at least one resin and Reactant B; wherein at least one of flowable Part A and flowable Part B further includes a free radically polymerizable resin; wherein at least one of flowable Part A and flowable Part B further includes a free radical initiator system; wherein flowable Part A and flowable Part B are capable of being mixed to provide a flowable mixed composition; wherein when flowable Part A and flowable Part B are mixed, Reactant A and Reactant B are capable of interacting to cause a non-free radical reaction within a first staging time to provide a first staged stable consistency for the mixed composition; wherein Reactant A comprises an acid and Reactant B comprises a base, and upon mixing flowable Part A and flowable Part B, the Reactant A acid is capable of reacting with the Reactant B base in an ionic acid-base reaction; and wherein the mixed composition having the first staged stable consistency is capable of forming a hardened dental composition upon initiation of free radical polymerization.
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公开(公告)号:US20230119465A1
公开(公告)日:2023-04-20
申请号:US17911569
申请日:2021-04-05
IPC分类号: C08F222/10 , C08K3/08
摘要: A curable composition comprises at least one monomer comprising at least one (meth)acryl group and a photoinitiator system. The photoinitiator system comprises at least one Type II photoinitiator and at least one cyclic β-diketone represented by the formula (I) or a tautomer thereof. R1 represents an organic moiety having at least one free-radically polymerizable group. Each R2 independently represents H or an aliphatic group having from 1 to 12 carbon atoms, and up to two of oxygen and sulfur atoms, n represents 1, 2, or 3.
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公开(公告)号:US11370940B2
公开(公告)日:2022-06-28
申请号:US16615477
申请日:2018-05-16
发明人: Erik M. Townsend , Shantanu R. Ranade , William H. Moser , Kathleen S. Shafer , Michael A. Kropp , Jayshree Seth , Ross E. Behling
IPC分类号: C09J4/00 , C09J7/40 , C08F4/40 , C08F220/18 , C08K5/15 , C08K5/1565
摘要: An adhesive article comprising first and second tacky latent adhesive layers disposed on respective first and second opposed major surfaces of a substrate. Each of the first and second tacky latent adhesive layers independently comprises at least one polymerizable component, and a redox initiator system comprising a transition metal complex that participates in a redox cycle, an oxidizing agent, and a blocked reducing agent represented by the formula ((I). Each of R1 and R2 are independently H, an alkyl, an aryl, or RPhoto5 with the proviso that at least one of R1 and R2 is RPhoto. RPhoto represents a photoremovable group. Each of R3 and R4 independently represents H, an alkyl group, or an aryl group comprising a monovalent ester, ether, urethane, or carbonate group. Methods of making and using the adhesive articles are also disclosed.
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公开(公告)号:US11021574B2
公开(公告)日:2021-06-01
申请号:US16348346
申请日:2017-11-21
发明人: William H. Moser , Erik M. Townsend , Ian Dailey
IPC分类号: C08G75/045 , C08G75/12 , C08G59/22
摘要: Provided are dual cure monomer are of the formula: (I) wherein R* is a (hetero)hydrocarbyl group; X1 is —O—, —S—, —NR3—, —NR3—CO—NR3, —CO—NR3— or NR3—CO—, where R3 is H, C1-C4 alkyl or R1-Epoxy; R1 is a divalent (hetero)hydrocarbyl group; X2 is —O—, —S—, —NR4—, —NR4—CO—NR4—, —CO—NR4—, —NR4—CO— where R4 is H, C1-C4 alkyl or R2—CH═CH2; R2 is a divalent (hetero)hydrocarbyl group; subscripts a and b are at least one, subscripts c and d are at least one, with the proviso that the monomer has at least two epoxy groups and at least two ene groups.
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公开(公告)号:US20210062858A1
公开(公告)日:2021-03-04
申请号:US16643895
申请日:2018-09-11
发明人: William H. Moser , Erik M. Townsend , Jonathan D. Zook , Susan E. DeMoss , Clinton J. Cook , Scott A. Boyd , Michael D. Swan
IPC分类号: F16B41/00 , C08F283/00
摘要: Curable sealant compositions comprise the components: a) x weight percent of at least one polythiol; b) y weight percent of at least one unsaturated compound having at least two non-aromatic carbon-carbon double bonds, at least one carbon-carbon triple bond, or a combination thereof; c) from 0.01 to 8 weight percent of at least one organoborane-amine complex; d) from 0.05 to 10 weight percent of at least one organic peroxide; and e) from 0.01 to 10 weight percent of a photoinitiator system capable of generating free radicals upon exposure to actinic radiation. Each of x and y represents a positive real number. The sum x+y is in the range of 72 to 99. The weight percent ranges of the components a)-e) are based on the total weight of the components a)-e). A seal cap including the curable sealant composition and methods of making and using the curable sealant compositions are also disclosed.
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公开(公告)号:US20200062908A1
公开(公告)日:2020-02-27
申请号:US16348346
申请日:2017-11-21
发明人: William H. Moser , Erik M. Townsend , Ian Dailey
IPC分类号: C08G75/045 , C08G75/12
摘要: Provided are dual cure monomer are of the formula: (I) wherein R* is a (hetero)hydrocarbyl group; X1 is —O—, —S—, —NR3—, —NR3—CO—NR3, —CO—NR3— or NR3—CO—, where R3 is H, C1-C4 alkyl or R1-Epoxy; R1 is a divalent (hetero)hydrocarbyl group; X2 is —O—, —S—, —NR4—, —NR4—CO—NR4—, —CO—NR4—, —NR4—CO— where R4 is H, C1-C4 alkyl or R2—CH═CH2; R2 is a divalent (hetero)hydrocarbyl group; subscripts a and b are at least one, subscripts c and d are at least one, with the proviso that the monomer has at least two epoxy groups and at least two ene groups.
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7.
公开(公告)号:US20190276588A1
公开(公告)日:2019-09-12
申请号:US16347417
申请日:2017-11-02
摘要: A composition including a polythiol having more than one thiol groups, a polyepoxide having more than one epoxide group, a photolatent base catalyst that can photochemically generate a first amine, and a second amine phase-separated within the composition. A polymer network preparable from the composition, and a method for making the polymer network are also disclosed.
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公开(公告)号:US10195119B2
公开(公告)日:2019-02-05
申请号:US14778191
申请日:2014-03-13
发明人: William H. Moser , Guy D. Joly , Ann R. Fornof , Ahmed S. Abuelyaman , Afshin Falsafi , Larry R. Krepski
IPC分类号: C07C69/00 , A61K6/00 , C07C271/28 , C07C69/76 , C08F222/10 , A61K6/083 , C08F222/20 , C08K9/00 , C09D4/00 , C09J4/00 , C09J5/00
摘要: Addition-fragmentation agents having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least one high refractive index group, and 3) at least one ethylenically unsaturated, polymerizable group are described.
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公开(公告)号:US09758478B2
公开(公告)日:2017-09-12
申请号:US15023757
申请日:2014-10-06
IPC分类号: C08L35/02 , C08L51/00 , C08G75/00 , A61C5/50 , C07C323/54 , C09D4/00 , C08F2/38 , A61K6/00 , C07C323/12 , C09D133/14 , C08F290/06 , C08L51/08 , A61K6/083 , C09D135/02 , C08F220/18 , C08F222/10 , C08F222/22 , C08F230/08
CPC分类号: C07C323/54 , A61C5/50 , A61K6/0073 , A61K6/083 , C07C323/12 , C08F2/38 , C08F290/067 , C08F2220/1858 , C08F2222/102 , C08F2222/225 , C08F2230/085 , C08F2438/03 , C08G75/00 , C08L35/02 , C08L51/08 , C09D4/00 , C09D133/14 , C09D135/02 , A61K6/0023 , C08L33/10 , A61K6/0017
摘要: A Addition-fragmentation oligomers containing allylic disulfide groups are described. The oligomers may be added to polymerizable compositions to provide labile crosslinks that can cleave and reform during the polymerization process.
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公开(公告)号:US11897977B2
公开(公告)日:2024-02-13
申请号:US16965688
申请日:2019-01-16
发明人: William H. Moser , Erik M. Townsend , Zachary J. Thompson , Mary M. Caruso Dailey , Michael A. Kropp
IPC分类号: C08F2/50 , C08F220/18 , C07D239/62 , C07D405/12
CPC分类号: C08F2/50 , C07D239/62 , C07D405/12 , C08F220/1802
摘要: The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent derived from a barbiturate, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization.
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