Cellulose fiber and process for the production thereof

    公开(公告)号:US09963820B2

    公开(公告)日:2018-05-08

    申请号:US13001098

    申请日:2009-06-18

    Abstract: The invention concerns a cellulose fiber of the genus Lyocell which is treated with a cross-linking agent, with the cross-linking agent inducing a protection from fibrillation on the fiber and exhibiting the following properties: the protection from fibrillation induced by the cross-linking agent changes if the fiber is stored within a pH range from 4.0 to 10.0, in particular under the influence of moisture and/or heat, within the pH range from 4.0 to 10.0, an optimum value exists at which the stability of the protection from fibrillation induced by the cross-linking agent during storage is highest a suitable range exists around the optimum value in which the stability is reduced by 20% at the most, compared to the stability at the optimum value, within the pH range from 4.0 to 10.0, the suitable range is limited by at least one limiting value at which the stability is reduced by 20% compared to the long-term stability at the optimum value and with a further decrease in stability occurring below and above said value, respectively, and the cross-linking agent has the capability to change the pH value. The fiber according to the invention is characterized in that the fiber comprises a buffering substance in the suitable range and exhibits a buffer capacity of at least about 12 mmol/kg fiber, preferably from about 15 to about 70 mmol/kg fiber, in the suitable range.

    COATED SUBSTRATE
    4.
    发明申请
    COATED SUBSTRATE 审中-公开
    涂层基材

    公开(公告)号:US20120040175A1

    公开(公告)日:2012-02-16

    申请号:US13138690

    申请日:2010-03-19

    Abstract: Methods for coating a substrate are disclosed, the methods comprising providing a substrate, providing pre-formed nanoparticles of an inorganic material, providing at least one precursor of a first metal oxide, and depositing a coating on at least one surface of the substrate by contacting the surface with the precursor of the metal oxide and pre-formed nanoparticles. Also disclosed are substrates coated using such a method. The coated substrates are coloured. Preferably the metal oxide is a doped metal oxide to modify the thermal properties of the coating. The preferred nanoparticles are of platinum group metals or coinage metals.

    Abstract translation: 公开了涂覆基材的方法,所述方法包括提供基材,提供无机材料的预先形成的纳米颗粒,提供至少一种第一金属氧化物的前体,以及通过接触将沉积在基材的至少一个表面上的涂层 表面与金属氧化物的前体和预形成的纳米颗粒。 还公开了使用这种方法涂覆的基材。 涂覆的基材是着色的。 优选地,金属氧化物是掺杂的金属氧化物以改变涂层的热性能。 优选的纳米颗粒是铂族金属或造币金属。

    CELLULOSE FIBER AND PROCESS FOR THE PRODUCTION THEREOF
    5.
    发明申请
    CELLULOSE FIBER AND PROCESS FOR THE PRODUCTION THEREOF 有权
    纤维素纤维及其生产方法

    公开(公告)号:US20110171865A1

    公开(公告)日:2011-07-14

    申请号:US13001098

    申请日:2009-06-18

    Abstract: The invention concerns a cellulose fiber of the genus Lyocell which is treated with a cross-linking agent, with the cross-linking agent inducing a protection from fibrillation on the fiber and exhibiting the following properties: the protection from fibrillation induced by the cross-linking agent changes if the fiber is stored within a pH range from 4.0 to 10.0, in particular under the influence of moisture and/or heat, within the pH range from 4.0 to 10.0, an optimum value exists at which the stability of the protection from fibrillation induced by the cross-linking agent during storage is highest a suitable range exists around the optimum value in which the stability is reduced by 20% at the most, compared to the stability at the optimum value, within the pH range from 4.0 to 10.0, the suitable range is limited by at least one limiting value at which the stability is reduced by 20% compared to the long-term stability at the optimum value and with a further decrease in stability occurring below and above said value, respectively, and the cross-linking agent has the capability to change the pH value. The fiber according to the invention is characterized in that the fiber comprises a buffering substance in the suitable range and exhibits a buffer capacity of at least about 12 mmol/kg fiber, preferably from about 15 to about 70 mmol/kg fiber, in the suitable range.

    Abstract translation: 本发明涉及用交联剂处理的Lyocell属的纤维素纤维,其中交联剂诱导纤维上的原纤维保护并具有以下性质:通过交联诱导的免于原纤维化的保护 如果纤维在4.0至10.0的pH范围内,特别是在水分和/或热的影响下,在4.0至10.0的pH范围内储存,则会发生变化,存在保护免于原纤维化的稳定性的最佳值 在保存期间由交联剂诱导的最高值是在与最佳值下的稳定性相比在4.0至10.0的pH范围内最稳定性降低20%的最佳值存在适当的范围, 合适的范围受到与最佳值下的长期稳定性相比稳定性降低20%的极限值和稳定性进一步降低的至少一个极限值的限制 环分别低于和高于所述值,并且交联剂具有改变pH值的能力。 根据本发明的纤维的特征在于纤维包含适当范围的缓冲物质,并且在合适的范围内表现出至少约12mmol / kg纤维,优选约15至约70mmol / kg纤维的缓冲能力 范围。

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