公开(公告)号：US08426515B2

公开(公告)日：2013-04-23

申请号：US13152847

申请日：2011-06-03

Applicant: Young Hoon Ko ,  Jae Young Ko ,  Dae Hyung Lee ,  Haeng Shin Jang

Inventor： Young Hoon Ko ,  Jae Young Ko ,  Dae Hyung Lee ,  Haeng Shin Jang

IPC: C08L9/06 ,  C08J3/22

CPC classification number: C08C19/25 ,  C08K5/548 ,  C08K9/06 ,  Y10T428/2991 ,  Y10T428/2995 ,  C08L9/06 ,  C08L21/00

Abstract: Provided are an organically modified silica master batch elastomer having superior affinity for silica and a method for preparing the same. A copolymer solution-polymerized from a conjugated diene-based monomer and a vinyl aromatic monomer is mixed in solution with organically modified silica having the silica modified with a specific aliphatic hydrocarbon to prepare the organically modified silica master batch elastomer. The organically modified silica master batch elastomer according to the present invention has improved mechanical properties, abrasion resistance and blending processability over the existing master batch elastomers containing common silica. Thus, when it is used as a tire material, improved fuel efficiency, abrasion resistance and wet traction may be expected.

Abstract translation: 提供对二氧化硅具有优异亲和性的有机改性二氧化硅母料弹性体及其制备方法。 将共轭二烯类单体和乙烯基芳族单体聚合的共聚物溶液与具有用特定脂肪族烃改性的二氧化硅的有机改性二氧化硅混合，制备有机改性二氧化硅母料弹性体。 根据本发明的有机改性的二氧化硅母料弹性体与现有的含有普通二氧化硅的母料弹性体相比具有改进的机械性能，耐磨性和共混加工性能。 因此，当将其用作轮胎材料时，可以预期提高燃料效率，耐磨性和湿牵引力。

公开(公告)号：US06864326B2

公开(公告)日：2005-03-08

申请号：US10653664

申请日：2003-09-02

Applicant: Young-Hoon Ko ,  Hoo-Chae Kim ,  Jae-Yun Kim ,  Jin-Man Hwang

Inventor： Young-Hoon Ko ,  Hoo-Chae Kim ,  Jae-Yun Kim ,  Jin-Man Hwang

IPC: B01J31/12 ,  C01B6/04 ,  C08C19/02 ,  C08F8/04

CPC classification number: C01B6/04 ,  C08C19/02 ,  C08F8/04

Abstract: The present invention relates to a process for polymer hydrogenation that includes: polymerizing or copolymerizing at least one conjugated diene in a hydrocarbon solvent using an organic alkali metal polymerization initiator to generate a living polymer; adding a terminating agent selected from amines, esters, ketones, or halogen compounds to deactivate the active terminal of the living polymer; and selectively hydrogenating the conjugated diene polymer using at least one organotitanium compound and a lithium hydride, which is prepared from a reactor equipped with a high-speed injection nozzle and thereby precisely controlled in regard to particle diameter. The lithium hydride as used in this process is a highly active lithium hydride having a precisely controlled particle diameter as prepared from a reactor equipped with a high-speed injection nozzle to acquire stable hydrogenation reaction rate and hydrogenation reproducibility, and particularly allow the quantitative control of the lithium hydride/titanium mole ratio in the hydrogenation of the conjugated diene polymer having different molecular weights, thereby maintaining a high hydrogenation activity.

Abstract translation: 本发明涉及一种聚合物氢化方法，其包括：使用有机碱金属聚合引发剂在烃溶剂中使至少一种共轭二烯聚合或共聚以产生活性聚合物; 加入选自胺，酯，酮或卤素化合物的终止剂以使活性聚合物的活性末端失活; 并使用至少一种有机钛化合物和氢化锂选择性地氢化共轭二烯聚合物，该有机钛化合物和氢化锂由装备有高速注射喷嘴的反应器制备，从而精确控制颗粒直径。 在该方法中使用的氢化锂是具有由配备有高速注射喷嘴的反应器制备的精确控制的粒径的高活性氢化锂，以获得稳定的氢化反应速率和氢化重现性，特别是允许定量控制 在具有不同分子量的共轭二烯聚合物的氢化中的氢化锂/钛摩尔比，从而保持高氢化活性。

公开(公告)号：US06040390A

公开(公告)日：2000-03-21

申请号：US119340

申请日：1998-07-20

Applicant: Young-Hoon Ko ,  Jung-Goo Lee ,  Jae-Yoon Kim

Inventor： Young-Hoon Ko ,  Jung-Goo Lee ,  Jae-Yoon Kim

IPC: C08C19/02 ,  C08F8/04 ,  C08F36/04 ,  C08F236/10

CPC classification number: C08F8/04 ,  C08C19/02

Abstract: This invention relates to a process for hydrogenating selectively the unsaturated double bonds of copolymer having the double bonds of conjugated diene unit, which has been widely used as a modifier of transparent impact-resistant resin or polyolefin, and polystyrene resin. According to this invention, the copolymer is saturated via hydrogenation in the presence of a novel homogeneous system organotitanium catalyst without a separate reducing agent, thus representing an extremely high hydrogenation yield with remarkable hydrogenation reproducibility. Hence, a compound represented by the following formula I is employed as an appropriate catalyst.Formula I ##STR1## Wherein Cp is a cyclopentadienyl (C.sub.5 H.sub.5) group; R.sub.1, R.sub.2 and R.sub.3 are hydrogen atom or alkyl group of 1 to 3 carbon atoms; andR.sub.1, R.sub.2 and R.sub.3 can be the same or different.

Abstract translation: 本发明涉及一种已广泛用作透明耐冲击性树脂或聚烯烃改性剂和聚苯乙烯树脂的共轭二烯单元双键共聚物的不饱和双键氢化方法。 根据本发明，在没有单独的还原剂的新型均相体系的有机钛催化剂的存在下，通过氢化使共聚物饱和，从而以显着的氢化重现性表现出非常高的氢化产率。 因此，使用下式I表示的化合物作为合适的催化剂。 其中Cp是环戊二烯基（C 5 H 5）基团; R1，R2和R3是氢原子或1〜3个碳原子的烷基; 并且R 1，R 2和R 3可以相同或不同。

公开(公告)号：US6020439A

公开(公告)日：2000-02-01

申请号：US13162

申请日：1998-01-26

Applicant: Young-Hoon Ko ,  Hoo-Chae Kim

Inventor： Young-Hoon Ko ,  Hoo-Chae Kim

IPC: C08F4/64 ,  B01J31/02 ,  B01J31/22 ,  C08C19/02 ,  C08F8/04 ,  C08F297/04 ,  C08L53/02 ,  B01J31/00 ,  C08F293/00

CPC classification number: B01J31/0212 ,  B01J31/0214 ,  B01J31/2226 ,  B01J31/2295 ,  C08C19/02 ,  C08F297/04 ,  C08F8/04 ,  C08L53/02 ,  C08L53/025 ,  B01J2231/645 ,  B01J2531/46

Abstract: A method for hydrogenating living polymers that include mainly conjugated double bond monomers and aromatic vinyl monomers. At least one conjugated diene compound is polymerized or copolymerized in an inert solvent by using a polymerization initiator of organic alkali metal. The produced polymer is contacted with hydrogen in the presence of a catalyst. The catalyst is formed of a cyclopentadienyl titanium compound represented by: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from halogen groups, C.sub.1 -C.sub.8 alkyl groups, C.sub.1 -C.sub.8 alkoxy groups, C.sub.6 -C.sub.20 aryloxy groups, C.sub.6 -C.sub.20 cycloalkyl groups, silyl groups, and carbonyl groups. A cocatalyst is provided of alkoxylithium compound represented by:R.sub.4 O--Liwherein R.sub.4 is a hydrocarbon. This cocatalyst selectively hydrogenates the unsaturated double bonds in the conjugated diene units of the living polymer.

Abstract translation: 用于氢化主要包含共轭双键单体和芳族乙烯基单体的活性聚合物的方法。 至少一种共轭二烯化合物通过使用有机碱金属的聚合引发剂在惰性溶剂中聚合或共聚。 所生产的聚合物在催化剂存在下与氢气接触。 催化剂由以下化合物形成的环戊二烯基钛化合物：其中R 1，R 2和R 3独立地选自卤素基，C 1 -C 8烷基，C 1 -C 8烷氧基，C 6 -C 20芳氧基，C 6 -C 20环烷基，甲硅烷基 基团和羰基。 提供由以下化合物表示的烷氧基锂化合物的助催化剂：R4O-Li，其中R4是烃。 该助催化剂选择性地氢化活性聚合物的共轭二烯单元中的不饱和双键。

公开(公告)号：US5994477A

公开(公告)日：1999-11-30

申请号：US998448

申请日：1997-12-26

Applicant: Young-Hoon Ko ,  Hoo-Chae Kim

Inventor： Young-Hoon Ko ,  Hoo-Chae Kim

IPC: C08C19/02 ,  C08F2/04 ,  C08F8/04

CPC classification number: C08C19/02 ,  C08F8/04

Abstract: There is provided a method for selectively hydrogenating a living polymer having olefinic double bonds. A monomer having at least one conjugated double bond, optionally together with an olefinic monomer, is polymerized in the presence of an alkyllithium polymerization initiator, to give a living polymer. This olefinic living polymer is reacted with a hydrocarbon compound, to give a deactivated living polymer and a hydrocarbon lithium compound. The double bonds within the conjugated dien units of the polymer are selectively hydrogenated in the presence of a monocyclopentadienyltitanium compound which is under the influence of the hydrocarbon lithium compound. The hydrocarbon, which acts as a deactivator of the living polymer, terminates the anion polymerization occurring due to an activated anion of the living polymer and thus, prevents the intermolecular cross-linking of the polymers so that the gelation of the polymers does not occur. In addition, the hydrocarbon lithium serves as a reducing agent for the hydrogenating catalyst, monocyclopentadienyltitanium compound, so that a high selectivity and hydrogenation efficiency can be obtained without accurate adjustment of Li/Ti mole ratio.

Abstract translation: 提供了选择性氢化具有烯属双键的活性聚合物的方法。 具有至少一个共轭双键的单体，任选与烯属单体一起在烷基锂聚合引发剂的存在下聚合，得到活性聚合物。 该烯属活性聚合物与烃化合物反应，得到失活的活性聚合物和烃锂化合物。 聚合物共轭二烯单元内的双键在烃锂化合物的影响下，在单环戊二烯基钛化合物的存在下选择氢化。 充当活性聚合物的失活剂的烃终止由于活性聚合物的活化阴离子而发生的阴离子聚合，从而防止聚合物的分子间交联，使得不发生聚合物的凝胶化。 此外，烃锂用作氢化催化剂，单环戊二烯基钛化合物的还原剂，从而可以在不准确调节Li / Ti摩尔比的情况下获得高选择性和氢化效率。

公开(公告)号：US5677416A

公开(公告)日：1997-10-14

申请号：US744737

申请日：1996-10-30

Applicant: Young-Hoon Ko ,  Seonkyeong Cheong

Inventor： Young-Hoon Ko ,  Seonkyeong Cheong

IPC: C08G63/692 ,  C08G63/78 ,  C08G63/00

CPC classification number: C08G63/6926

Abstract: There are disclosed a wholly aromatic polyester represented by formula I with enhanced flame retardance and chemical stability, and a method for the preparing the same. The polymer is prepared in interface polymerization wherein an alkali aqueous phase containing cyclotriphosphagene-containing bisphenols is in contact with an organic phase containing aromatic dicarboxylic acid chlorides in the presence of a phase transfer catalyst. ##STR1## wherein m and n each are an integer which satisfies the following conditions: 0

Abstract translation: 公开了具有增强的阻燃性和化学稳定性的由式I表示的全芳族聚酯及其制备方法。 在界面聚合中制备聚合物，其中在相转移催化剂存在下，含有含环三磷酰的双酚的碱性水相与含有芳族二羧酸氯化物的有机相接触。 其中m和n分别是满足以下条件的整数：0

公开(公告)号：US07846993B2

公开(公告)日：2010-12-07

申请号：US12251818

申请日：2008-10-15

Applicant: Young Hoon Ko ,  Jae Young Ko ,  Seung Kyung Ko

Inventor： Young Hoon Ko ,  Jae Young Ko ,  Seung Kyung Ko

IPC: C08K9/06

CPC classification number: C08J3/22 ,  C08J2309/06 ,  C08K5/5419 ,  C08K5/548 ,  C08K9/06

Abstract: The present invention relates to an organic silica master batch elastomer prepared by mixing a conjugated diene based copolymer, a vinyl aromatic copolymer or a mixture thereof prepared by solution polymerization with organically modified silica in which the surface of silica is modified with a particular organosilicon compound and a silane coupling agent in solution. The resultant organic silica master batch elastomer exhibits improved mechanical properties, wear resistance and blending processability, and can provide the effect of extending durability of a tire.

Abstract translation: 本发明涉及通过将通过溶液聚合制备的共轭二烯基共聚物，乙烯基芳族共聚物或其混合物与有机改性二氧化硅混合而制备的有机二氧化硅母料弹性体，其中二氧化硅表面被特定的有机硅化合物改性， 溶液中的硅烷偶联剂。 所得的有机二氧化硅母料弹性体显示改进的机械性能，耐磨性和共混加工性，并且可以提供延长轮胎的耐久性的效果。

公开(公告)号：US20090163633A1

公开(公告)日：2009-06-25

申请号：US12251818

申请日：2008-10-15

Applicant: Young Hoon KO ,  Jae Young KO ,  Seung Kyung KO

Inventor： Young Hoon KO ,  Jae Young KO ,  Seung Kyung KO

IPC: C08K5/5419

CPC classification number: C08J3/22 ,  C08J2309/06 ,  C08K5/5419 ,  C08K5/548 ,  C08K9/06

Abstract: The present invention relates to an organic silica master batch elastomer prepared by mixing a conjugated diene based copolymer, a vinyl aromatic copolymer or a mixture thereof prepared by solution polymerization with organically modified silica in which the surface of silica is modified with a particular organosilicon compound and a silane coupling agent in solution. The resultant organic silica master batch elastomer exhibits improved mechanical properties, wear resistance and blending processability, and can provide the effect of extending durability of a tire.

Abstract translation: 本发明涉及通过将通过溶液聚合制备的共轭二烯基共聚物，乙烯基芳族共聚物或其混合物与有机改性二氧化硅混合而制备的有机二氧化硅母料弹性体，其中二氧化硅表面用特定的有机硅化合物改性， 溶液中的硅烷偶联剂。 所得的有机二氧化硅母料弹性体显示改进的机械性能，耐磨性和共混加工性，并且可以提供延长轮胎的耐久性的效果。

公开(公告)号：US20050176886A1

公开(公告)日：2005-08-11

申请号：US10940470

申请日：2004-09-14

Applicant: Young-Chan Jang ,  Hyung-Kyu Choi ,  Shin Han ,  Young-Hoon Ko

Inventor： Young-Chan Jang ,  Hyung-Kyu Choi ,  Shin Han ,  Young-Hoon Ko

IPC: C08F236/14 ,  C08C19/44 ,  C08G77/442 ,  C08G77/50 ,  C08G81/02 ,  C08L51/08

CPC classification number: C08G81/024 ,  C08C19/44 ,  C08G77/442 ,  C08G77/50

Abstract: The present invention provides a method for preparing a copolymer useful for the manufacture of tires by coupling the ends of a living polymer, obtained from copolymerization of a diene monomers in the presence of an organolithium initiator and a hydrocarbon solvent, with a multi-reactive polysiloxane compound, and then completing the reaction or subsequently modifying the remaining uncoupled ends of the polymer with an amine compound. The use of the copolymer thus obtained for tire production improves the affinity to silica and greatly enhances the dynamic properties required for tires, such as wet traction and rolling resistance.

Abstract translation: 本发明提供一种制备用于制造轮胎的共聚物的方法，该方法是将有机锂引发剂和烃溶剂存在下的二烯单体的共聚得到的活性聚合物的末端与多反应性聚硅氧烷 化合物，然后用胺化合物完成反应或随后改性聚合物的剩余的未偶联的末端。 由此获得的用于轮胎生产的共聚物的使用提高了对二氧化硅的亲和性，并且大大提高了轮胎所需的动态性能，例如湿牵引和滚动阻力。

公开(公告)号：US06777493B2

公开(公告)日：2004-08-17

申请号：US10283160

申请日：2002-10-30

Applicant: Young Hoon Ko ,  Sun Woo Cheen

Inventor： Young Hoon Ko ,  Sun Woo Cheen

IPC: C08L8304

CPC classification number: C08G77/442 ,  C08F8/42

Abstract: A radial end-modified styrene-conjugated diene block copolymer having a general formula 1. The copolymer is obtained by synthesizing a styrene-conjugated diene block copolymer by way of copolymerization using an organic lithium initiator in the presence of a nonpolar solvent and then coupling the anionic active end of the resulting copolymer with a polyfunctional polysiloxane: (PS-PD)3Si—CH2CH2—[SiO(CH3)2—]nSi(CH3)2R  Formula 1 wherein, PS is polystyrene, PD is polydiene such as polyisoprene or polyisoprene-polybutadiene, R is hydroxy group or -(PD-PS), and n is an integer of 1 to 100. The block copolymer based adhesives have low melt viscosity and excellent adhesive strength.

Abstract translation: 具有通式1的径向末端改性苯乙烯 - 共轭二烯嵌段共聚物。该共聚物通过在非极性溶剂的存在下使用有机锂引发剂通过共聚合合苯乙烯 - 共轭二烯嵌段共聚物，然后将 所得共聚物的阴离子活性末端与多官能聚硅氧烷：其中PS为聚苯乙烯，PD为聚二烯如聚异戊二烯或聚异戊二烯 - 聚丁二烯，R为羟基或 - （PD-PS），n为1至100的整数 基于嵌段共聚物的粘合剂具有低熔体粘度和优异的粘合强度。