公开(公告)号：US20160115402A1

公开(公告)日：2016-04-28

申请号：US14877027

申请日：2015-10-07

申请人： Xiaochun Xu ,  Amanda K. MILLER ,  Adam MADLINGER ,  Richard J. QUANN ,  Dean Edwin PARKER ,  Jeffrey Lawrence KAUFMAN ,  Matthew KAWABE

发明人： Xiaochun Xu ,  Amanda K. MILLER ,  Adam MADLINGER ,  Richard J. QUANN ,  Dean Edwin PARKER ,  Jeffrey Lawrence KAUFMAN ,  Matthew KAWABE

IPC分类号： C10G65/12 ,  C10G69/02

摘要： Systems and methods are provided for producing an improved product slate during hydrocracking of a feedstock that results in production of naphtha and distillate fuels. The methods can include use of stacked beds and/or sequential reactors so that a feedstock is exposed to suitable catalysts under hydrocracking conditions and aromatic saturation conditions. The catalyst for performing the aromatic saturation process can be a catalyst including a Group VIII noble metal, such as Pt, Pd, or a combination thereof, while the hydrocracking catalyst can include Group VIB and Group VIII non-noble metals.

摘要翻译： 提供的系统和方法用于在原料加氢裂化过程中产生改进的产品板岩，从而产生石脑油和馏出燃料。 所述方法可以包括使用堆叠床和/或顺序反应器，使得原料在加氢裂化条件和芳族饱和条件下暴露于合适的催化剂。 用于进行芳族饱和过程的催化剂可以是包括VIII族贵金属如Pt，Pd或其组合的催化剂，而加氢裂化催化剂可以包括VIB族和VIII族非贵金属。

公开(公告)号：US5100535A

公开(公告)日：1992-03-31

申请号：US279748

申请日：1988-12-05

申请人： Nai Yuen Chen ,  Tai-Sheng Chou ,  Grant G. Karsner ,  Clinton R. Kennedy ,  Rene B. LaPierre ,  Melcon G. Melconian ,  Richard J. Quann ,  Stephen S. Wong

发明人： Nai Yuen Chen ,  Tai-Sheng Chou ,  Grant G. Karsner ,  Clinton R. Kennedy ,  Rene B. LaPierre ,  Melcon G. Melconian ,  Richard J. Quann ,  Stephen S. Wong

IPC分类号： C10G45/64 ,  C10G47/16 ,  C10G47/36

CPC分类号： C10G47/36 ,  C10G45/64 ,  C10G47/16 ,  Y10S208/01

摘要： Nitrogenous compounds especially bases such as amines are used to control the operation of a hydrocracker. Catalyst activity and selectivity may be controlled by addition of the base to the feed, for example, to control the balance between isomerization and conversion in an operation using a zeolite beta catalyst. Runaway conditions may be controlled by the addition of nitrogenous compounds and if they are added at intermediate points along the length of the reactor, the temperature profile within the reactor can be effectively regulated.

摘要翻译： 氮化合物特别是碱例如胺用于控制加氢裂化器的操作。 催化剂活性和选择性可以通过向进料添加碱来控制，例如在使用沸石β催化剂的操作中控制异构化和转化之间的平衡。 失控条件可以通过加入含氮化合物来控制，并且如果它们在反应器长度的中间点加入，则反应器内的温度曲线可被有效地调节。

公开(公告)号：US06676829B1

公开(公告)日：2004-01-13

申请号：US09456851

申请日：1999-12-08

申请人： Philip J. Angevine ,  Anna B. Gorshteyn ,  Larry A. Green ,  Yuk Mui Louie ,  David A. Pappal ,  Peter J. Owens ,  Richard J. Quann ,  Jolie A. Rhinehart

发明人： Philip J. Angevine ,  Anna B. Gorshteyn ,  Larry A. Green ,  Yuk Mui Louie ,  David A. Pappal ,  Peter J. Owens ,  Richard J. Quann ,  Jolie A. Rhinehart

IPC分类号： C10G4504

CPC分类号： C10G45/52 ,  C10G65/04 ,  C10G65/08

摘要： A method is provided for removing sulfur from an effluent produced by hydrotreating a hydrocarbon feed, said effluent having a heavy fraction containing polyaromatic sulfur compounds and a lighter fraction, said method comprising contacting the effluent with a noble metal containing hydrodearomatization catalyst on a support under super-atmospheric hydrogen pressure and reaction conditions sufficient to hydrogenate at least one ring of said polyaromatic sulfur compounds and thereby produce a product with a reduced sulfur content.

摘要翻译： 提供一种从通过加氢处理烃进料产生的流出物中除去硫的方法，所述流出物具有含有多芳族硫化合物的重馏分和较轻馏分，所述方法包括将流出物与含有脱氢脱氢催化剂的贵金属接触， - 大气压力和足以氢化所述多芳族硫化合物的至少一个环的反应条件，从而产生具有降低的硫含量的产物。

公开(公告)号：US4686317A

公开(公告)日：1987-08-11

申请号：US815342

申请日：1985-12-31

申请人： Richard J. Quann ,  Samuel A. Tabak

发明人： Richard J. Quann ,  Samuel A. Tabak

IPC分类号： C07C1/04 ,  C10G21/00 ,  C07C15/00

CPC分类号： C07C1/0485 ,  C10G21/00

摘要： A process for removing oxygenated impurities from a hydrocarbon stream includes extracting said oxygenates by a heavy organic polar solvent, water scrubbing the extracted hydrocarbon to recover dissolved solvent and combining the solvent phase from the extractor and the water phase from the scrubber and distilling to recover the solvent.

摘要翻译： 从烃流中除去含氧杂质的方法包括通过重的有机极性溶剂萃取所述含氧化合物，水洗涤所提取的烃以回收溶解的溶剂并将来自萃取器的溶剂相和来自洗涤器的水相组合并蒸馏以回收 溶剂。

公开(公告)号：US20150041634A1

公开(公告)日：2015-02-12

申请号：US14065626

申请日：2013-10-29

申请人： Richard J. Quann ,  William J. Novak ,  Kuangnan Qian ,  William E. Riedinger ,  Roger G. Gaughan ,  Beatrice M. Gooding

发明人： Richard J. Quann ,  William J. Novak ,  Kuangnan Qian ,  William E. Riedinger ,  Roger G. Gaughan ,  Beatrice M. Gooding

IPC分类号： G01N33/28 ,  H01J49/00 ,  G01N33/22 ,  C10G45/10 ,  C10L1/00

CPC分类号： G01N33/2841 ,  C10G45/10 ,  C10L1/00 ,  C10L2270/04 ,  C10L2290/60 ,  G01N33/22 ,  G01N33/2805 ,  H01J49/0027

摘要： Systems and methods are provided for characterizing kerosene fractions in order to determine whether the fractions will satisfy a desired thermal breakpoint specification. Additionally, hydrotreating conditions can be determined that will result in a hydrotreated kerosene fraction that satisfies the desired thermal breakpoint specification. The hydrotreating conditions can be determined based on a model constructed from data corresponding to a plurality of reference samples. The model can include data for compositional groups within the reference samples. The data for compositional groups can be derived from Fourier transform ion cyclotron resonance mass spectrometry data or from another suitable characterization technique.

摘要翻译： 提供系统和方法来表征煤油馏分，以确定馏分是否将满足所需的热断裂指标。 此外，可以确定加氢处理条件，这将导致满足期望热断裂规格的加氢处理煤油馏分。 加氢处理条件可以基于由对应于多个参考样品的数据构成的模型来确定。 该模型可以包括参考样本中的组成组的数据。 组成组的数据可以从傅里叶变换离子回旋共振质谱数据或另一种合适的表征技术得到。

公开(公告)号：US4587012A

公开(公告)日：1986-05-06

申请号：US547704

申请日：1983-10-31

申请人： Richard J. Quann

发明人： Richard J. Quann

IPC分类号： B01J21/00 ,  B01J21/04 ,  B01J23/00 ,  B01J35/10 ,  C10G45/04 ,  C10G49/02 ,  C10G45/06

CPC分类号： C10G49/02 ,  B01J21/04 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  C10G45/04

摘要： A process for upgrading a hydrocarbonaceous feedstock employing an alumina-based catalyst at least a portion of which is in the alpha phase. The catalyst has at least 25% of its pore volume in pores from 300-1,000 .ANG. in diameter, has no more than 10% macropores, and has a surface area of less that 100 m.sup.2 /g.

摘要翻译： 一种使用氧化铝基催化剂升级含烃原料的方法，所述氧化铝基催化剂的至少一部分处于α相。 该催化剂的孔体积至少为孔体积的25％，直径为300-1,000，不超过10％的大孔，表面积小于100m2 / g。

公开(公告)号：US20160060545A1

公开(公告)日：2016-03-03

申请号：US14810048

申请日：2015-07-27

申请人： Mark A. GREANEY ,  Richard J. QUANN ,  Heather A. ELSEN ,  Kuangnan QIAN ,  Anthony S. MENNITO

发明人： Mark A. GREANEY ,  Richard J. QUANN ,  Heather A. ELSEN ,  Kuangnan QIAN ,  Anthony S. MENNITO

IPC分类号： C10G32/02 ,  C10G29/00 ,  C10L1/04 ,  C10G31/06

CPC分类号： C10G32/02 ,  C10G49/007 ,  C10G49/06 ,  C10G49/18 ,  C10G2300/1048 ,  C10G2300/202 ,  C10L2200/043 ,  C10L2270/04 ,  C10L2290/38

摘要： The stability of distillate type jet fuels is improved by cathodic hydrogenation in an electrolytic cell with a proton permeable membrane separating cathode and anode compartments; a source of hydrogen is oxidized in the anode compartment to form protons which permeate the membrane to effect a cathodic reduction of the nitrogenous components of the fuel in the cathode compartment.

摘要翻译： 通过在具有分离阴极和阳极隔室的质子渗透膜的电解池中进行阴极氢化，改善了馏出型喷气燃料的稳定性; 氢源在阳极室中被氧化以形成渗透膜的质子，以实现阴极室中燃料的含氮组分的阴极还原。

公开(公告)号：US20110277377A1

公开(公告)日：2011-11-17

申请号：US13106282

申请日：2011-05-12

申请人： William J. Novak ,  Randolph J. Smiley ,  Richard J. Quann ,  Karlton J. Hickey

发明人： William J. Novak ,  Randolph J. Smiley ,  Richard J. Quann ,  Karlton J. Hickey

IPC分类号： C10L1/00

CPC分类号： C10L1/026 ,  C10G2300/1011 ,  C10G2300/1059 ,  C10G2300/202 ,  Y02E50/13 ,  Y02P30/20

摘要： This invention provides low sulfur fuels, particularly low sulfur bunker fuels, comprising hydroprocessed pyrolysis oil. The hydroprocessed pyrolysis oil can be produced using a catalyst suited to processing pyrolysis oils that may be relatively high in water content and under relatively low severity conditions to limit water formation, while making the hydroprocessed pyrolysis oil more stable than prior to hydroprocessing. The pyrolysis oil can be converted to a more stable hydroprocessed product, e.g., by converting at least a majority of the aldehydes, ketones, and/or carboxylic acids in the pyrolysis oil to more highly stable compounds, such as alcohols. The hydroprocessed product can be particularly suited as a blend component for producing a variety of reduced sulfur fuels.

摘要翻译： 本发明提供了包含加氢热解油的低硫燃料，特别是低硫燃料。 加氢处理的裂解油可以使用适于加工热解油的催化剂来生产，该催化裂化油的水分含量相对较高，并且在相对低的苛刻度条件下限制水的形成，同时使得加氢热解油比加氢处理更稳定。 热解油可以转化为更稳定的加氢处理产物，例如通过将热解油中的至少大部分醛，酮和/或羧酸转化成更稳定的化合物，例如醇。 加氢处理的产品可以特别适用于生产各种还原硫燃料的混合组分。

公开(公告)号：US06416654B1

公开(公告)日：2002-07-09

申请号：US08367418

申请日：1994-12-30

申请人： Tai-Sheng Chou ,  Nai Yuen Chen ,  Grant G. Karsner ,  Clinton R. Kennedy ,  Rene B. LaPierre ,  Melcon G. Melconian ,  Richard J. Quann ,  Stephen S. Wong

发明人： Tai-Sheng Chou ,  Nai Yuen Chen ,  Grant G. Karsner ,  Clinton R. Kennedy ,  Rene B. LaPierre ,  Melcon G. Melconian ,  Richard J. Quann ,  Stephen S. Wong

IPC分类号： C10G7342

CPC分类号： C10G45/64 ,  C10G47/16 ,  C10G47/36 ,  Y10S208/01

摘要： Nitrogenous compounds especially bases such as ammonia vapor are used to control the operation of a hydrocracker or catalytic dewaxer. Catalyst activity and selectivity may be controlled by addition of the base to the feed, for example, to control the balance between isomerization and hydrocracking in an operation using a zeolite beta catalyst. Runaway conditions may be controlled by the addition of nitrogenous compounds to regulate the temperature profile within the reactor.

摘要翻译： 氮化合物尤其是碱例如氨蒸汽用于控制加氢裂化器或催化脱蜡机的运行。 催化剂活性和选择性可以通过向进料添加碱来控制，例如在使用沸石β催化剂的操作中控制异构化和加氢裂化之间的平衡。 失控条件可以通过加入含氮化合物来控制，以调节反应器内的温度分布。

公开(公告)号：US4665245A

公开(公告)日：1987-05-12

申请号：US816072

申请日：1986-01-03

申请人： Richard J. Quann

发明人： Richard J. Quann

IPC分类号： C07C2/12 ,  B01J29/00 ,  C07B61/00 ,  C07C1/00 ,  C07C11/02 ,  C07C67/00 ,  C08F8/00 ,  C08F10/00 ,  C10G50/00 ,  C10G57/02 ,  C07C6/02

CPC分类号： C07C11/02

摘要： A process for preparing alpha-olefins is provided which comprises:(a) converting a feed containing one or more lower olefins in the presence of a medium pore crystalline silicate zeolite catalyst under reaction conditions providing a mixture of higher olefinic products;(b) contacting at least a part of the mixture of higher olefinic products resulting from step (a) with an alpha-olefin in the presence of a metathesis catalyst under olefin metathesis conditions to provide a mixture of alpha-olefins having a different carbon number than the feed olefin;(c) separating the alpha-olefin product of step (b) into at least two fractions, one fraction containing predominantly lower alpha-olefin hydrocarbons and the other fraction containing predominantly higher alpha-olefin hydrocarbons; and,(d) recycling at least a part of the lower alpha-olefin hydrocarbon fraction resulting from step (c) as feed for step (a).

摘要翻译： 提供一种制备α-烯烃的方法，其包括：（a）在提供高级烯烃产物的混合物的反应条件下，在中孔结晶硅酸盐沸石催化剂存在下，将含有一种或多种低级烯烃的进料转化; （b）在复分解催化剂存在下，在烯烃复分解条件下使步骤（a）得到的较高级烯烃产物的至少一部分混合物与α-烯烃接触，以提供具有不同碳数的α-烯烃的混合物 比进料烯烃; （c）将步骤（b）的α-烯烃产物分离成至少两个馏分，一个馏分含有主要较低的α-烯烃烃，另一部分含有主要高含量的α-烯烃; 和（d）将步骤（c）得到的低级α-烯烃烃级分的至少一部分再循环作为步骤（a）的进料。