Unsaturated polycations and their preparation and use
    1.
    发明授权
    Unsaturated polycations and their preparation and use 失效
    不饱和聚阳离子及其制备和用途

    公开(公告)号:US5973108A

    公开(公告)日:1999-10-26

    申请号:US75662

    申请日:1998-05-11

    CPC分类号: C08F8/44 C08F8/48

    摘要: Novel water-soluble homo- or copolymers are described which comprise 1,1-diallyl-3,4-dimethylenepyrrolidinium cations in the polymer and can additionally include 1,1-dialkyl-3,4-dimethylenepyrrolidinium cations. The polymers are prepared by first polymerizing a diallylammonium salt of the formula [(CH.sub.2 .dbd.CH--CH.sub.2).sub.2 NH.sub.2 ].sup.+ X.sup.- in which X.sup.- is the anion of any Bronstedt acid and, preferably, a halide, alone or together with an unsaturated comonomer, and reacting the resulting polymer or copolymer with a base and an allyl halide. The novel polymers are preferably used for treating textiles.

    摘要翻译: 描述了在聚合物中包含1,1-二烯丙基-3,4-二甲基吡咯烷鎓阳离子的新型水溶性均聚物或共聚物,并且还可以包括1,1-二烷基-3,4-二甲基苯并吡咯鎓阳离子。 通过首先聚合式[(CH 2 = CH-CH 2)2 NH 2] + X-的二烯丙基铵盐制备聚合物,其中X-是任何Br + E,uml + EEstedt酸的阴离子,优选地, 卤化物,单独或与不饱和共聚单体一起,并使所得聚合物或共聚物与碱和烯丙基卤反应。 新型聚合物优选用于处理织物。

    Mixtures of long-chain alkyl phosphates
    3.
    发明授权
    Mixtures of long-chain alkyl phosphates 失效
    长链烷基磷酸酯的混合物

    公开(公告)号:US6066753A

    公开(公告)日:2000-05-23

    申请号:US151865

    申请日:1998-09-11

    CPC分类号: B01F17/0064 Y10S516/01

    摘要: The invention relates to mixtures of long-chain alkyl phosphates of the formula ##STR1## in which R is a mixture of C.sub.12 -C.sub.22, preferably C.sub.14 -C.sub.20, straight-chain alkyl radicals and C.sub.12 -C.sub.22, preferably C.sub.14 -C.sub.20, .beta.-branched alkyl radicals, and X and Y are identical or different and are hydrogen, alkali metal or an equivalent of an alkaline earth metal, ammonium, mono-, di- or tri-alkylammonium or an organic base, or X and/or Y are as defined under R. These esters are suitable as emulsifiers, in particular for oil-in-water emulsions of a cosmetic pharmaceutical nature.

    摘要翻译: 本发明涉及下式的长链烷基磷酸酯的混合物,其中R是C12-C22,优选C14-C20,直链烷基和C12-C22,优选C14-C20,β-支链烷基的混合物 ,X和Y相同或不同,为氢,碱金属或当量的碱土金属,铵,一,二或三烷基铵或有机碱,或X和/或Y定义如下 这些酯适合用作乳化剂,特别是用于化妆品药物性质的水包油乳剂。

    Mixtures of alkylphosphoric esters and use thereof as cosmetic and pharmaceutical emulsifiers
    4.
    发明授权
    Mixtures of alkylphosphoric esters and use thereof as cosmetic and pharmaceutical emulsifiers 失效
    烷基磷酸酯的混合物及其作为化妆品和药物乳化剂的用途

    公开(公告)号:US06541016B1

    公开(公告)日:2003-04-01

    申请号:US09031430

    申请日:1998-02-26

    IPC分类号: A61K700

    摘要: This invention relates to monoalkyl phosphoric esters, dialkyl phosphoric esters, and, in small amounts, trialkyl phosphoric esters or salts thereof, which are preferably based on &bgr;-branched fatty alcohols, particularly Guerbet alcohol, which are effective in lowering the surface tension of both polar and also nonpolar liquids, and which have high stability, even at elevated temperatures, and low sensitivity to electrolytes and acids. The invention further relates to the use of such mixtures as emulsifiers in cosmetic and pharmaceutical formulations, and to the resulting products.

    摘要翻译: 本发明涉及单烷基磷酸酯,二烷基磷酸酯和少量三烷基磷酸酯或其盐,其优选基于β-支链脂肪醇,特别是格尔伯特醇,它们有效降低两者的表面张力 极性和非极性液体,甚至在高温下也具有高稳定性,对电解质和酸的敏感性低。 本发明还涉及这样的混合物在化妆品和药物制剂中的乳化剂以及所得产物的用途。

    Substantially water-insoluble cationized solids, and their preparation and use
    6.
    发明授权
    Substantially water-insoluble cationized solids, and their preparation and use 失效
    基本上不溶于水的阳离子化固体及其制备和用途

    公开(公告)号:US06184302B2

    公开(公告)日:2001-02-06

    申请号:US09075657

    申请日:1998-05-11

    申请人: Oliver Eyrisch

    发明人: Oliver Eyrisch

    IPC分类号: C05J27102

    CPC分类号: D21H21/10 D21H17/44

    摘要: The present invention relates to water-insoluble cationized solids obtained by treating solids with cationic homopolymers and/or copolymers comprising allylic and/or vinylic double bonds, where cationization is carried out using nitrogen-containing cationic polymers and/or copolymers which comprise from 0.5 to 100 mol-%, preferably from 5 to 20 mol-%, of said double bonds, based on nitrogen equivalents. The invention relates in particular to cationized solids obtained by cationization with allylated and/or vinylated derivatives of amino-containing polymers and/or copolymers. The invention also embraces the preparation of cationized solids by free-radical crosslinking of the abovementioned cationic polymers and/or copolymers in the presence of solids. The products obtained are in general at least 95% insoluble in water. They are obtained by cationizing mineral materials and, preferably, cellulose and are used preferably as retention aids and/or fixing agents in papermaking.

    摘要翻译: 本发明涉及通过用包含烯丙基和/或乙烯基双键的阳离子均聚物和/或共聚物处理固体而获得的水不溶性阳离子化固体,其中使用含氮阳离子聚合物和/或共聚物进行阳离子化,所述阳离子聚合物和/ 100摩尔%,优选5至20摩尔%的所述双键,基于氮当量。 本发明特别涉及通过阳离子化获得的含氨基聚合物和/或共聚物的烯丙基化和/或乙烯化衍生物获得的阳离子化固体。 本发明还包括通过在固体存在下自由基交联上述阳离子聚合物和/或共聚物来制备阳离子化固体。 所得产物通常至少不溶于水95%。 它们通过阳离子化矿物材料,优选纤维素获得,并且优选用作造纸中的助留剂和/或固定剂。

    Low-melting ester quats
    7.
    发明授权
    Low-melting ester quats 失效
    低熔点季铵盐

    公开(公告)号:US6072063A

    公开(公告)日:2000-06-06

    申请号:US807868

    申请日:1997-02-26

    摘要: Ester quats of the formula (1) below are described: ##STR1## where RCO is an aliphatic acyl radical having 6 to 22 carbon atoms, R.sup.1 is a methyl radical, R.sup.2 is a C.sub.1 -C.sub.6 -alkyl radical, R.sup.3 is a C.sub.3 -C.sub.6 -alkyl radical and X.sup.- is a halogen anion. They are prepared by quaternizing the corresponding carboxylic acid ethanolamine ester compound with a methyl halide in the absence or presence of solvents. The ester quats of the invention have a low melting point. Furthermore, even in high concentration they are highly water soluble and, on account of their preparation, are obtained in high purity and free from toxic contents. These ester quats can be used in many ways and are suitable, for example, for preparing solid or aqueous formulations having a high surfactant effect.

    摘要翻译: 其中,RCO为碳原子数为6〜22的脂肪族酰基,R1为甲基,R2为C1-C6烷基,R3为C3-C6烷基, 自由基和X-是卤素阴离子。 它们通过在不存在或不存在溶剂的情况下用甲基卤化物将相应的羧酸乙醇胺酯化合物季铵化来制备。 本发明的酯季度具有低熔点。 此外,即使在高浓度下,它们是高度水溶性的,并且由于其制备,获得高纯度且没有有毒物质。 这些酯季铵盐可以以许多方式使用,并且适用于例如制备具有高表面活性剂效果的固体或水性制剂。

    High-concentration aqueous ester quat solutions
    8.
    发明授权
    High-concentration aqueous ester quat solutions 失效
    高浓度水性酯季溶液

    公开(公告)号:US5811385A

    公开(公告)日:1998-09-22

    申请号:US835843

    申请日:1997-04-23

    CPC分类号: B01F17/0042 C11D1/62

    摘要: The ester quat solutions described contain at least 70% by weight, based on the solution, of at least one ester quat compound of the formula below ##STR1## where RCO is an aliphatic acyl radical having 6 to 22 carbon atoms, R' is H or a C.sub.1 to C.sub.22 alkyl radical, R.sup.1 is a methyl or ethyl radical, R.sup.2 is a C.sub.1 to C.sub.8 alkyl radical, R.sup.3 is a C.sub.3 to C.sub.8 alkyl radical and X.sup.- is a halide, alkyl carbonate, alkyl phosphate or an alkyl sulfate, where alkyl is methyl or ethyl. They are prepared by quaternizing corresponding carboxylic acid alkanolamine esters with, preferably, methyl chloride or dimethyl sulfate. The aqueous solutions described are advantageously suitable for preparing laundry detergents and cosmetics.

    摘要翻译: 所描述的酯季溶液含有至少70重量%的至少一种下式的酯季铵化合物至少70重量%,其中RCO是具有6-22个碳原子的脂族酰基,R'是H 或C 1至C 22烷基,R 1为甲基或乙基,R 2为C 1至C 8烷基,R 3为C 3至C 8烷基,X为卤化物,烷基碳酸酯,烷基磷酸酯或烷基硫酸酯, 其中烷基是甲基或乙基。 它们通过用优选氯甲烷或硫酸二甲酯将相应的羧酸链烷醇胺酯季铵化来制备。 所述的水溶液有利地适用于制备衣物洗涤剂和化妆品。