Organoborane-containing compositions, and methods of using same

    公开(公告)号:US10513583B2

    公开(公告)日:2019-12-24

    申请号:US15129331

    申请日:2015-03-20

    摘要: A polymerizable composition that includes: an organoborane-base complex, wherein the base is a complexing agent selected from a compound having one or more amine groups, amidine groups, hydroxide groups, alkoxide groups, or combinations thereof; a decomplexing agent that liberates the organoborane from the organoborane-base complex; a polymerizable thiol-containing component that includes at least one polymerizable thiol-containing compound having a plurality of thiol groups in which the sulfur atom of the thiol group is covalently bonded to carbon; and a polymerizable ethylenically unsaturated component that includes at least one polymerizable ethylenically unsaturated compound having a plurality of ethylenically unsaturated groups; wherein the total amount of the thiol-containing and ethylenically unsaturated compounds total at least 50% by weight of all polymerizable material in the composition.

    Two-part adhesive composition and method of making an adhesive composition

    公开(公告)号:US10221337B2

    公开(公告)日:2019-03-05

    申请号:US15526520

    申请日:2015-11-06

    摘要: A two-part adhesive composition includes: a Part A including a complex of an organoborane and an amine complexing agent, and reactive diluent selected from the group consisting of at least one vinyl ether, at least one vinylpolysiloxane, or combinations thereof; and a Part B. Part B includes a decomplexing agent that decomplexes the organoborane and the amine complexing agent, and at least one silicon-free free-radically polymerizable ethylenically-unsaturated compound selected from the group consisting of (meth)acrylates, (meth)acrylamides, and combinations thereof. The two-part adhesive composition is essentially free of organic polythiol compounds. A method of making an adhesive composition by mixing Part A with Part B is also disclosed.

    BONDING COMPOSITION AND COMPONENT THEREOF, AND METHOD OF USING THE SAME
    6.
    发明申请
    BONDING COMPOSITION AND COMPONENT THEREOF, AND METHOD OF USING THE SAME 审中-公开
    粘结组合物及其组分及其使用方法

    公开(公告)号:US20160160085A1

    公开(公告)日:2016-06-09

    申请号:US14903274

    申请日:2014-07-01

    IPC分类号: C09J4/06

    摘要: A two-part bonding composition includes parts A and B. Part A includes an organoborane-base complex and reactive diluent. Reactive diluent includes: triallyl isocyanurate; triallyl cyanurate; N-allylamide having the formula R1C(=0)N(R2) CH2CH═CH2, wherein R1 and R2 independently represent alkyl groups having from 1 to 7 carbon atoms, optionally interrupted up to 3 times by oxygen, and optionally substituted up to 2 times with hydroxyl groups, or taken together R1 and R2 represent —(CH2)3—, —(CH2)4—, or —(CH2)5—; and/or allyl ether having the formula R3[OCH2CH═CH2]n wherein R3 represents an n-valent hydrocarbonaceous group having from 1 to 24 carbon atoms, optionally interrupted up to 8 times by oxygen, and optionally substituted up to 6 times with hydroxyl groups, and n represents 1, 2, 3, 4, 5, or 6. Part B includes free-radically polymerizable monomer and at least one compound capable of decomplexing the organoborane-base complex. A method combining Parts A and B is also disclosed.

    摘要翻译: 两部分粘合组合物包括部分A和B.部分A包括有机基硼烷基络合物和反应性稀释剂。 活性稀释剂包括:异氰脲酸三烯丙酯; 氰尿酸三烯丙酯 具有式R 1 C(= O)N(R 2)CH 2 CH = CH 2的N-烯丙基酰胺,其中R 1和R 2独立地表示具有1至7个碳原子的烷基,任选地被氧中断至多3次,并且任选地被至多2个 或(R 1和R 2)表示 - (CH 2)3 - , - (CH 2)4 - 或 - (CH 2) 和/或具有式R 3 [OCH 2 CH = CH 2] n的烯丙基醚,其中R 3表示具有1至24个碳原子的n价烃基,任选地被氧中断至多8次,并且任选地被羟基取代至多6次 基团,n表示1,2,3,4,5或6.B部分包括可自由基聚合的单体和至少一种能够使有机硼烷基络合物解复配的化合物。 还公开了组合A部分和B部分的方法。