公开(公告)号：US08709168B2

公开(公告)日：2014-04-29

申请号：US13504436

申请日：2010-10-04

Applicant: Alan Geoffrey Waite ,  Trevor Graham Blease ,  Sean Alexander Robins

Inventor： Alan Geoffrey Waite ,  Trevor Graham Blease ,  Sean Alexander Robins

IPC: B08B3/04 ,  C11D1/00 ,  C11D1/62

CPC classification number: C08G73/0226 ,  C08G73/02 ,  C11D3/3723

Abstract: Hard surfaces can be treated to improve soil resistance, particularly resistance to oily soils, by applying a composition of a quaternised, polyamine, polypropoxylate, polyethoxylate. The polyamine can be a polyethyleneimme, desirably having a molecular weight of from 10 to 50 kDa. The average length of the polypropylenoxy chains is desirably from 10 to 100 and the polyethylenoxy chains from 5 to 50 (each per NH group in the polyamine), particularly at a molar ratio of PO:EO of about 3:1. The degree of quaternization of the nitrogen atoms in the polyamine is desirably from 70 to 100%. The polymer will usually be used in solution in water or an aqueous formulation, which may include detergent and other detergent formulation components.

Abstract translation: 通过施用季铵化的多胺，聚丙氧基化物，聚乙氧基化物的组合物，可以处理硬表面以改善土壤抗性，特别是耐油性土壤。 多胺可以是聚乙烯亚胺，理想地具有10至50kDa的分子量。 聚丙烯氧基链的平均长度优选为10〜100，聚乙烯氧基链为5〜50（多胺中的每个NH基），特别是PO:EO的摩尔比为约3:1。 多胺中氮原子的季铵化程度优选为70〜100％。 聚合物通常用于水或水性制剂中的溶液中，其可以包括洗涤剂和其它洗涤剂配方组分。

公开(公告)号：US20100093543A1

公开(公告)日：2010-04-15

申请号：US12588018

申请日：2009-09-30

Applicant: Trevor Graham Blease

Inventor： Trevor Graham Blease

IPC: A01N25/04

CPC classification number: C11D1/526 ,  A01N25/04 ,  A61K8/06 ,  A61K8/85 ,  A61K8/88 ,  A61Q1/02 ,  A61Q17/04 ,  B01F17/0021 ,  B01F17/0028 ,  B01F17/0042 ,  B01F17/005 ,  C11D1/04 ,  C11D1/74 ,  C11D3/0036 ,  A01N47/22

Abstract: Polyethylene glycol esters and amides of polymerised fatty acids are useful dispersing agents for solids, particularly particulate solids, e.g. agrochemicals, oil drilling mud components, pigments, personal care formulants, ceramics, magnetic materials, extenders, fillers, optical brighteners, textile auxiliaries, or soil removed from clothes during cleaning, in aqueous media. Particular such agents are of the formula (I): [Pol]-(COX)m (I), where: Pol is the core residue of a polymerised fatty acid; m is 2 or 3; and each X is: OM; where M is H, a cationic salt forming species or a group -(AO)nR7; or a group —NR8-(AO)nR9; where AO is an alkylene oxide residue; n is from 1 to 100; and R7, R8 and R9 are as defined, from H, an anionic group, alkyl or alkenyl; provided that at least one X is a group of the formula -(AO)nR7 or —NR8-(AO)nR9.

Abstract translation: 聚乙二醇酯和聚合脂肪酸的酰胺是用于固体，特别是颗粒固体的有用的分散剂，例如。 在水性介质中，农药，石油钻井泥浆成分，颜料，个人护理制剂，陶瓷，磁性材料，增量剂，填料，荧光增白剂，纺织助剂或从衣物中除去的污垢。 特别的这样的试剂是式（I）：[Pol] - （COX）m（I），其中：Pol是聚合脂肪酸的核心残基; m为2或3; 每个X是：OM; 其中M是H，阳离子盐形成物质或基团 - （AO）nR 7; 或基团-NR 8 - （AO）n R 9; 其中AO是环氧烷残基; n为1〜100; 并且R 7，R 8和R 9如H所定义，阴离子基团，烷基或烯基; 条件是至少一个X是式 - （AO）nR 7或-NR 8 - （AO）n R 9的基团。

公开(公告)号：US08673816B2

公开(公告)日：2014-03-18

申请号：US13266873

申请日：2010-05-05

Applicant: Trevor Graham Blease ,  Gregory James Lindner ,  Lee David Richards

Inventor： Trevor Graham Blease ,  Gregory James Lindner ,  Lee David Richards

IPC: A01N25/00 ,  A01P7/02 ,  C07C217/04 ,  A01P21/00 ,  A01N57/20 ,  A01N25/04 ,  A01P13/00 ,  A01P7/04

CPC classification number: B01F17/005 ,  A01N25/30 ,  A01N43/653 ,  A01N43/70 ,  A01N47/22 ,  A01N47/38 ,  A01N51/00 ,  A01N57/20 ,  A01N2300/00

Abstract: Surfactant compounds which include an amine ended polyalkylene glycol hydrophile linked to C22 to C60 mainly hydrocarbyl, particularly composite hydrocarbyl, especially derived from a polymerised fatty acid and/or an aralkyl substituted phenol, hydrophobe, are useful in dispersing solids, particularly active agrochemicals, in aqueous media, or as adjuvants in agrochemical formulations, particularly of water soluble non-selective herbicides. In particular the hydrophobe is derived from polymerised fatty acids, such as dimer and, especially, trimer acids or from aralkyl substituted phenols. Aqueous dispersions using such surfactants can remain stable even with substantial concentrations of electrolyte e.g. in stable agrochemical dispersions including water soluble electrolyte agrochemical, such as glyphosate and/or ammonium sulphate.

Abstract translation: 包括连接到C22至C60的胺末端聚亚烷基二醇亲水体的表面活性剂化合物主要用于分散固体，特别是活性农业化学品，主要是烃基，特别是复合烃基，特别是衍生自聚合的脂肪酸和/或芳烷基取代的酚，疏水基， 水性介质，或作为农药制剂，特别是水溶性非选择性除草剂的佐剂。 特别地，疏水物衍生自聚合的脂肪酸，例如二聚体，特别是三聚酸或芳烷基取代的酚。 使用这种表面活性剂的水性分散体即使具有相当浓度的电解质也可保持稳定。 在稳定的农业化学分散体中，包括水溶性电解质农业化学品，例如草甘膦和/或硫酸铵。

公开(公告)号：US20120040834A1

公开(公告)日：2012-02-16

申请号：US13266873

申请日：2010-05-05

Applicant: Trevor Graham Blease ,  Gregory James Lindner ,  Lee David Richards

Inventor： Trevor Graham Blease ,  Gregory James Lindner ,  Lee David Richards

IPC: A01N25/04 ,  A01N25/00 ,  A01P21/00 ,  A01P7/02 ,  A01N57/20 ,  A01P13/00 ,  C07C217/04 ,  A01P7/04

CPC classification number: B01F17/005 ,  A01N25/30 ,  A01N43/653 ,  A01N43/70 ,  A01N47/22 ,  A01N47/38 ,  A01N51/00 ,  A01N57/20 ,  A01N2300/00

Abstract: Surfactant compounds which include an amine ended polyalkylene glycol hydrophile linked to C22 to C60 mainly hydrocarbyl, particularly composite hydrocarbyl, especially derived from a polymerised fatty acid and/or an aralkyl substituted phenol, hydrophobe, are useful in dispersing solids, particularly active agrochemicals, in aqueous media, or as adjuvants in agrochemical formulations, particularly of water soluble non-selective herbicides. In particular the hydrophobe is derived from polymerised fatty acids, such as dimer and, especially, trimer acids or from aralkyl substituted phenols. Aqueous dispersions using such surfactants can remain stable even with substantial concentrations of electrolyte e.g. in stable agrochemical dispersions including water soluble electrolyte agrochemical, such as glyphosate and/or ammonium sulphate.

Abstract translation: 包括连接到C22至C60的胺末端聚亚烷基二醇亲水体的表面活性剂化合物主要用于分散固体，特别是活性农业化学品，主要是烃基，特别是复合烃基，特别是衍生自聚合的脂肪酸和/或芳烷基取代的酚，疏水基， 水性介质，或作为农药制剂，特别是水溶性非选择性除草剂的佐剂。 特别地，疏水物衍生自聚合的脂肪酸，例如二聚体，特别是三聚酸或芳烷基取代的酚。 使用这种表面活性剂的水性分散体即使具有相当浓度的电解质也可保持稳定。 在稳定的农业化学分散体中，包括水溶性电解质农业化学品，例如草甘膦和/或硫酸铵。

公开(公告)号：US06878763B2

公开(公告)日：2005-04-12

申请号：US10123527

申请日：2002-04-17

Applicant: Trevor Graham Blease ,  Johny Denis Grade

Inventor： Trevor Graham Blease ,  Johny Denis Grade

IPC: C08F2/26

CPC classification number: C08F2/26 ,  Y10S526/911

Abstract: The free radical initiated addition polymerization of ethylenically unsaturated, particularly acrylic monomers in which the dispersed phase is stabilised by a surfactant including at least one anionic surfactant compound of the formula (I): R1—(OA)n—X where R1 is C16 to C22 hydrocarbyl including at least two double bonds; OA is oxyalkylene group; n is from 2 to 60; and X includes at least one acidic H atom, and is particularly a phosphate ester group, or a salt thereof, is described. The use of the surfactants of the formula (I) enable efficient emulsification and thus polymerization at temperatures above those at which non-ionic unsaturated surfactants are effective. The polymer latex products give polymer films having good water resistance properties.

Abstract translation: 包含至少一种式（I）的阴离子表面活性剂化合物：R 1 - （OA）n X的表面活性剂的表面活性剂使得分散相稳定的烯属不饱和，特别是丙烯酸单体的自由基引发加成聚合，其中R 1 >是C16至C22烃基，包括至少两个双键; OA为氧化烯基; n为2〜60; 并且X包括至少一个酸性H原子，特别是磷酸酯基或其盐。 使用式（I）的表面活性剂能够在高于非离子不饱和表面活性剂有效的温度下进行有效的乳化和聚合。 聚合物胶乳产品具有良好的耐水性能的聚合物膜。

公开(公告)号：US20120208736A1

公开(公告)日：2012-08-16

申请号：US13504436

申请日：2010-10-04

Applicant: Alan Geoffrey Waite ,  Trevor Graham Blease ,  Sean Robins

Inventor： Alan Geoffrey Waite ,  Trevor Graham Blease ,  Sean Robins

IPC: C11D3/37 ,  C07C217/42 ,  C08G73/04 ,  C09D179/02 ,  C09K3/00

CPC classification number: C08G73/0226 ,  C08G73/02 ,  C11D3/3723

Abstract: Hard surfaces can be treated to improve soil resistance, particularly resistance to oily soils, by applying a composition of a quaternised, polyamine, polypropoxylate, polyethoxylate. The polyamine can be a polyethyleneimme, desirably having a molecular weight of from 10 to 50 kDa. The average length of the polypropylenoxy chains is desirably from 10 to 100 and the polyethylenoxy chains from 5 to 50 (each per NH group in the polyamine), particularly at a molar ratio of PO:EO of about 3:1. The degree of quaternisation of the nitrogen atoms in the polyamine is desirably from 70 to 100%. The polymer will usually be used in solution in water or an aqueous formulation, which may include detergent and other detergent formulation components.

Abstract translation: 通过施用季铵化的多胺，聚丙氧基化物，聚乙氧基化物的组合物，可以处理硬表面以改善土壤抗性，特别是耐油性土壤。 多胺可以是聚乙烯亚胺，理想地具有10至50kDa的分子量。 聚丙烯氧基链的平均长度优选为10〜100，聚乙烯氧基链为5〜50（多胺中的每个NH基），特别是PO:EO的摩尔比为约3:1。 多胺中氮原子的季铵化程度优选为70〜100％。 聚合物通常用于水或水性制剂中的溶液中，其可以包括洗涤剂和其它洗涤剂配方组分。

公开(公告)号：US08883945B2

公开(公告)日：2014-11-11

申请号：US10583085

申请日：2004-12-15

Applicant: William Harry McNamee ,  Trevor Graham Blease ,  Johnny Denis Grade ,  Hanamanthsa Shankarsa Bevinakatti

Inventor： William Harry McNamee ,  Trevor Graham Blease ,  Johnny Denis Grade ,  Hanamanthsa Shankarsa Bevinakatti

IPC: C09D5/02 ,  B01F17/00 ,  C09D167/00 ,  C09D167/08 ,  C08G65/26 ,  C08G65/329 ,  C08L67/08 ,  C08K3/00 ,  C08K5/41 ,  C08K5/00 ,  C08K5/42 ,  C08K5/09 ,  C08K5/521

CPC classification number: B01F17/005 ,  B01F17/0021 ,  B01F17/0028 ,  B01F17/0042 ,  C08G65/26 ,  C08G65/329 ,  C08K3/013 ,  C08K5/0041 ,  C08K5/09 ,  C08K5/41 ,  C08K5/42 ,  C08K5/521 ,  C08L67/08 ,  C08L2201/50 ,  C08L2201/52 ,  C09D167/08 ,  Y10S526/932 ,  C08L2666/22

Abstract: A compound of the formula R1.[(AO)n.—R2]m (I) where: R1 is the residue of a group having at least m active hydrogen atoms; AO is an alkylene oxide residue; each n is independently from 1 to 100; m is at least 2; and each R2 is independently H, a C1 to C21 hydrocarbyl, or an acyl group —OC.R3, where R3 is a C1 to C21 hydrocarbyl group, wherein on average greater than one of the R2 groups is or comprises a C4 to C21 hydrocarbyl group comprising at least two ethylenic double bonds. The compounds are particularly suitable for use in preparing aqueous emulsions or dispersions of resins and polymers, especially alkyd resins.

Abstract translation: 式（R1）[（AO）n.-R2] m（I）的化合物其中：R1是具有至少m个活性氢原子的基团的残基; AO是氧化烯残基; 每个n独立地为1至100; m至少为2; 并且每个R 2独立地为H，C 1至C 21烃基或酰基-OC.R 3，其中R 3为C 1至C 21烃基，其中平均大于一个R 2基团为或包含C 4至C 21烃基 包含至少两个烯属双键的基团。 该化合物特别适用于制备树脂和聚合物，特别是醇酸树脂的水性乳液或分散体。

公开(公告)号：US20090181070A1

公开(公告)日：2009-07-16

申请号：US12223692

申请日：2007-01-19

Applicant: Trevor Graham Blease ,  Francisus Johannes Groenhof ,  Graham Timothy Pennick

Inventor： Trevor Graham Blease ,  Francisus Johannes Groenhof ,  Graham Timothy Pennick

IPC: A61K8/89 ,  B01F17/54 ,  A61K8/06

CPC classification number: B01F17/005 ,  A61K8/0208 ,  A61K8/06 ,  A61K8/73 ,  A61K8/92 ,  A61Q17/04 ,  A61Q19/10

Abstract: A method of making an oil-in-water emulsion is described in which an oil emulsifier and a polysaccharide emulsion stabiliser, which stabiliser comprises a Xanthan polysaccharide and a polyglucomannan polysaccharide, is dispersed in an oil. The oil-based dispersion so formed is then combined with water, preferably at low temperature and under low shear conditions, to form an oil-in-water emulsion. The polysaccharide emulsion stabiliser and optionally oil emulsifier may be dispersed directly into a relatively polar oil to form the oil-based dispersion or, alternatively, into a relatively polar non-aqueous liquid medium, which medium then being mixed with the oil before it is combined with the water to form the emulsion. The oil-in-water emulsions are particularly useful in personal care and cosmetic applications such as sprays, body moisturisers, sun screens and wet wipes for cosmetic or personal hygiene cleaning uses.

Abstract translation: 描述了一种制备水包油乳液的方法，其中将包含黄原胶多糖和聚葡甘聚糖多糖的稳定剂的油乳化剂和多糖乳液稳定剂分散在油中。 然后将如此形成的油基分散体与水合并，优选在低温和低剪切条件下，形成水包油乳液。 多糖乳化稳定剂和任选的油性乳化剂可以直接分散到相对极性的油中以形成油基分散体，或者替代地进入相对极性的非水性液体介质中，然后在组合之前将其与油混合 用水形成乳液。 水包油乳剂特别适用于个人护理和化妆品应用，例如喷雾剂，身体保湿剂，防晒剂和用于化妆品或个人卫生清洁用途的湿巾。

公开(公告)号：US07481893B2

公开(公告)日：2009-01-27

申请号：US10518916

申请日：2003-06-24

Applicant: Harold Russell Motson ,  Derek John Irvine ,  Trevor Graham Blease

Inventor： Harold Russell Motson ,  Derek John Irvine ,  Trevor Graham Blease

IPC: B08B7/00

CPC classification number: D06L1/00 ,  D06L1/04

Abstract: Cleaning media based on liquid CO2 and including from 0.01 to 5% by weight of the formulation of a cleaning additive which is at least one C6 to C24 hydrocarbyl ester of a multi-carboxylic acid can be used in dry cleaning of textiles. Desirable cleaning additives are of the formula (I): R1(CO2R2)n where R1 is the residue of a C1 to C10 hydrocarbyl group from which n hydrogen atoms have been removed, R2 is a C6 to C24 hydrocarbyl, particularly alkyl or alkenyl, group; and n is from 2 to 5; particularly C12 to C18 adipate esters.

Abstract translation: 基于液体CO 2的清洁介质，包括0.01至5重量％的作为多羧酸的至少一种C 6至C 24烃基酯的清洁添加剂的制剂可用于纺织品的干洗。 理想的清洁添加剂具有式（I）：R1（CO2R2）n其中R1是其中去除了n个氢原子的C1至C10烃基的残基，R2是C6至C24烃基，特别是烷基或烯基， 组; n为2〜5; 特别是C12至C18己二酸酯。