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公开(公告)号：US07135152B2
公开(公告)日：2006-11-14
申请号：US10842171
申请日：2004-05-10
CPC分类号： C10G2/342 , B01J8/1809 , B01J8/228 , B01J2208/00548
摘要： A gas-agitated multiphase reactor system with multiple reaction zones comprising gas-liquid or gas-liquid-solid mixtures that can maximize the production rate while allowing better control of the temperature distribution and better control of the liquid and solid phases in the reactors. Still more particularly, this invention relates to a method for operating a pair of linked gas-agitated slurry reaction zones such that the hydrodynamic behavior and reactor performance of such reactor system are improved compared to that of a conventional slurry bed reactor
摘要翻译： 具有多个反应区域的气体搅拌多相反应器系统，其包括气液或气 - 液 - 固 - 固混合物，其可以最大化生产速率，同时更好地控制温度分布并更好地控制反应器中的液相和固相。 更具体地说，本发明涉及一种用于操作一对连接的气体搅拌浆料反应区的方法，使得与常规淤浆床反应器相比，这种反应器系统的流体动力学行为和反应器性能得到改善
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公开(公告)号：US07078439B2
公开(公告)日：2006-07-18
申请号：US10753140
申请日：2004-01-07
申请人： Oluwaseyi A. Odueyungbo , Rafael L. Espinoza , Sergio R. Mohedas , James Dale Ortego, Jr. , Beatrice C. Ortego , Ralph T. Goodwin , Todd H. Harkins
发明人： Oluwaseyi A. Odueyungbo , Rafael L. Espinoza , Sergio R. Mohedas , James Dale Ortego, Jr. , Beatrice C. Ortego , Ralph T. Goodwin , Todd H. Harkins
CPC分类号： C10G2/33 , B01D21/0045 , C10G2/331 , C10G2/342
摘要： This invention relates to methods and apparatus for separating liquid products and catalyst particles from a slurry used in a Fischer-Tropsch reactor system. The preferred embodiments of the present invention are characterized by a separation system that uses a sedimentation chamber, which contains at least one inclined channel that enhances the settling of particles within the slurry. The enhanced settling separates the slurry into a catalyst-rich bottom stream and a catalyst-lean overhead stream. The catalyst-rich bottom product stream is preferably recycled to the reactor, while the catalyst-lean overhead stream can be further processed by a secondary separation system to produce valuable synthetic fuels. The inclined channel may be provided by a structure selected from the group consisting of tube, pipe, conduit, sheets, trays, walls, plates, and combinations thereof.
摘要翻译： 本发明涉及用于从费 - 托反应器系统中使用的浆料中分离液体产物和催化剂颗粒的方法和装置。 本发明的优选实施方案的特征在于分离系统，其使用沉淀室，该沉淀室包含至少一个倾斜通道，其增强了浆料内颗粒的沉降。 增强的沉降将浆料分离成富含催化剂的底部流和贫催化塔顶流。 富催化剂的底部产物流优选地循环到反应器中，而贫催化催化剂塔顶流可以通过二次分离系统进一步加工以产生有价值的合成燃料。 倾斜通道可以由选自由管，管，导管，片，盘，壁，板及其组合组成的组中的结构提供。
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公开(公告)号：US06929754B2
公开(公告)日：2005-08-16
申请号：US10414636
申请日：2003-04-16
申请人： Rafael L. Espinoza , Sergio R. Mohedas , Doug S. Jack , Oluwaseyi A. Odueyungbo , James Dale Ortego, Jr.
发明人： Rafael L. Espinoza , Sergio R. Mohedas , Doug S. Jack , Oluwaseyi A. Odueyungbo , James Dale Ortego, Jr.
CPC分类号： B01D37/02 , B01D29/15 , B01D29/60 , B01D37/043
摘要： Methods and apparatus for removing wax products from a slurry used in a Fischer-Tropsch reactor. The preferred embodiments of the present invention are characterized by a solid/liquid separation system that removes liquid products from a slurry by drawing the fluid across a filter medium composed of a filter cake disposed on a substrate. In the preferred embodiments, the filter cake is desirable and performs the majority of the filtration. In certain embodiments, the filter medium is disposed in a filter housing where slurry flows parallel to the longitudinal axis of the filter medium from and inlet to an outlet. The characteristics or properties of the cake, which will effect the performance of the solid/liquid separation system, can be controlled by regulating the velocity of the slurry flowing across the cake, where the velocity may be regulated by adjusting the slurry flow through the filter housing or may be self-regulated by changing slurry velocities influenced by the design of the filter housing.
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4.发明授权Managing hydrogen and carbon monoxide in a gas to liquid plant to control the H2/CO ratio in the Fischer-Tropsch reactor feed 失效管理气体到液体设备中的氢气和一氧化碳，以控制费 - 托反应堆进料中的H2 / CO比公开(公告)号：US06872753B2
公开(公告)日：2005-03-29
申请号：US10388843
申请日：2003-03-15
申请人： Stephen R. Landis , Rafael L. Espinoza , Sergio R. Mohedas , Barbara A. Belt , Vincent H. Melquist , Ralph T. Goodwin, III
发明人： Stephen R. Landis , Rafael L. Espinoza , Sergio R. Mohedas , Barbara A. Belt , Vincent H. Melquist , Ralph T. Goodwin, III
CPC分类号： C01B3/48 , C01B3/386 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0475 , C01B2203/061 , C01B2203/062
摘要： The present invention provides a process for controlling the ratio of hydrogen to carbon monoxide in feed streams to reactors that convert syngas to hydrocarbon liquids. The process includes primary syngas production process for converting hydrocarbon gas to syngas comprising hydrogen and carbon monoxide. The process further includes introducing a hydrogen rich stream, a carbon monoxide rich stream, or both produced by an auxiliary source to a feed stream being passed to a reactor for converting the syngas to hydrocarbon liquid, thereby adjusting the H2/CO ratio in the feed stream. Examples of reactors that may be used to convert syngas to hydrocarbon liquids are FT reactors staged in series and oxygenate producing reactors staged in series.
摘要翻译： 本发明提供了一种控制进料流中的氢气与一氧化碳与将合成气转化为烃液体的反应器的比例的方法。 该方法包括用于将烃气转化成包含氢气和一氧化碳的合成气的初级合成气生产方法。 该方法还包括将富氢流，一氧化碳浓缩物流或由辅助源产生的二者引入进料流中，将其转化为反应器以将合成气转化为烃液体，由此调节进料中的H 2 / CO比 流。 可用于将合成气转化为烃类液体的反应器的实例是分级式的FT反应器和串联的含氧化合物反应器。
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公开(公告)号：US07232848B2
公开(公告)日：2007-06-19
申请号：US10238008
申请日：2002-09-09
CPC分类号： C10G2/341 , B01J8/0292 , B01J8/067 , B01J10/007 , B01J2208/00132 , B01J2208/00194 , B01J2208/00203 , B01J2208/00814 , B01J2208/00884 , B01J2219/00081 , C07C27/22
摘要： An apparatus for converting a gaseous and/or liquid feed fluid to gaseous and/or liquid products using a solid catalyst comprises a reactor, a liquid phase disposed within the reactor volume, a fixed catalyst at least partially disposed in the liquid phase, a cooling system having a cooling element in thermal contact with the liquid phase, a feed inlet positioned to feed the feed fluid into the reactor volume, and a fluid outlet in fluid communication with the liquid phase. The catalyst is contained in a catalyst container and the container may be adjacent to said cooling element, extend through said cooling element, or may surround the catalyst container. The catalyst may be a Fischer-Tropsch catalyst.
摘要翻译： 使用固体催化剂将气体和/或液体进料流体转化为气体和/或液体产物的装置包括反应器，设置在反应器体积内的液相，至少部分地设置在液相中的固定催化剂，冷却 系统，其具有与液相热接触的冷却元件，定位成将进料流体进料到反应器体积中的进料口和与液相流体连通的流体出口。 催化剂包含在催化剂容器中，并且容器可以与所述冷却元件相邻，延伸穿过所述冷却元件，或可围绕催化剂容器。 催化剂可以是费 - 托催化剂。
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公开(公告)号：US06887390B2
公开(公告)日：2005-05-03
申请号：US10417307
申请日：2003-04-16
申请人： Sergio R. Mohedas , Rafael L. Espinoza , Doug S. Jack , Oluwasei A. Odueyungbo , James Dale Ortego, Jr.
发明人： Sergio R. Mohedas , Rafael L. Espinoza , Doug S. Jack , Oluwasei A. Odueyungbo , James Dale Ortego, Jr.
CPC分类号： B01D37/02 , B01D29/15 , B01D29/60 , B01D37/043
摘要： Methods for producing clean liquid/wax products from a slurry used in a Fischer-Tropsch reactor are disclosed. In general, one embodiment of the present invention comprises a solid/liquid filtration system having a filter medium comprising a substrate and a filter cake deposited on the substrate, wherein the filter cake is generated by deposition of solids from the slurry. The thickness of the filter cake can be maintained within a desired range by controlling the slurry velocity and/or the pressure differential across the filter medium. This invention relates to a method of operation of such filtration system which increases filtration cycle time and improved filtrate quality resulting in very low solid content in filtrate.
摘要翻译： 公开了从费 - 托反应器中使用的浆料制备清洁液体/蜡产品的方法。 通常，本发明的一个实施方案包括具有过滤介质的固体/液体过滤系统，该过滤介质包括沉积在基底上的基底和滤饼，其中通过从浆液沉积固体产生滤饼。 通过控制过滤介质上的浆料速度和/或压力差，滤饼的厚度可以保持在所需范围内。 本发明涉及这种过滤系统的操作方法，其增加了过滤循环时间并提高了滤液质量，导致滤液中固体含量非常低。
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7.发明授权Prevention of and recovering from a catalyst bed slumping in a gas-agitated multiphase reactor 有权在气体搅拌的多相反应器中预防和从催化剂床中回收坍落公开(公告)号：US07230034B2
公开(公告)日：2007-06-12
申请号：US10804521
申请日：2004-03-19
申请人： Sergio R. Mohedas , Rafael L. Espinoza , Jack E. Cnossen , Todd H. Harkins , Vincent H. Melquist , Larry D. Swinney
发明人： Sergio R. Mohedas , Rafael L. Espinoza , Jack E. Cnossen , Todd H. Harkins , Vincent H. Melquist , Larry D. Swinney
IPC分类号： C07C27/00
CPC分类号： B01J8/22 , B01J8/1809 , B01J8/1827 , B01J2208/00088 , B01J2208/00132 , B01J2208/00548 , C10G2/344
摘要： The invention relates to methods for prevention of and recovery from a catalyst bed slumping in a gas-agitated multiphase hydrocarbon synthesis reactor, while the reactor is either under non-reactive conditions or under reaction promoting conditions when syngas is converted to products. The reactor contains a catalyst bed comprising catalyst particles and a gas injection zone suitable for injecting a reactor gas feed. A method for preventing bed slumping comprises supplying a supplemental gas to the gas-agitated multiphase reactor to prevent the catalyst bed from slumping due to insufficient reactor gas feed flow. The method may include recycling some or all of the supplemental gas to the reactor. The method may further comprise separating the gas injection zone from the catalyst bed with a porous plate so as to prevent migration of catalyst particles into the gas injection zone and to minimize plugging of gas distributor(s) present in said zone.
摘要翻译： 本发明涉及用于在气体搅拌的多相烃合成反应器中预防和从催化剂床坍落的方法，同时当合成气转化成产物时，反应器处于非反应性条件或反应促进条件下。 反应器包含催化剂床，催化剂床包含催化剂颗粒和适于注入反应器气体进料的气体注入区。 防止床塌陷的方法包括向气体搅拌的多相反应器供应补充气体，以防止催化剂床由于反应器气体进料流量不足而塌陷。 该方法可以包括将一些或全部补充气体再循环到反应器中。 该方法可以进一步包括用多孔板将气体注入区与催化剂床分离，以防止催化剂颗粒迁移到气体注入区中并且使存在于所述区中的气体分配器的堵塞最小化。
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公开(公告)号：US06946493B2
公开(公告)日：2005-09-20
申请号：US10388884
申请日：2003-03-15
申请人： Sergio R. Mohedas , Stephen R. Landis , Rafael L. Espinoza , Ralph T. Goodwin, III , Barbara A. Belt
发明人： Sergio R. Mohedas , Stephen R. Landis , Rafael L. Espinoza , Ralph T. Goodwin, III , Barbara A. Belt
CPC分类号： C10G2/30 , C01B3/382 , C01B2203/00 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/0425 , C01B2203/046 , C01B2203/0475 , C01B2203/062 , C01B2203/065 , C01B2203/1041 , C01B2203/1082 , C01B2203/1241 , C01B2203/141 , C01B2203/145 , C01B2203/84 , C10G2/32 , C10G2/33 , Y02P20/584
摘要： The present invention provides a process for managing hydrogen in a hydrocarbon gas to liquid plant. The process includes feeding a syngas stream produced by a partial oxidation reactor to a Fischer-Tropsch reactor, thereby converting the syngas to hydrocarbon liquids. It also includes passing a substantially oxygen-free feed stream comprising hydrocarbon gas and water to a steam reformer, thereby producing a hydrogen-rich stream. The H2/CO ratio in the syngas feed stream can be adjusted to a desired value by introducing a first portion of the hydrogen-rich stream to the syngas feed stream. A second portion of the hydrogen-rich stream can be passed to one or more hydrogen users, e.g., a catalyst regeneration unit, in the GTL plant.
摘要翻译： 本发明提供了一种管理烃气体中的氢气到液态装置的方法。 该方法包括将由部分氧化反应器产生的合成气流进料到费 - 托反应器，从而将合成气转化为烃液体。 它还包括将包含烃气体和水的基本上无氧的进料流通入蒸汽重整器，从而产生富氢流。 通过将富氢流的第一部分引入合成气进料流，合成气进料流中的H 2 CO 2比可以调节至所需值。 富含氟的物流的第二部分可以通过GTL设备中的一个或多个氢使用者，例如催化剂再生单元。
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公开(公告)号：US06800664B1
公开(公告)日：2004-10-05
申请号：US10444459
申请日：2003-05-23
IPC分类号： C07C2700
CPC分类号： C10G2/342 , B01J8/1809 , B01J8/228 , B01J2208/00548
摘要： A gas-agitated multiphase reactor system with multiple reaction zones comprising gas-liquid or gas-liquid-solid mixtures that can maximize the production rate while allowing better control of the temperature distribution and better control of the liquid and solid phases in the reactors. Still more particularly, this invention relates to a method for operating a pair of linked gas-agitated slurry reaction zones such that the hydrodynamic behavior and reactor performance of such reactor system are improved compared to that of a conventional slurry bed reactor.
摘要翻译： 具有多个反应区域的气体搅拌多相反应器系统，其包括气液或气 - 液 - 固 - 固混合物，其可以最大化生产速率，同时更好地控制温度分布并更好地控制反应器中的液相和固相。 更具体地，本发明涉及一种用于操作一对连接的气体搅拌的浆料反应区的方法，使得与常规浆料床反应器相比，这种反应器系统的流体动力学行为和反应器性能得到改善。
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公开(公告)号：US07183327B2
公开(公告)日：2007-02-27
申请号：US10803319
申请日：2004-03-18
IPC分类号： C07C27/00
CPC分类号： C10G2/33 , B01J8/22 , B01J2208/00672 , B01J2208/00725 , C10G2/342
摘要： A method for selecting maximum and minimum catalyst particle sizes for use in a multiphase reactor that reflects optimum operating conditions of the reactor is based on a maximum Archimedes number for estimating the maximum particle size and a property of a separation system linked to the reactor to determine the minimum particle size. The maximum Archimedes number could be selected based on a maximum catalyst non-uniformity in the reactor. Additionally, a method for producing hydrocarbons from syngas in a slurry bubble column reactor comprises the use of a plurality of fresh catalyst particles with an optimum size distribution based on a range of Archimedes numbers between about 0.02 and 250 or alternatively based on an average Reynolds number less than about 0.1.
摘要翻译： 用于选择反映反应器的最佳操作条件的多相反应器中使用的最大和最小催化剂粒度的方法基于用于估计最大粒径的最大阿基米德数和连接到反应器的分离系统的性质来确定 最小粒径。 可以基于反应器中最大催化剂不均匀性来选择最大阿基米德数。 另外，在浆液鼓泡塔反应器中从合成气生产烃的方法包括使用多个新型催化剂颗粒，其具有基于约0.02至250的阿基米德数范围内的最佳尺寸分布，或者基于平均雷诺数 小于约0.1。
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