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公开(公告)号:US4451678A
公开(公告)日:1984-05-29
申请号:US484267
申请日:1983-04-12
IPC分类号: B01J31/00 , C07B61/00 , C07C27/00 , C07C29/156 , C07C29/32 , C07C31/08 , C07C67/00 , C07C29/00
CPC分类号: C07C29/156 , C07C29/32
摘要: A process for producing ethanol which comprises reacting methanol, carbon monoxide and hydrogen in the presence of (a) a catalyst comprising cobalt or a cobalt compound and an alkyl phosphine as an effective component and (b) a co-catalyst comprising hydrochloric acid and in the absence of an iodide is disclosed. According to the present invention, formation of by-products becomes less and selectivity to realizable ethanol becomes higher.
摘要翻译: 一种生产乙醇的方法,其包括在(a)包含钴或钴化合物和烷基膦作为有效成分的催化剂存在下使甲醇,一氧化碳和氢气反应,和(b)包含盐酸的助催化剂和 没有公开碘化物。 根据本发明,副产物的形成变小,可实现乙醇的选择性变高。
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公开(公告)号:US4339597A
公开(公告)日:1982-07-13
申请号:US240966
申请日:1981-03-05
IPC分类号: B01J23/00 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533
CPC分类号: C07C69/52 , C07C67/333 , C07C69/533
摘要: A process for producing a 2-pentenoic ester which comprises contacting the corresponding 3-pentenoic ester with a composite catalyst composed of magnesia and alumina is disclosed.
摘要翻译: 公开了一种制备2-戊烯酸酯的方法,其包括使相应的3-戊烯酸酯与由氧化镁和氧化铝组成的复合催化剂接触。
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公开(公告)号:US4332966A
公开(公告)日:1982-06-01
申请号:US199332
申请日:1980-10-21
IPC分类号: C07C67/36 , C07C69/52 , C07C69/533
CPC分类号: C07C69/52 , C07C67/36 , C07C69/533
摘要: A process is disclosed for producing a 3-pentenoic ester which comprises reacting butadiene, carbon monoxide and an alcohol in the presence of cobalt carbonyl catalyst, characterized in that the reaction is carried out in a reaction medium composed of at least two solvents selected from the group consisting of pyridine, quinoline, isoquinoline and substituted pyridine, substituted quinoline and substituted isoquinoline in which substituent or substituents are selected from the group consisting of alkyl having 1-6 carbon atoms, alkenyl having 1-6 carbon atoms, aryl, alkylaryl having 7-10 carbon atoms and aralkyl having 7-10 carbon atoms.
摘要翻译: 公开了一种制备3-戊烯酸酯的方法,该方法包括在羰基钴催化剂存在下使丁二烯,一氧化碳和醇反应,其特征在于反应在由至少两种选自 由吡啶,喹啉,异喹啉和取代的吡啶组成的基团,取代的喹啉和取代的异喹啉,其中取代基或取代基选自具有1-6个碳原子的烷基,具有1-6个碳原子的烯基,芳基,具有7个 -10个碳原子和具有7-10个碳原子的芳烷基。
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公开(公告)号:US4605796A
公开(公告)日:1986-08-12
申请号:US682335
申请日:1984-12-17
IPC分类号: C07C29/32 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/156 , C07C31/08 , C07C67/00 , C07C29/00
CPC分类号: C07C29/156
摘要: A process for producing ethanol which comprises reacting methanol, carbon monoxide and hydrogen in the presence of (a) a catalyst comprising cobalt or a cobalt compound and a tertiary phosphine as an effective component and (b) promoter comprising an aromatic carboxylic acid, an ester thereof, or a cobalt salt of aromatic carboxylic acid is disclosed. According to the present invention, formation of by-products becomes less and selectivity to realizable ethanol becomes higher.
摘要翻译: 一种生产乙醇的方法,其包括在(a)包含钴或钴化合物和叔膦作为有效成分的催化剂存在下使甲醇,一氧化碳和氢气反应,和(b)包含芳族羧酸,酯 或芳族羧酸的钴盐。 根据本发明,副产物的形成变小,可实现乙醇的选择性变高。
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公开(公告)号:US4423258A
公开(公告)日:1983-12-27
申请号:US426140
申请日:1982-09-28
CPC分类号: C07C29/32
摘要: A process for producing ethanol which comprises reacting methanol, carbon monoxide and hydrogen, characterized in that the reaction is carried out in the presence of (a) an inert solvent and (b) a catalyst containing cobalt compound, a manganese compound and a tertiary phosphine. According to the present invention, amount of by-products formed is small.
摘要翻译: 一种生产乙醇的方法,其包括使甲醇,一氧化碳和氢气反应,其特征在于反应在(a)惰性溶剂和(b)含有钴化合物,锰化合物和叔膦的催化剂存在下进行 。 根据本发明,形成的副产物的量少。
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公开(公告)号:US4408080A
公开(公告)日:1983-10-04
申请号:US274360
申请日:1981-06-16
IPC分类号: C07C47/06 , B01J23/74 , B01J27/00 , B01J27/08 , C07C45/00 , C07C45/49 , C07C45/50 , C07C67/00
CPC分类号: C07C45/49
摘要: In a process for producing acetaldehyde which comprises reacting a mixture of methanol and methyl acetate with carbon monoxide and hydrogen in the presence of a cobalt-iodine catalyst, the improvement wherein methyl acetate is used in an amount of 0.4 to 9 parts by weight per part by weight of methanol, cobalt and iodine are used in an amount of 2 to 100 milligram-atoms and 8 to 200 milligram-atoms, respectively, per mole of the entire methyl groups in the methanol and methyl acetate, 1 to 4 iodine atoms being present per cobalt atom, and the reaction is carried out at a temperature lower than 160.degree. C. and a pressure of not more than 300 kg/cm.sup.2.
摘要翻译: 在制备乙醛的方法中,包括在钴 - 碘催化剂存在下使甲醇和乙酸甲酯与一氧化碳和氢气的混合物反应,其中乙酸甲酯的使用量为每部分重量为0.4-9份 的甲醇,钴和碘的用量分别为甲醇和乙酸甲酯中的每摩尔全部甲基为2至100毫克原子和8至200毫克原子,1至4个碘原子为 每个钴原子存在,并且反应在低于160℃的温度和不超过300kg / cm 2的压力下进行。
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公开(公告)号:US4404394A
公开(公告)日:1983-09-13
申请号:US318980
申请日:1981-11-06
摘要: A process for producing adipic acid diester which comprises the first step of reacting butadiene, carbon monoxide and an alcohol in the present of cobalt carbonyl catalyst at a temperature of from 80.degree. to 160.degree. C. to form a 3-pentenoic acid ester, andthe second step of reacting the 3-pentenoic acid ester in the reaction mixture, carbon monoxide and an alcohol at a temperature of from 160.degree. to 220.degree. C., characterized in that the first and second reactions are carried out in an amine solvent is disclosed.
摘要翻译: 一种生产己二酸二酯的方法,该方法包括在80℃至160℃的温度下在羰基催化剂中使丁二烯,一氧化碳和醇反应的第一步,形成3-戊烯酸酯,和 使反应混合物中的3-戊烯酸酯与一氧化碳和醇在160℃至220℃的温度下反应的第二步骤,其特征在于第一和第二反应在胺溶剂中进行, 披露
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公开(公告)号:US4350668A
公开(公告)日:1982-09-21
申请号:US246065
申请日:1981-03-20
CPC分类号: B01J31/20 , B01J31/403 , B01J2231/321 , B01J2531/0208 , B01J2531/845 , B01J31/0235
摘要: In a process for producing a 3-pentenoic ester which comprises reacting butadiene, carbon monoxide and an alcohol in the presence of a solvent and a catalyst selected from cobalt carbonyl or cobalt carbonyl complex, the improvement which comprises distilling the reaction mixture to remove organic volatile components comprised of the 3-pentenoic ester and the unreacted raw materials and the solvent and contacting the distillation residue with an organic solvent to dissolve and/or disperse the residue in the solvent and contacting the resulting organic solution with an aqueous acid solution to extract any cobalt component from the organic solution with the aqueous acid solution, and separating the aqueous acid solution containing the cobalt component from the organic solution, and neutralizing the aqueous acid solution with an alkaline solution to precipitate a cobalt component is disclosed.
摘要翻译: 在制备3-戊烯酸酯的方法中,其包括在溶剂和选自羰基钴或羰基钴络合物的催化剂存在下使丁二烯,一氧化碳和醇反应,其改进在于蒸馏反应混合物以除去有机挥发物 由3-戊烯酸酯和未反应的原料组成的组分和溶剂,并使蒸馏残余物与有机溶剂接触以使残余物溶解和/或分散在溶剂中,并使所得有机溶液与酸水溶液接触以提取任何 从有机溶液中加入含有酸溶液的钴组分,并将含有钴组分的酸水溶液与有机溶液分离,并用碱溶液中和酸水溶液沉淀出钴组分。
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公开(公告)号:US07780115B2
公开(公告)日:2010-08-24
申请号:US10584923
申请日:2004-10-01
申请人: Toshiyasu Watanabe
发明人: Toshiyasu Watanabe
IPC分类号: B64D11/06
CPC分类号: B64D11/0601 , B60N2/01 , B61D1/04 , B64D11/06 , Y02T30/30
摘要: An aircraft (or vehicle) and a vehicle seat arranging method by which the number of seats is increased to the maximum, while comfortability of passengers is ensured, includes a seat 20B immediately adjacent to an inner wall surface 11a out of a plurality of seats 20 provided in an array in a body 11 of an aircraft (or vehicle) 10, with the seat 20B being arranged inwardly obliquely so that a foot clearance of passengers is ensured. Oblique angles of mutually adjacent seats 20A, 20B can be made different from each other to form a fan shape so that passengers are prevented from interfering with each other on their shoulders. Also, baggage receiving spaces 30 provided in immediate front of the seats 20A, 20B, respectively, can be arranged so as not to interfere with each other.
摘要翻译: 一种飞机(或车辆)和车座安排方法,其中座位数量增加到最大,同时确保乘客的舒适性,包括立即与多个座位20中的内壁表面11a相邻的座椅20B 设置在飞行器(或车辆)10的主体11中的阵列中,其中座椅20B被向内倾斜地布置,使得确保乘客的脚间隙。 相互相邻的座20A,20B的倾斜角度可以彼此不同以形成扇形,从而防止乘客在他们的肩上相互干扰。 此外,分别设置在座位20A,20B的前方的行李接收空间30可以布置成不会彼此干涉。
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公开(公告)号:US06657556B2
公开(公告)日:2003-12-02
申请号:US10050844
申请日:2002-01-18
申请人: Koichi Ogura , Toshiyasu Watanabe , Shunji Yano , Naoki Terada
发明人: Koichi Ogura , Toshiyasu Watanabe , Shunji Yano , Naoki Terada
IPC分类号: G08G114
CPC分类号: G08G1/207 , G06Q10/02 , G06Q10/025 , G07B15/02 , G07C9/00039 , G07C9/00309 , G07F17/0042
摘要: A vehicle managing system including a vehicle to be lent to a user and a plurality of ports used for parking the vehicle. The plurality of ports include a first port which is located in the vicinity of a station of a transportation facility, and a second port which is located in the vicinity of both a residential area where a first user who uses the station resides and a place of destination for a second user who uses the station. In the vehicle managing system, the users are divided into a plurality of groups based on a direction of the vehicle between the first port and second port and a time zone using the vehicle, and the vehicles are alternately assigned to a group that moves to the station and another group that moves from the station based on the order of the time zone using the vehicle.
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