Abstract:
Highly-ordered block copolymer films are prepared by a method that includes forming a polymeric replica of a topographically patterned crystalline surface, forming a block copolymer film on the topographically patterned surface of the polymeric replica, and annealing the block copolymer film. The resulting structures can be used in a variety of different applications, including the fabrication of high density data storage media. The ability to use flexible polymers to form the polymeric replica facilitates industrial-scale processes utilizing the highly-ordered block copolymer films.
Abstract:
Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.
Abstract:
A method for forming a patterned film on a substrate, the method including: providing a first flowable medium on the substrate and a second flowable medium on the first flowable medium, the first and second flowable media having different dielectric properties and defining an interface there between; applying an electric field to the interface for a time sufficient to produce a structure in the first flowable medium along the interface; and hardening the structure in the first flowable medium to form the patterned film.
Abstract:
The thermal stability of an N,N-dinitramide salt of the formula M.sup.+ �N(NO.sub.2).sub.2 !.sup.- where M.sup.+ is a nitrogen-containing cation, is improved by mixing with the N,N-dinitramide salt a compound of the formula ##STR1## where R, R' and R" are the same or different and are aryl or alkyl. A new composition of matter is formed by mixing the N,N-dinitramide salt and the prophosphatrane compound.
Abstract:
A nanopatterned surface is prepared by forming a block copolymer film on a miscut crystalline substrate, annealing the block copolymer film, then reconstructing the surface of the annealed block copolymer film. The method creates a well-ordered array of voids in the block copolymer film that is maintained over a large area. The nanopatterned block copolymer films can be used in a variety of different applications, including the fabrication of high density data storage media.
Abstract:
A method for neutralizing explosive ordnance is provided. According to an aspect of the method, an energetic charge is activated to produce a shockwave, which is imparted at an effective velocity and temperature on a gas to ionize the gas for creating plasma and to drive the plasma. The plasma is impacted on a casing of an ordnance containing an explosive to penetrate through the casing and, without or before causing an explosive event of explosive within the casing, substantially consume the explosive.
Abstract:
An apparatus for measuring pressure in a medium includes a laser for emitting linearly polarized light; a polarizing beam splitter that reflects the linearly polarized light from the laser; a first lens that receives and focuses the linearly polarized light from the polarizing beam splitter; an optical fiber having first and second ends, the first end for receiving the linearly polarized light from the first lens, the second end comprising a tip disposed in the medium, the tip receiving reflected light from the medium, the reflected light being transmitted back through the optical fiber and the first lens to the polarizing beam splitter; the polarizing beam splitter transmitting the reflected light that has polarization orthogonal to the linearly polarized light emitted by the laser but not transmitting the reflected light that has polarization substantially parallel to the linearly polarized light emitted by the laser; a second lens for receiving the reflected light that has polarization orthogonal to the linearly polarized light emitted by the laser; a photodiode for receiving the orthogonal reflected light from the second lens; an oscilloscope connected to the photodiode; and a delay generator connected to the photodiode, the oscilloscope and the laser.
Abstract:
A block copolymer film having a line pattern with a high degree of long-range order is formed by a method that includes forming a block copolymer film on a substrate surface with parallel facets, and annealing the block copolymer film to form an annealed block copolymer film having linear microdomains parallel to the substrate surface and orthogonal to the parallel facets of the substrate. The line-patterned block copolymer films are useful for the fabrication of magnetic storage media, polarizing devices, and arrays of nanowires.
Abstract:
The invention provides for a nanostructured silicon or holey silicon (HS) that has useful thermoelectric properties. The invention also provides for a device comprising the nanostructured silicon or HS. The HS can be placed between two electrodes and used for thermoelectric power generation or thermoelectric cooling.
Abstract:
A nanopatterned surface is prepared by forming a block copolymer film on a miscut crystalline substrate, annealing the block copolymer film, then reconstructing the surface of the annealed block copolymer film. The method creates a well-ordered array of voids in the block copolymer film that is maintained over a large area. The nanopatterned block copolymer films can be used in a variety of different applications, including the fabrication of high density data storage media.