摘要:
The method for producing the optical semiconductor of the present disclosure includes a mixing step of producing a mixture containing a reduction inhibitor and a niobium compound that contains at least oxygen in its composition; a nitriding step of nitriding the mixture by the reaction between the mixture and a nitrogen compound gas; and a washing step of isolating niobium oxynitride from the material obtained through the nitriding step by dissolving chemical species other than niobium oxynitride with a washing liquid. The optical semiconductor of the present disclosure substantially consists of niobium oxynitride having a crystal structure of baddeleyite and having a composition represented by the composition formula, NbON.
摘要:
The hydrogen production device of the present invention includes: a first electrode (120) including a conductive substrate (101) and a photocatalytic semiconductor layer (102); a second electrode (103) that is electrically connected to the first electrode (120) and disposed in a second region (123) opposite to a first region (122) relative to the first electrode (120), when the first region (122) is defined as a region on a side of a surface of the first electrode (120) in which the photocatalytic semiconductor layer (102) is provided; a water-containing electrolyte solution (106); and a housing (105) containing these. The first electrode (120) is provided with a through-hole (131) at a position and the second electrode (103) is provided with a through-hole (132) at a position corresponding to the position, and the through-holes form a communicating hole (130) for allowing the first region (122) and the second region (123) to communicate with each other. An ion exchange membrane (104) having substantially the same shape as the communicating hole (130) is disposed in the communicating hole (130) to close the communicating hole (130).
摘要:
A photoelectrochemical cell (1) includes: an optical semiconductor electrode (first electrode) (3) including a conductive substrate (3a) and an n-type semiconductor layer (3b) as an optical semiconductor layer disposed on the conductive substrate (3a); a counter electrode (second electrode) (4) disposed to face the surface of the optical semiconductor electrode (3) on the conductive substrate (3a) side and connected electrically to the conductive substrate (3a); an electrolyte solution (11) containing water and disposed in contact with the surface of the n-type semiconductor layer (3b) and the surface of the counter electrode (4); a container (2) in which the optical semiconductor electrode (3), the counter electrode (4), and the electrolyte solution (11) are disposed; an inlet (5) for supplying water into the container; and an ion passing portion (12) that allows ions to move between the electrolyte solution in a region A on the surface side of the n-type semiconductor layer (3b) and the electrolyte solution in a region B on the opposite side of the region A with respect to the optical semiconductor electrode (3).
摘要:
Provided are a photocatalytic material that improves a decomposition performance and a decomposition rate, as well as a photocatalytic member and a purification device in which the photocatalytic material is used. The photocatalytic member is a photocatalytic member (1) that includes a substrate (10) and a photocatalyst layer (11) formed on a surface of the substrate (10), wherein the photocatalyst layer (11) contains a titanium oxide photocatalyst and zeolite, the titanium oxide photocatalyst containing at least an anatase-type titanium oxide and fluorine, in which a content of the fluorine in the titanium oxide photocatalyst is 2.5 wt % to 3.5 wt %, and 90 wt % or more of the fluorine is chemically bonded to the anatase-type titanium oxide.
摘要:
A material which conducts protons or oxide ions with high ionic conductivity and is excellent in moisture resistance and reduction resistance is provided. A perovskite oxide represented by the formula (1): BaZraCebM1cL1dO3-α (1) (wherein M1 is at least one member selected from the group consisting of rare earth elements, In, Mn, Fe, Co, Ni, Al and Ga, L1 is at least one member selected from the group consisting of P, B and N and a, b, c, d and a satisfy 0≦a
摘要翻译:提供了具有高离子电导率并且具有优异的耐湿性和还原性的质子或氧离子的材料。 由式(1)表示的钙钛矿型氧化物:BaZraCebM1cL1dO3-α(1)(其中M1为选自稀土元素,In,Mn,Fe,Co,Ni,Al和Ga中的至少一种,Ga,L1 是选自P,B和N中的至少一个,a,b,c,d和α满足0 <= a <1.2,0
摘要:
A material which conducts protons or oxide ions with high ionic conductivity and is excellent in moisture resistance and reduction resistance is provided. A perovskite oxide represented by the formula (1): BaZraCebM1cL1dO3-α (1) (wherein M1 is at least one member selected from the group consisting of rare earth elements, In, Mn, Fe, Co, Ni, Al and Ga, L1 is at least one member selected from the group consisting of P, B and N and a, b, c, d and a satisfy 0≦a
摘要:
A solid electrolyte fuel cell including a protonic oxide conductor having a composition represented by Ba(Zr1−xCex)1−yMyAlzO3−α (M: one or more kinds of elements selected from a group of tri-valent rare earth elements and In, 1≧x≧0, 0.3>y>0, 0.04>z≧0, and 1.5>α>0); and an electrode that is mainly made of platinum and has catalysis properties; wherein an electrolyte has a film thickness of 300 μm or less, and a method of manufacturing the same are disclosed. The solid electrolyte fuel cell can obtain a cell output even at low temperatures equal to 500 degrees centigrade or less.
摘要:
A hydrocarbon sensor of the present invention includes a substrate made of a solid electrolyte that conducts protons, and a pair of electrodes formed on the substrate, and at least one electrode of the pair of electrodes contains Au and Al. Assuming that a content of an Al simple substance in one of the pair of electrodes is “a” mol %, and a content of aluminum oxide therein is “b” mol %, “a” and “b” satisfy a relationship: a+2b≦7.
摘要:
A mixed ionic conductor with an ion conductive oxide has a perovskite structure of the formula BadZr1−x−yCexMy3O3−&ggr; wherein M3 is at least one element selected from the group consisting of Sm, Eu, Gd, Tb, Yb, Y, Sc, and In; with 0.98≦d≦1; 0.01≦x
摘要翻译:具有离子导电氧化物的混合离子导体具有式BadZr1-x-yCexMy3O3-gamma的钙钛矿结构,其中,M3是选自由Sm,Eu,Gd,Tb,Yb,Y,Sc, 和In 其中0.98 <= d <= 1; 0.01 <= x <0.5; 0.01 <= y <= 0.3; (2 + y-2d)/ 2 <=γ<1.5。 这种混合离子导体不仅具有用于诸如燃料电池的电化学装置所必需的导电性,而且具有优异的耐湿性。
摘要:
A limiting-current-type hydrocarbon sensor comprising a solid electrolyte formed of a barium-cerium-based oxide, capable of detecting hydrocarbon stably and accurately regardless of whether no oxygen is present or a high concentration of oxygen is present. The cathode on the surface of the solid electrolyte is formed of an alloyed layer including Au and Al. In particular, an alloyed layer including an Al—Au intermediate phase is suited for the alloyed layer of the cathode. The alloyed layer comprises a first layer including an Al—Au intermediate phase and making contact with the surface of the solid electrolyte and a second layer including a metal Al phase and covering the first layer. The Al phase of the alloyed layer blocks oxygen, and the Al—Au intermediate phase smoothens hydrogen association and reduces the resistance of the electrode. The hydrocarbon sensor can thus detect hydrocarbon accurately even when oxygen is included in an atmosphere.