公开(公告)号：US20210179892A1

公开(公告)日：2021-06-17

申请号：US17169119

申请日：2021-02-05

申请人： Sirrus, Inc.

发明人： Bernard M. Malofsky ,  Adam G. Malofsky ,  Matthew M. Ellison

IPC分类号： C09J4/00 ,  B32B27/28 ,  B32B29/00 ,  B32B15/18 ,  B32B7/12 ,  B32B15/20 ,  B32B5/24 ,  B32B15/04 ,  B32B27/36 ,  B32B27/32 ,  B32B21/04 ,  C09J5/00 ,  C08F122/14 ,  C08F20/36 ,  C08J3/24 ,  C08F222/14 ,  C08F20/28 ,  C08J5/24 ,  C08K3/22 ,  C08K3/36 ,  C08K7/06 ,  C08K7/14 ,  C09J11/04 ,  C09J11/08

摘要： A composite material comprises a reinforcing material carried in a polymer matrix material which is the polymerization product of a polymerizable composition comprising a di-activated vinyl compound, with the proviso that the di-activated vinyl compound is not a cyanoacrylate. The reinforcing materials may be a wide variety of substrates including thermally sensitive materials. Exemplary composites can be molded and cured at ambient temperatures. Also disclosed are laminate materials having layered materials adhered by curing a di-activated vinyl polymerizable composition.

公开(公告)号：US20200223779A1

公开(公告)日：2020-07-16

申请号：US16641415

申请日：2018-09-12

申请人： Sirrus, Inc.

发明人： Jeffrey M. Sullivan ,  Ami Doshi ,  Kshitij Kishen Parab

IPC分类号： C07C67/30 ,  C07C45/61 ,  B01J31/04

摘要： The present teachings disclose contacting an amine salt catalyst with a dicarbonyl compound having an alkylene group between the carbonyl group; adding formaldehyde, paraformaldehyde, or formalin in an amount of about 2:1 to about 3:1 moles of formaldehyde to moles of the dicarbonyl compound to form a mixture; and refluxing the mixture. The process forms a carbonyl-substituted alkene. The process may be performed in the absence of a solvent. The process may form methylene malonates, methylene dimalonates, methylene keto malonamides, methylene diketones, methylene keto esters, and the like.

公开(公告)号：US10703842B2

公开(公告)日：2020-07-07

申请号：US16147859

申请日：2018-09-30

申请人： Sirrus, Inc.

发明人： Peter Rulon Stevenson ,  Aniruddha Sudhir Palsule ,  Jeffrey M. Sullivan

IPC分类号： C08F22/14 ,  C08F16/36 ,  C08K9/10 ,  C09J4/06 ,  B01J13/18 ,  B01J13/22 ,  C08F222/14 ,  C09J135/02 ,  C08K5/00 ,  C08K3/01 ,  C08L27/06 ,  C08J3/24 ,  C08K5/11

摘要： A polymerizable system includes a curable composition and one or more encapsulated initiator particles. The curable composition can include one or more 1,1-disubstituted alkene compounds and the encapsulated initiator particles can include one or more polymerization initiators encapsulated by a cured composition. The cured composition includes one or more 1,1-disubstituted alkene compounds.

公开(公告)号：US10607910B2

公开(公告)日：2020-03-31

申请号：US14648629

申请日：2013-11-27

申请人： Sirrus, Inc.

发明人： Bernard Miles Malofsky ,  Adam Gregg Malofsky ,  Matthew McBrayer Ellison

IPC分类号： H01L23/29 ,  H01L21/56 ,  H01L23/498 ,  H01L23/00

摘要： An electronics composition includes a curable matrix material and, optionally, a filler material disposed within the matrix material. The cured matrix material includes an oligomer or polymer material derived from a compound selected from a methylene malonate monomer, a multifunctional methylene monomer, a methylene beta ketoester monomer, a methylene beta diketone monomer, or a mixture thereof.

公开(公告)号：US10519257B2

公开(公告)日：2019-12-31

申请号：US15857808

申请日：2017-12-29

申请人： SIRRUS, INC.

发明人： Jeffrey M. Sullivan ,  Aniruddha Palsule ,  Alexander R. Holzer ,  Kshitij K. Parab ,  Ami Doshi

IPC分类号： C08F22/10 ,  C07C69/50 ,  C08F222/14 ,  C09J135/02 ,  C08F2/06 ,  C07C69/593

摘要： The disclosure relates to compositions containing 1,1-di-carbonyl-substituted alkene compounds capable of preparing polymers having glass transition temperatures above room temperature. The present teaching also relates to polymers prepared 1,1-di-carbonyl-substituted alkene compounds which exhibit glass transition temperatures of 60° C. The disclosure also relate to methods for enhancing the glass transition temperatures of polymers prepared from 1,1-di-carbonyl-substituted alkene compounds.

公开(公告)号：US20190315892A1

公开(公告)日：2019-10-17

申请号：US16455040

申请日：2019-06-27

申请人： Sirrus, Inc.

发明人： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan

IPC分类号： C08F20/28 ,  C08F24/00 ,  C07C67/333 ,  C07D333/24 ,  C09D129/12 ,  C08F128/06 ,  C08F116/36 ,  C07D333/22 ,  C09D141/00 ,  C07D307/46 ,  C09J133/06 ,  C08F20/68 ,  C07C67/343 ,  C08F20/14 ,  C09D4/00 ,  C09J4/00 ,  C08K3/013 ,  C08K5/00 ,  C07C67/30 ,  C07C49/80 ,  C09J133/16 ,  C09J135/02 ,  C09D135/02 ,  C09D133/16 ,  C09D133/14 ,  C08F20/30 ,  C07C69/738 ,  C08F28/06 ,  C08F222/14 ,  C08L35/02 ,  C08L33/16 ,  C08L33/14 ,  C08L21/00 ,  C08F22/20 ,  C08F20/38 ,  C07D307/54 ,  C09J133/14 ,  C07C45/75 ,  C07C49/798 ,  C07C49/796 ,  C07C49/794 ,  C07C67/03 ,  C07C69/604

摘要： The present teachings are directed at 1,1-di substituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

公开(公告)号：US20180346615A1

公开(公告)日：2018-12-06

申请号：US15978923

申请日：2018-05-14

申请人： Sirrus, Inc.

发明人： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Matthew M. Ellison ,  Larry Hines

IPC分类号： C08F20/28 ,  C09D4/00 ,  C07D307/54 ,  C08K3/013 ,  C08F20/14 ,  C09J133/14 ,  C08F20/30 ,  C08F20/38 ,  C08F22/20 ,  C08K5/00 ,  C08L21/00 ,  C08L33/14 ,  C08L33/16 ,  C08L35/02 ,  C09D133/14 ,  C09D135/02 ,  C09J135/02 ,  C09J133/16 ,  C09D133/16 ,  C07C49/80 ,  C07C67/03 ,  C07C69/604

CPC分类号： C08F20/28 ,  C07C45/75 ,  C07C49/794 ,  C07C49/796 ,  C07C49/798 ,  C07C49/80 ,  C07C67/03 ,  C07C67/30 ,  C07C69/604 ,  C07C69/738 ,  C07D307/46 ,  C07D307/54 ,  C07D333/22 ,  C07D333/24 ,  C08F20/14 ,  C08F20/30 ,  C08F20/38 ,  C08F20/68 ,  C08F22/20 ,  C08F24/00 ,  C08F28/06 ,  C08F116/36 ,  C08F128/06 ,  C08F222/1006 ,  C08F222/14 ,  C08K3/013 ,  C08K5/0008 ,  C08L21/00 ,  C08L33/14 ,  C08L33/16 ,  C08L35/02 ,  C09D4/00 ,  C09D129/12 ,  C09D133/14 ,  C09D133/16 ,  C09D135/02 ,  C09D141/00 ,  C09J133/06 ,  C09J133/14 ,  C09J133/16 ,  C09J135/02 ,  Y02P20/127

摘要： The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

公开(公告)号：US10081685B2

公开(公告)日：2018-09-25

申请号：US15467330

申请日：2017-03-23

申请人： Sirrus, Inc.

发明人： Peter Rulon Stevenson ,  Alexander R. Holzer ,  Aniruddha Sudhir Palsule ,  Jeffrey M. Sullivan

IPC分类号： C08F2/24 ,  C08F22/14 ,  C08F267/06 ,  C08F2/26 ,  C08F122/14

CPC分类号： C09J135/02 ,  B01J19/10 ,  B01J19/18 ,  C08F2/26 ,  C08F2/30 ,  C08F22/10 ,  C08F122/14 ,  C08F267/06 ,  C08J3/07 ,  C08K5/103 ,  C08K5/1535 ,  C08K5/42 ,  C09D7/63 ,  C09D7/65 ,  C09D135/02 ,  C09J11/06 ,  C09J11/08

摘要： The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US10047192B2

公开(公告)日：2018-08-14

申请号：US14404870

申请日：2013-05-31

申请人： Sirrus, Inc.

发明人： Matthew McBrayer Ellison ,  Bernard Miles Malofsky ,  Adam Gregg Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan

IPC分类号： B01F17/00 ,  C08G63/00 ,  C08F18/14 ,  G02B1/04 ,  C08F222/10 ,  C07C69/38 ,  C07C69/708 ,  C09J5/00 ,  C09J167/00 ,  G02B6/255

CPC分类号： C08G63/00 ,  C07C69/38 ,  C07C69/708 ,  C08F18/14 ,  C08F222/10 ,  C09J5/00 ,  C09J167/00 ,  G02B1/04 ,  G02B6/255 ,  C08L31/06

摘要： Optical materials including polymerizable compositions and oligomeric and polymeric material formed therefrom. The oligomer or polymer material include structural repeat units. The optical material has low or substantially no absorbance of wavelengths in at least one of the spectral regions of interest. Optical components include adhesives, waveguides, spherical or non-spherical optical lenses, architectural articles, automotive components, laminated structures and composites.

公开(公告)号：US20170355789A1

公开(公告)日：2017-12-14

申请号：US15661893

申请日：2017-07-27

申请人： SIRRUS, INC.

发明人： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan

IPC分类号： C08F20/28 ,  C09D135/02 ,  C07C67/30 ,  C08L33/14 ,  C08F24/00 ,  C08F20/68 ,  C07C69/604 ,  C09J133/16 ,  C07C49/794 ,  C09D133/16 ,  C08F20/38 ,  C07C49/80 ,  C08F20/30 ,  C07D307/54 ,  C08K3/00 ,  C08K5/00 ,  C08F128/06 ,  C07C49/798 ,  C07D333/22 ,  C07C49/796 ,  C09J133/06 ,  C07C69/738 ,  C07C67/03 ,  C09J133/14 ,  C07C45/75 ,  C08F28/06 ,  C09D141/00 ,  C09D129/12 ,  C08F116/36 ,  C08L21/00 ,  C08F22/20 ,  C07D307/46 ,  C08L33/16 ,  C08L35/02 ,  C09J135/02 ,  C07D333/24 ,  C09D133/14 ,  C08F222/14 ,  C08F222/10

CPC分类号： C08F20/28 ,  C07C45/75 ,  C07C49/794 ,  C07C49/796 ,  C07C49/798 ,  C07C49/80 ,  C07C67/03 ,  C07C67/30 ,  C07C67/333 ,  C07C67/343 ,  C07C69/604 ,  C07C69/738 ,  C07C2601/02 ,  C07C2601/04 ,  C07C2601/08 ,  C07C2601/14 ,  C07D307/46 ,  C07D307/54 ,  C07D333/22 ,  C07D333/24 ,  C08F20/14 ,  C08F20/30 ,  C08F20/38 ,  C08F20/68 ,  C08F22/20 ,  C08F24/00 ,  C08F28/06 ,  C08F116/36 ,  C08F128/06 ,  C08F222/1006 ,  C08F222/14 ,  C08K3/013 ,  C08K5/0008 ,  C08K5/005 ,  C08K5/08 ,  C08K5/13 ,  C08L21/00 ,  C08L33/14 ,  C08L33/16 ,  C08L35/02 ,  C09D4/00 ,  C09D129/12 ,  C09D133/14 ,  C09D133/16 ,  C09D135/02 ,  C09D141/00 ,  C09J4/00 ,  C09J133/06 ,  C09J133/14 ,  C09J133/16 ,  C09J135/02 ,  Y02P20/127 ,  C07C69/716

摘要： The present teachings are directed at 1,1-disubstituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).