公开(公告)号：US20110271462A1

公开(公告)日：2011-11-10

申请号：US13185106

申请日：2011-07-18

Applicant: Harold Russell Motson ,  Derek John Irvine ,  Steven Huntley

Inventor： Harold Russell Motson ,  Derek John Irvine ,  Steven Huntley

IPC: D06L1/00

CPC classification number: D06L1/00

Abstract: Fatty branched polyalkoxylates, particularly of the formula: R1O(AO)mR2 (I) where R1 is C8 to C30 aliphatic hydrocarbyl or acyl; AO is predominantly branched alkyleneoxy, particularly propyleneoxy; m is from 2 to 50; and R2 is H or a is C1 to C4 aliphatic hydrocarbyl or acyl, are used as fabric conditioners in CO2 based dry cleaning systems. The cleaning medium may include detergent surfactant and/or non surfactant cleaning additive or may be free from such additives in which case the treatment can be provided in a rinse cycle in a cleaning process.

Abstract translation: 脂肪支链多烷氧基化物，特别是下式：R 1 O（AO）m R 2（I），其中R 1为C 8至C 30脂族烃基或酰基; AO主要是支链亚烷基氧基，特别是丙烯氧基; m为2〜50; R2为H或a为C1至C4脂族烃基或酰基，用作基于CO2的干洗系统中的织物调理剂。 清洁介质可以包括洗涤剂表面活性剂和/或非表面活性剂清洁添加剂，或者可以不含这种添加剂，在这种情况下，处理可以在清洗过程中的漂洗循环中提供。

公开(公告)号：US06534605B2

公开(公告)日：2003-03-18

申请号：US09750222

申请日：2000-12-29

Applicant: Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

Inventor： Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

IPC: C08F444

CPC classification number: C08F4/44 ,  C08F4/80

Abstract: A polymerization process for the preparation of vinylic polymers from the corresponding vinylic monomers which process comprises the step of reacting a vinylic monomer in the presence of a catalyst system comprising a) a compound of general formula (I) where M is any metal capable of coordinating to an enolate or delocalized enolate-like species; B1, B2, B3 and B4 are chosen from nitrogen, oxygen, sulphur or phosphorus containing moieties wherein each of said nitrogen, oxygen, sulphur or phosporus is linked to at least one carbon atom of an organic group and to M; X1 is selected from the group consisting of alkyl, H, halogen, alkoxy, thiol aryloxy, ester, b) a metal, complex of general formula (II) where A is selected from the group consisting of nickel, iron, cobalt, chromium, manganese, titanium, zirconium, vanadium and the rare earth metals; L1, L2, L3 and L4 are ligands and c) a Lewis acid of general formula (III) wherein at least one of W, Y or Z is capable of forming a co-ordination bond with A and the others of W, Y and Z are bulky groups; D is selected from the group concsisting of aluminium, magnesium, zinc and boron

Abstract translation: 用于从相应的乙烯基单体制备乙烯基聚合物的聚合方法包括在催化剂体系存在下使乙烯基单体反应的步骤，该催化剂体系包含：a）通式（I）的化合物，其中M是能够配位的任何金属 到烯醇化或离碱化的烯醇化物质; B1，B2，B3和B4选自氮，氧，硫或含磷部分，其中所述氮，氧，硫或磷的每一个与有机基团的至少一个碳原子连接，并与M相连; 酯选自烷基，H，卤素，烷氧基，硫醇芳氧基，酯，b）金属，通式（II）的络合物，其中A选自镍，铁，钴，铬， 锰，钛，锆，钒和稀土金属; L1，L2，L3和L4是配体，c）通式（III）的路易斯酸，其中W，Y或Z中的至少一个能够与A形成配位键，其它的W，Y和 Z是体积大的组; D选自铝，镁，锌和硼的组合

公开(公告)号：US08003591B2

公开(公告)日：2011-08-23

申请号：US10525042

申请日：2002-08-20

Applicant: Harold Russell Motson ,  Derek John Irvine ,  Steven Huntley

Inventor： Harold Russell Motson ,  Derek John Irvine ,  Steven Huntley

IPC: D06L1/00

CPC classification number: D06L1/00

Abstract: Fatty branched polyalkoxylates, particularly of the formula: R1O(AO)mR2 (I) where R1 is C8 to C30 aliphatic hydrocarbyl or acyl; AO is predominantly branched alkyleneoxy, particularly propyleneoxy; m is from 2 to 50; and R2 is H or a is C1 to C4 aliphatic hydrocarbyl or acyl, are used as fabric conditioners in CO2 based dry cleaning systems. The cleaning medium may include detergent surfactant and/or non surfactant cleaning additive or may be free from such additives in which case the treatment can be provided in a rinse cycle in a cleaning process.

Abstract translation: 脂肪支链多烷氧基化物，特别是下式：R 1 O（AO）m R 2（I），其中R 1为C 8至C 30脂族烃基或酰基; AO主要是支链亚烷基氧基，特别是丙烯氧基; m为2〜50; R2为H或a为C1至C4脂族烃基或酰基，用作基于CO2的干洗系统中的织物调理剂。 清洁介质可以包括洗涤剂表面活性剂和/或非表面活性剂清洁添加剂，或者可以不含这种添加剂，在这种情况下，处理可以在清洗过程中的漂洗循环中提供。

公开(公告)号：US07481893B2

公开(公告)日：2009-01-27

申请号：US10518916

申请日：2003-06-24

Applicant: Harold Russell Motson ,  Derek John Irvine ,  Trevor Graham Blease

Inventor： Harold Russell Motson ,  Derek John Irvine ,  Trevor Graham Blease

IPC: B08B7/00

CPC classification number: D06L1/00 ,  D06L1/04

Abstract: Cleaning media based on liquid CO2 and including from 0.01 to 5% by weight of the formulation of a cleaning additive which is at least one C6 to C24 hydrocarbyl ester of a multi-carboxylic acid can be used in dry cleaning of textiles. Desirable cleaning additives are of the formula (I): R1(CO2R2)n where R1 is the residue of a C1 to C10 hydrocarbyl group from which n hydrogen atoms have been removed, R2 is a C6 to C24 hydrocarbyl, particularly alkyl or alkenyl, group; and n is from 2 to 5; particularly C12 to C18 adipate esters.

Abstract translation: 基于液体CO 2的清洁介质，包括0.01至5重量％的作为多羧酸的至少一种C 6至C 24烃基酯的清洁添加剂的制剂可用于纺织品的干洗。 理想的清洁添加剂具有式（I）：R1（CO2R2）n其中R1是其中去除了n个氢原子的C1至C10烃基的残基，R2是C6至C24烃基，特别是烷基或烯基， 组; n为2〜5; 特别是C12至C18己二酸酯。

公开(公告)号：US06867272B2

公开(公告)日：2005-03-15

申请号：US10274264

申请日：2002-10-21

Applicant: Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

Inventor： Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

IPC: C07C251/24 ,  C07C33/02 ,  C07F5/06 ,  C08F4/00 ,  C08F4/06 ,  C08F4/44 ,  C08F4/54 ,  C08F20/00 ,  C08F230/04 ,  C08F2/00

CPC classification number: C08F230/04 ,  C07F5/069

Abstract: An enolate functionalized reaction intermediate of general formula (I), wherein X is an alkyl group; Z is selected from the group consisting of alkyl, hydrogen, halogen, alkoxy, thiol, aryloxy or ester; n is an integer and is at least one; Y is alkyl or H; the tetradentate ligand around the Al is optionally substituted. Also claimed is a process for the preparation of the enolate functionalized reaction intermediate and its reaction with a vinylic monomer and a Lewis acid to produce the corresponding vinylic polymer.

Abstract translation: 一种通式（I）的烯醇化官能化反应中间体，其中X为烷基; Z选自烷基，氢，卤素，烷氧基，硫醇，芳氧基或酯; n为整数，至少为1; Y是烷基或H; Al周围的四齿配体任选被取代。 还要求的是制备烯醇化物官能化反应中间体及其与乙烯基单体和路易斯酸的反应以制备相应的乙烯基聚合物的方法。

公开(公告)号：US06649711B2

公开(公告)日：2003-11-18

申请号：US09750176

申请日：2000-12-29

Applicant: Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

Inventor： Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

IPC: C08F444

CPC classification number: C08F220/14 ,  Y10S526/943

Abstract: A polymerisation process for the preparation of vinylic polymers from the corresponding vinylic monomers which process comprises the step of reacting a vinylic monomer in the presence of a catalyst system comprising a) a metal complex of general formula (I) where A is selected from the group consisting of nickel, iron, cobalt, chromium, manganese, titanium, zirconium, vanadium and the rare earth metals; L1, L2, L3 and L4 are ligands and b) a Lewis acid of general formula (II) wherein at least one of W, Y or Z is capable of forming a co-ordination bond with A and the others of W, Y and Z are bulky groups; D is selected from the group consisting of aluminium, magnesium, zinc and boron.

Abstract translation: 用于从相应的乙烯基单体制备乙烯基聚合物的聚合方法包括在催化剂体系存在下使乙烯基单体反应的步骤，该催化剂体系包含：a）通式（I）的金属络合物，其中A选自 由镍，铁，钴，铬，锰，钛，锆，钒和稀土金属组成; L 1，L 2，L 3和L 4是配位体，b）通式（II）的路易斯酸，其中W，Y或Z中的至少一个能够形成共 - 与A的协调债券，W，Y和Z的其他债券是庞大的基金; D选自铝，镁，锌和硼。

公开(公告)号：US06593439B1

公开(公告)日：2003-07-15

申请号：US09719987

申请日：2001-03-06

Applicant: Paul Christian ,  Steven Melvyn Howdle ,  Derek John Irvine

Inventor： Paul Christian ,  Steven Melvyn Howdle ,  Derek John Irvine

IPC: C08F1820

CPC classification number: C08F2/06 ,  Y02P20/544

Abstract: A method of producing a polymer comprises the steps of forming a heterogeneous reaction mixture comprising at least one addition polymerizable monomer, a supercritical fluid, and a stabilizer, wherein the stabilizer comprises a chain which is soluble in the supercritical fluid and functional end-group which is not polymerizable by a free-radical mechanism, and polymerizing said at least one monomer in the reaction mixture. In a preferred system for polymerizing acrylic monomers, the fluid comprises supercritical carbon dioxide and the stabilizer comprises an acid-functionalized perfluoropolyether.

Abstract translation: 制备聚合物的方法包括以下步骤：形成包含至少一种可加成聚合单体，超临界流体和稳定剂的非均相反应混合物，其中稳定剂包括可溶于超临界流体和功能性末端基团的链， 不能通过自由基机理聚合，并且在反应混合物中聚合所述至少一种单体。 在用于聚合丙烯酸单体的优选体系中，流体包含超临界二氧化碳，并且稳定剂包含酸官能化的全氟聚醚。

公开(公告)号：US07514396B2

公开(公告)日：2009-04-07

申请号：US10518921

申请日：2002-06-24

Applicant: Harold Russell Motson ,  Derek John Irvine ,  Eric Appelman

Inventor： Harold Russell Motson ,  Derek John Irvine ,  Eric Appelman

IPC: C11D3/22

CPC classification number: D06L1/00 ,  D06L1/04

Abstract: Detergent or micelle free cleaning media based on detergent free and/or micelle free liquid CO2 and including from 0.01 to 5% by weight of the formulation of a cleaning additive which is at least one multi-ester having a molecular weight of not more than 750 can be used in dry cleaning of textiles. Desirable cleaning additives are of the formula (1): R1(XR2)n where X, R1, R2, and n have defined meanings, particularly to be esters of multi-carboxylic acids and mono-hydroxy alcohols or esters of mono-carboxylic acids and multi-hydroxy alcohols.

Abstract translation: 基于无洗涤剂和/或无胶束液体CO 2的洗涤剂或无胶束清洁介质，包括0.01至5重量％的制剂，其为至少一种分子量不超过750的多酯 可用于纺织品的干洗。 理想的清洁添加剂具有式（1）：R1（XR2）n其中X，R1，R2和n具有定义的含义，特别是多羧酸和单羟基醇或单羧酸的酯 和多羟基醇。

公开(公告)号：US06469190B2

公开(公告)日：2002-10-22

申请号：US09750220

申请日：2000-12-29

Applicant: Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

Inventor： Paul Alexander Cameron ,  Vernon Charles Gibson ,  Derek John Irvine

IPC: C07F506

CPC classification number: C08F230/04 ,  C07F5/069

Abstract: An enolate functionalized reaction intermediate, represented by the formula (I) shown in the specification, such as, N,N′-ethylenebis (3,5-di-tertbutylsalicylidene imine) enolate of ter-butyl-isobutyrate aluminum, is useful for the production of vinyl polymers, such as polymethylmethacrylate, from the corresponding vinyl polymers, e.g., methylmethacrylate, by a living polymerization reaction. A Lewis acid may be used in the polymerization.

Abstract translation: 由说明书中所示的式（I）表示的烯醇化官能化反应中间体，例如叔丁基异丁酸铝的N，N'-亚乙基双（3,5-二叔丁基亚水杨基亚胺）烯醇化物，可用于 通过活性聚合反应从相应的乙烯基聚合物例如甲基丙烯酸甲酯生产乙烯基聚合物，如聚甲基丙烯酸甲酯。 路易斯酸可用于聚合反应。