公开(公告)号：US5411756A

公开(公告)日：1995-05-02

申请号：US175332

申请日：1993-12-29

Applicant: Edward L. Wheeler ,  Ronald P. D'Amelia ,  Gilbert A. Leveille ,  Michael S. Otterburn ,  Lawrence P. Klemann ,  John W. Finley ,  Allan D. Roden ,  Michael M. Chrysam ,  Turiddu A. Pelloso ,  Peter S. Given, Jr.

Inventor： Edward L. Wheeler ,  Ronald P. D'Amelia ,  Gilbert A. Leveille ,  Michael S. Otterburn ,  Lawrence P. Klemann ,  John W. Finley ,  Allan D. Roden ,  Michael M. Chrysam ,  Turiddu A. Pelloso ,  Peter S. Given, Jr.

IPC: A21D2/16 ,  A23C11/04 ,  A23C19/055 ,  A23D7/00 ,  A23D7/015 ,  A23D7/02 ,  A23D9/00 ,  A23G1/00 ,  A23G1/36 ,  A23G1/38 ,  A23G3/34 ,  A23G9/32 ,  A23G9/52 ,  A23K1/18 ,  A23L1/19 ,  A23L1/30 ,  A23L1/36 ,  C07C69/30 ,  C11C3/04 ,  C11C3/08 ,  C11C3/10

CPC classification number: A23G1/36 ,  A21D2/165 ,  A23C11/04 ,  A23C19/055 ,  A23D7/001 ,  A23D7/003 ,  A23D7/015 ,  A23D7/02 ,  A23D9/00 ,  A23G1/38 ,  A23G3/343 ,  A23G3/346 ,  A23G9/327 ,  A23G9/52 ,  A23K50/42 ,  A23L25/20 ,  A23L33/115 ,  A23L33/12 ,  A23L9/22 ,  C07C69/30 ,  C11C3/04 ,  C11C3/08 ,  C11C3/10 ,  A23G2200/08 ,  Y10S426/804

Abstract: Fat mixtures enriched with triglycerides having long, saturated, preferably C.sub.16 to C.sub.22, fatty acid residues and short, preferably C.sub.2 to C.sub.4, acid residues are employed in edible compositions as low calorie fats. The preferred embodiments comprise mixtures of at least two triglycerides bearing long residues (e.g. stearyl) and short residues (e.g. acetyl or propyl). In one preferred embodiment, each triglyceride contains short chain residues which are different from those in the other triglyceride. In another preferred embodiment, at least a portion of the triglycerides have two different short residues. Methods of using the low calorie fats and food products incorporating them, particularly in coating, shortening and margarine products, are disclosed.

公开(公告)号：US5378490A

公开(公告)日：1995-01-03

申请号：US83795

申请日：1993-06-28

Applicant: Edward L. Wheeler ,  Ronald P. D'Amelia ,  Gilbert A. Leveille ,  Michael S. Otterburn ,  Lawrence P. Klemann ,  John W. Finley ,  Allan D. Roden ,  Michael M. Chrysam ,  Turiddu A. Pelloso ,  Peter S. Given, Jr.

Inventor： Edward L. Wheeler ,  Ronald P. D'Amelia ,  Gilbert A. Leveille ,  Michael S. Otterburn ,  Lawrence P. Klemann ,  John W. Finley ,  Allan D. Roden ,  Michael M. Chrysam ,  Turiddu A. Pelloso ,  Peter S. Given, Jr.

IPC: A21D2/16 ,  A23C11/04 ,  A23C19/055 ,  A23D7/00 ,  A23D7/015 ,  A23D7/02 ,  A23D9/00 ,  A23G1/00 ,  A23G1/36 ,  A23G1/38 ,  A23G3/34 ,  A23G9/32 ,  A23G9/52 ,  A23K1/18 ,  A23L1/19 ,  A23L1/30 ,  A23L1/36 ,  C07C69/30 ,  C11C3/04 ,  C11C3/08 ,  C11C3/10

CPC classification number: A23G1/36 ,  A21D2/165 ,  A23C11/04 ,  A23C19/055 ,  A23D7/001 ,  A23D7/003 ,  A23D7/015 ,  A23D7/02 ,  A23D9/00 ,  A23G1/38 ,  A23G3/343 ,  A23G3/346 ,  A23G9/327 ,  A23G9/52 ,  A23K50/42 ,  A23L25/20 ,  A23L33/115 ,  A23L33/12 ,  A23L9/22 ,  C07C69/30 ,  C11C3/04 ,  C11C3/08 ,  C11C3/10 ,  A23G2200/08 ,  Y10S426/804

Abstract: Fat mixtures enriched with triglycerides having long, saturated, preferably C.sub.16 to C.sub.22, fatty acid residues and short, preferably C.sub.2 to C.sub.4, acid residues are employed in edible compositions as low calorie fats. The preferred embodiments comprise mixtures of at least two triglycerides bearing long residues (e.g. stearyl) and short residues (e.g. acetyl or propyl). In one preferred embodiment, each triglyceride contains short chain residues which are different from those in the other triglyceride. In another preferred embodiment, at least a portion of the triglycerides have two different short residues. Methods of using the low calorie fats and food products incorporating them, particularly in coating, shortening and margarine products, are disclosed.

公开(公告)号：US5286512A

公开(公告)日：1994-02-15

申请号：US690743

申请日：1991-04-24

Applicant: Lawrence P. Klemann ,  John W. Finley ,  Anthony Scimone

Inventor： Lawrence P. Klemann ,  John W. Finley ,  Anthony Scimone

IPC: A23K1/16 ,  A21D2/16 ,  A23C9/152 ,  A23C9/154 ,  A23C19/05 ,  A23C19/055 ,  A23C19/093 ,  A23D7/01 ,  A23D7/015 ,  A23D9/013 ,  A23G1/00 ,  A23G1/30 ,  A23G3/00 ,  A23G3/34 ,  A23G9/32 ,  A23G9/44 ,  A23G9/52 ,  A23K1/18 ,  A23L1/19 ,  A23L1/307 ,  A23L1/308 ,  C07C69/28 ,  C11C3/00 ,  A23D9/00

CPC classification number: A23C9/1528 ,  A23C19/054 ,  A23C19/055 ,  A23C9/1544 ,  A23D7/013 ,  A23D9/013 ,  A23K50/42 ,  A23L33/26 ,  C07C69/28 ,  C07C69/533 ,  C07C69/58 ,  Y10S426/804

Abstract: Diol lipid analogues, notably fatty acid diesters of various dihydric alcohols containing 4 to 10 carbon atoms, are physiologically compatible fat replacements for edible compositions. Preferred compounds are partially digestible.

Abstract translation: 二醇脂质类似物，特别是含有4-10个碳原子的各种二元醇的脂肪酸二酯，是用于食用组合物的生理上相容的脂肪替代物。 优选的化合物是部分可消化的。

公开(公告)号：US5219604A

公开(公告)日：1993-06-15

申请号：US654863

申请日：1991-02-13

Applicant: Lawrence P. Klemann ,  John W. Finley

Inventor： Lawrence P. Klemann ,  John W. Finley

IPC: A23D7/01 ,  A23L1/30

CPC classification number: A23D7/013 ,  A23L33/12 ,  Y10S426/804

Abstract: The use of inter- and intra-molecular ester bridges of the formula--O--(CO)--(CH.sub.2).sub.n --(CO)--O--where n=1 to 8, between fatty side chains attached to fat compounds is disclosed. These ester bridges, which can be used with both fat mimetics and triglycerides, suppress caloric availability and modulate the functional characteristics of the compounds. Methods of forming and using the bridged structures, and food compositions incorporating them are disclosed.

Abstract translation: 公开了在脂肪化合物的脂肪侧链之间使用式-O-（CO） - （CH2）n-（CO）-O-（其中n = 1至8）的分子内和分子内的酯桥。 这些可与脂肪模拟物和甘油三酯一起使用的酯桥抑制热量的可利用性并调节化合物的功能特征。 公开了形成和使用桥连结构的方法以及掺入其中的食物组合物。

公开(公告)号：US5139807A

公开(公告)日：1992-08-18

申请号：US626845

申请日：1990-12-13

Applicant: Lawrence P. Klemann ,  John W. Finley ,  Ronald G. Yarger

Inventor： Lawrence P. Klemann ,  John W. Finley ,  Ronald G. Yarger

IPC: A21D2/24 ,  A21D10/00 ,  A21D13/06 ,  A21D13/08 ,  A23C9/152 ,  A23C19/05 ,  A23C20/00 ,  A23D7/01 ,  A23D7/015 ,  A23D9/013 ,  A23G3/34 ,  A23K1/18 ,  A23L1/18 ,  A23L1/187 ,  A23L1/19 ,  A23L1/30 ,  A23L1/317 ,  A23L1/38

CPC classification number: A21D13/068 ,  A21D10/00 ,  A21D2/24 ,  A23C19/054 ,  A23C20/00 ,  A23C9/1528 ,  A23D7/013 ,  A23D7/015 ,  A23D9/013 ,  A23G3/346 ,  A23K50/40 ,  A23L13/65 ,  A23L25/10 ,  A23L33/115 ,  A23L7/17 ,  A23L9/10 ,  A23L9/22 ,  A23C2250/25 ,  A23G2200/00 ,  A23G2200/08 ,  A23G2200/10

Abstract: Novel fat mimetic compositions are disclosed to be useful in reduced calorie foods. These compounds, which can be referred to as amide linked fat mimetics, consist of fragments bearing ester, ether, and/or amide groups joined by an aliphatic or alicyclic group through at least one amide linkage. These complex amide linked fat mimetics may be partially broken down in the body to produce digestion residues which are substantially nondigestible themselves and are sufficiently hydrophilic to enable the digestion residues to be incorporated in the normal stool. These fat mimetic compounds are useful as replacements for fats and oils for most food applications.

Abstract translation: 公开了新的脂肪模拟组合物可用于减少热量的食物。 这些被称为酰胺连接的脂肪模拟物的化合物由带有酯，醚和/或酰胺基的片段组成，所述片段通过至少一个酰胺键被脂肪族或脂环族基团连接。 这些复合酰胺连接的脂肪模拟物可以在体内被部分分解以产生自身基本上不易消化的消化残余物，并且足够亲水以使消化残余物能够结合到正常的粪便中。 这些脂肪模拟化合物可用作大多数食品应用中脂肪和油的替代品。

公开(公告)号：US5068119A

公开(公告)日：1991-11-26

申请号：US590298

申请日：1990-09-28

Applicant: Lawrence P. Klemann ,  John W. Finley

Inventor： Lawrence P. Klemann ,  John W. Finley

IPC: A21D2/14 ,  A23C9/152 ,  A23D7/01 ,  A23D9/013 ,  A23G3/34 ,  A23L1/19 ,  A23L1/30 ,  A23L1/308 ,  C07C69/708

CPC classification number: C07C69/708 ,  A21D2/14 ,  A23C9/1528 ,  A23D7/013 ,  A23D9/013 ,  A23G3/346 ,  A23L33/115 ,  A23L33/25 ,  A23L9/22 ,  A23G2200/08 ,  Y10S426/804

Abstract: Acid-hydrolyzable ester derivatives, notably compounds having the following formula ##STR1## where ##STR2## X=H, an alkyl having 1 to 4 carbons, --O--(CO)--R, or --(CO)--O--R, or mixtures thereof,Y=H, an alkyl having 1 to 4 carbons, or --(CO)--O--R,R=an aliphatic group having 1 to 29 carbons,m=0, 1, or 2,n=0, 1, or 2, andp=0, 1, or 2,are a new class of edible fat mimetics suitable for use in neutral or alkaline food compositions.

Abstract translation: 酸可水解的酯衍生物，特别是具有下式的化合物：其中X = H，具有1至4个碳的烷基，-O-（CO）-R或 - （CO）-OR或其混合物 其中Y = H，具有1至4个碳的烷基或 - （CO）-OR，R =具有1至29个碳的脂族基团，m = 0,1或2，n = 0,1或2 和p = 0,1或2是适用于中性或碱性食品组合物的新一类可食用脂肪模拟物。

公开(公告)号：US4927659A

公开(公告)日：1990-05-22

申请号：US312076

申请日：1989-02-16

Applicant: Lawrence P. Klemann ,  John W. Finley ,  Anthony Scimone

Inventor： Lawrence P. Klemann ,  John W. Finley ,  Anthony Scimone

IPC: A23G3/00 ,  A21D2/16 ,  A23D7/01 ,  A23D9/013 ,  A23G3/34 ,  A23G9/32 ,  A23G9/44 ,  A23G9/52 ,  A23L9/10 ,  A23L27/60 ,  A23L33/20 ,  A61K31/25 ,  A61K36/00 ,  A61P3/04 ,  C07C69/30 ,  C11C3/00

CPC classification number: C11C3/003 ,  A23D7/013 ,  A23D9/013 ,  A23L33/20 ,  Y10S426/804

Abstract: Trishydroxymethyl ethane and propane, esterified with fatty acids, are physiologically compatible, partially digestible edible synthetic fat replacements for foods and pharmaceuticals.

公开(公告)号：US4590288A

公开(公告)日：1986-05-20

申请号：US508937

申请日：1983-06-29

Applicant: Lawrence P. Klemann

Inventor： Lawrence P. Klemann

IPC: C07D213/38 ,  C07D333/20 ,  C07F1/00 ,  C07F3/00 ,  C07F1/08 ,  C07F15/02 ,  C07F15/04

CPC classification number: C07D333/20 ,  C07D213/38 ,  C07F1/005 ,  C07F3/003

Abstract: A polydentate binucleating ligand having at least four donor sites selected from N, O and S, complexed with two atoms of the same metal, forms a coordination complex useful in homogeneous catalysis. Most preferably, all the metal cations are Cu cations and the ligand has a meta-xylyl functionality.

Abstract translation: 具有选自N，O和S的至少四个供体位点的多齿双核配体，与相同金属的两个原子络合，形成可用于均相催化的配位络合物。 最优选地，所有金属阳离子是Cu阳离子，并且配体具有间二甲苯基官能团。

公开(公告)号：US4216192A

公开(公告)日：1980-08-05

申请号：US34579

申请日：1979-04-30

Applicant: Bhaskara M. L. Rao ,  Lawrence P. Klemann

Inventor： Bhaskara M. L. Rao ,  Lawrence P. Klemann

IPC: C01C3/20

CPC classification number: C01C3/20

Abstract: The present invention is directed to a method of making anhydrous lithium thiocyanate and solutions containing anhydrous lithium thiocyanate by reacting a thiocyanate reactant selected from the group consisting of inorganic ammonium thiocyanate, quaternary alkyl ammonium thiocyanates, trialkyl ammonium thiocyanates, non-lithium alkali metal thiocyanates and alkaline earth metal thiocyanates, with a lithium salt selected from the group consisting of LiClO.sub.4 ; LiAsF.sub.6 ; LiBF.sub.4 ; LiPF.sub.6 ; LiO.sub.3 SCF.sub.3 ; LiNO.sub.2 ; LiNO.sub.3 ; LiCl; LiBr; LiI; LiO.sub.2 CCF.sub.3 ; LiOC.sub.6 H.sub.5 ; LiB(C.sub.6 H.sub.5).sub.4 and LiBR.sub.4 wherein R is methyl, ethyl, butyl or mixtures thereof, in an organic solvent in which the reactants are soluble.

Abstract translation: 本发明涉及一种制备无水硫氰酸锂和含有无水硫氰酸锂的溶液的方法，该方法是将选自无机硫氰酸铵，硫氰酸季铵烷基铵，硫氰酸三烷基铵，非锂碱金属硫氰酸盐和 碱土金属硫氰酸盐，具有选自LiClO 4的锂盐; LiAsF6; LiBF4; LiPF6; LiO3SCF3; LiNO2; LiNO3; 锂离子 李伯 I LiO2CCF3; LiOC6H5; LiB（C 6 H 5）4和LiBR 4，其中R是甲基，乙基，丁基或其混合物，其中可溶于反应物的有机溶剂中。

公开(公告)号：US5662953A

公开(公告)日：1997-09-02

申请号：US555234

申请日：1995-11-08

Applicant: Edward L. Wheeler ,  Ronald P. D'Amelia ,  Gilbert A. Leveille ,  Michael S. Otterburn ,  Lawrence P. Klemann ,  John W. Finley ,  Allan D. Roden ,  Michael M. Chrysam ,  Turiddu A. Pelloso ,  Peter S. Given, Jr.

Inventor： Edward L. Wheeler ,  Ronald P. D'Amelia ,  Gilbert A. Leveille ,  Michael S. Otterburn ,  Lawrence P. Klemann ,  John W. Finley ,  Allan D. Roden ,  Michael M. Chrysam ,  Turiddu A. Pelloso ,  Peter S. Given, Jr.

IPC: A21D2/16 ,  A23D7/00 ,  A23D7/015 ,  A23D9/00 ,  A23G1/00 ,  A23G1/36 ,  A23G1/38 ,  A23G3/34 ,  A23G9/32 ,  C07C69/30 ,  C11C3/04 ,  C11C3/08 ,  C11C3/10

CPC classification number: A23G1/36 ,  A21D2/165 ,  A23D7/001 ,  A23D7/003 ,  A23D7/015 ,  A23D9/00 ,  A23G1/38 ,  A23G3/343 ,  A23G3/346 ,  A23G9/327 ,  C07C69/30 ,  C11C3/04 ,  C11C3/08 ,  C11C3/10 ,  A23G2200/08 ,  Y10S426/804

Abstract: Fat mixtures enriched with triglycerides having long, saturated, preferably C.sub.16 to C.sub.22, fatty acid residues and short, preferably C.sub.2 to C.sub.4, acid residues are employed in edible compositions as low calorie fats. The preferred embodiments comprise mixtures of at least two triglycerides bearing long residues (e.g. stearyl) and short residues (e.g. acetyl or propyl). In one preferred embodiment, each triglyceride contains short chain residues which are different from those in the other triglyceride. In another preferred embodiment, at least a portion of the triglycerides have two different short residues. Methods of using the low calorie fats and food products incorporating them, particularly in coating, shortening and margarine products, are disclosed.

Abstract translation: 富含甘油三酸酯的脂肪混合物在食用组合物中用作低卡路里脂肪，其具有长的，饱和的，优选C16至C22的脂肪酸残基和短的，优选为C2至C4的酸残基。 优选的实施方案包括具有长残基（例如硬脂基）和短残基（例如乙酰基或丙基）的至少两种甘油三酯的混合物。 在一个优选的实施方案中，每个甘油三酸酯含有与其它甘油三酸酯不同的短链残基。 在另一个优选的实施方案中，甘油三酯的至少一部分具有两个不同的短残基。 公开了使用含有低热量脂肪和食品的方法，特别是在涂料，起酥油和人造黄油产品中。