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公开(公告)号：US5798306A
公开(公告)日：1998-08-25
申请号：US835899
申请日：1997-04-14
CPC分类号： C03C3/112 , C03C3/062 , C03C3/11 , C03C4/0071 , H01S3/17 , H01S3/1603 , H01S3/1608 , H01S3/173
摘要： The oxyhalide rare earth doped laser glass of the present invention comprises the substitution of fluorine for oxygen in glasses having the general molar batch composition of 50% SiO.sub.2, 25% CaO, 25% Al.sub.2 O.sub.3 to improve the distribution of rare earth dopants in the glass. The general molar batch composition of the invention ranges from approximately 45-70% SiO.sub.2, 15-35% CaO, 10-25% Al.sub.2 O.sub.3, 4-15% Al.sub.2 F.sub.6, and 0.001-2% Er.sub.2 O.sub.3. This substitution of fluorine into the 2SiO.sub.2. Al.sub.2 O.sub.3. CaO glass system provides erbium doped laser glasses having a Er.sub.2 O.sub.3 batch content of 0.01 mole % Er.sub.2 O.sub.3 to 1.2 mole % Er.sub.2 O.sub.3 (500 ppm Er.sub.2 O.sub.3 to 5.68 wt. % Er.sub.2 O.sub.3) which show little to no concentration quenching and exhibit useful fluorescence lifetimes of approximately 6 milliseconds (ms) or greater.
摘要翻译： 本发明的卤氧化物稀土掺杂激光玻璃包括在具有一般摩尔批次组成为50％SiO 2，25％CaO，25％Al 2 O 3的玻璃中用氟代替氧，以改善玻璃中稀土掺杂剂的分布。 本发明的一般摩尔批次组合物的范围为约45-70％的SiO 2，15-35％的CaO，10-25％的Al 2 O 3，4-15％的Al 2 F 6和0.001-2％的Er 2 O 3。 氟取代为2SiO2。 Al2O3。 CaO玻璃系统提供具有Er2O3批次含量为0.01摩尔％Er 2 O 3至1.2摩尔％Er 2 O 3（500ppm Er 2 O 3至5.68重量％Er 2 O 3）的掺铒激光玻璃，其显示出很少至无浓度猝灭并且显示出约6毫秒的有用荧光寿命 （ms）以上。
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2.发明授权公开(公告)号：US08975199B2
公开(公告)日：2015-03-10
申请号：US13569756
申请日：2012-08-08
申请人： Bruce Gardiner Aitken , James Edward Dickinson, Jr. , Timothy James Kiczenski , John Christopher Mauro , Adama Tandia
发明人： Bruce Gardiner Aitken , James Edward Dickinson, Jr. , Timothy James Kiczenski , John Christopher Mauro , Adama Tandia
IPC分类号： C03C3/087 , H01L31/048 , C03C3/091 , C03C17/34 , C03C17/36 , H01L31/0392
CPC分类号： C03C3/097 , C03C3/087 , C03C3/091 , C03C3/093 , C03C3/095 , C03C17/3429 , C03C17/3452 , C03C17/3678 , C03C2217/94 , H01L31/03923 , H01L31/03925 , H01L31/0488 , Y02E10/541 , Y02P70/521
摘要： A compositional range of high strain point and/or intermediate expansion coefficient alkali metal free aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CdTe or CIGS photovoltaic devices or crystalline silicon wafer devices. These glasses can be characterized as having strain points≧600° C., thermal expansion coefficient of from 35 to 50×10−7/° C.
摘要翻译： 本文描述了高应变点和/或中间膨胀系数的无碱金属铝硅酸盐和硼硅铝酸盐玻璃的组成范围。 该玻璃可以用作光伏器件的衬底或衬底，例如，诸如CdTe或CIGS光电器件或晶体硅晶片器件的薄膜光伏器件。 这些玻璃的特征在于应变点为≥600℃，热膨胀系数为35〜50×10-7 /℃。
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公开(公告)号：US08647995B2
公开(公告)日：2014-02-11
申请号：US12840754
申请日：2010-07-21
IPC分类号： C03C3/085 , C03C3/087 , C03C3/091 , H01L31/042 , H01L31/0288 , H01L31/0296
CPC分类号： H01L31/0352 , C03C3/085 , C03C3/087 , C03C3/091 , H01L31/03923 , Y02E10/541 , Y02E10/543
摘要： Sodium containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ≧535° C., for example, ≧570° C., thermal expansion coefficients of from 8 to 9 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.
摘要翻译： 本文描述了含钠硅酸铝和硼硅铝酸盐玻璃。 该玻璃可以用作光伏器件的衬底或衬底，例如，诸如CIGS光伏器件的薄膜光伏器件。 这些玻璃的特征在于应变点> = 535℃，例如> = 570℃，热膨胀系数为8至9ppm /℃，以及超过50,000泊的液相线粘度 。 因此，它们理想地适合于通过熔融法形成片材。
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4.发明申请公开(公告)号：US20110100058A1
公开(公告)日：2011-05-05
申请号：US12610026
申请日：2009-10-30
申请人： James Edward Dickinson, JR. , Richard Robert Grzybowski , Daniel R. Harvey , Stephan Lvovich Logunov , Alexander Mikhailovich Streltsov
发明人： James Edward Dickinson, JR. , Richard Robert Grzybowski , Daniel R. Harvey , Stephan Lvovich Logunov , Alexander Mikhailovich Streltsov
IPC分类号： C03B25/00
CPC分类号： C03B23/02 , C03B2215/414 , C03C23/0025 , E06B3/66304 , G02B6/02147
摘要： The disclosure teaches methods of forming at least one bump in a glass substrate having a surface and a body portion. The method includes performing a first irradiation of a portion of the glass substrate to form in the glass surface the at least one bump having bump height. The method also includes performing thermal annealing of at least a portion of the glass substrate that includes the first irradiated portion. The method then includes performing a second irradiation of the bump to increase the bump height.
摘要翻译： 本公开教导了在具有表面和主体部分的玻璃基板中形成至少一个凸块的方法。 该方法包括执行玻璃基板的一部分的第一次照射以在玻璃表面中形成具有凸起高度的至少一个凸块。 该方法还包括对包括第一照射部分的玻璃基板的至少一部分执行热退火。 该方法然后包括执行凸块的第二次照射以增加凸起高度。
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公开(公告)号：US09371247B2
公开(公告)日：2016-06-21
申请号：US12788763
申请日：2010-05-27
申请人： Bruce Gardiner Aitken , James Edward Dickinson, Jr. , Timothy J Kiczenski , Michelle Diane Pierson-Stull
发明人： Bruce Gardiner Aitken , James Edward Dickinson, Jr. , Timothy J Kiczenski , Michelle Diane Pierson-Stull
CPC分类号： C03C3/064 , C03C3/078 , C03C3/089 , C03C3/091 , H01L31/0296 , H01L31/0322 , H01L31/048 , Y02E10/541 , Y02P70/521
摘要： A compositional range of fusion-formable, high strain point sodium free, silicate, aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points≧540° C., thermal expansion coefficient of from 6.5 to 10.5 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.
摘要翻译： 本文描述了可熔融成型的高应变点无钠，硅酸盐，硅铝酸盐和硼硅铝酸盐玻璃的组成范围。 该玻璃可用作光电器件的基板，例如，诸如CIGS光伏器件的薄膜光伏器件。 这些玻璃的特征在于应变点≧540℃，热膨胀系数为6.5〜10.5ppm /℃，液相线粘度超过5万泊。 因此，它们理想地适合于通过熔融法形成片材。
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6.发明申请公开(公告)号：US20130037105A1
公开(公告)日：2013-02-14
申请号：US13569756
申请日：2012-08-08
申请人： Bruce Gardiner Aitken , James Edward Dickinson, JR. , Timothy James Kiczenski , John Christopher Mauro , Adama Tandia
发明人： Bruce Gardiner Aitken , James Edward Dickinson, JR. , Timothy James Kiczenski , John Christopher Mauro , Adama Tandia
IPC分类号： C03C3/091 , C03C3/087 , C03C3/089 , H01L31/0264 , C03C3/095 , C03C3/097 , B32B17/00 , H01L31/0376 , C03C3/085 , C03C3/093
CPC分类号： C03C3/097 , C03C3/087 , C03C3/091 , C03C3/093 , C03C3/095 , C03C17/3429 , C03C17/3452 , C03C17/3678 , C03C2217/94 , H01L31/03923 , H01L31/03925 , H01L31/0488 , Y02E10/541 , Y02P70/521
摘要： A compositional range of high strain point and/or intermediate expansion coefficient alkali metal free aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CdTe or CIGS photovoltaic devices or crystalline silicon wafer devices. These glasses can be characterized as having strain points ≧600° C., thermal expansion coefficient of from 35 to 50×10−7/° C.
摘要翻译： 本文描述了高应变点和/或中间膨胀系数的无碱金属铝硅酸盐和硼硅铝酸盐玻璃的组成范围。 该玻璃可以用作光伏器件的衬底或衬底，例如，诸如CdTe或CIGS光电器件或晶体硅晶片器件的薄膜光伏器件。 这些玻璃的特征在于应变点为≥600℃，热膨胀系数为35〜50×10-7 /℃。
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公开(公告)号：US20120132282A1
公开(公告)日：2012-05-31
申请号：US13305051
申请日：2011-11-28
IPC分类号： C03C3/093 , C03C3/14 , C03C3/145 , C03C3/078 , C03C3/089 , C03C3/091 , C03C3/085 , C03C3/087 , C03C3/062 , C03C3/064 , C03C3/066 , B32B5/00 , H01L31/02 , H01L31/0272 , C03C3/12
CPC分类号： C03C3/062 , C03C3/064 , C03C3/066 , C03C3/087 , C03C3/091 , C03C3/125 , C03C17/3476 , H01L31/03923 , Y02E10/541
摘要： A compositional range of high strain point alkali metal free, silicate, aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ≧570° C., thermal expansion coefficient of from 5 to 9 ppm/° C.
摘要翻译： 本文描述了高应变点无碱金属，硅酸盐，硅铝酸盐和硼硅铝酸盐玻璃的组成范围。 该玻璃可用作光电器件的基板，例如，诸如CIGS光伏器件的薄膜光伏器件。 这些玻璃的特征在于应变点≧570℃，热膨胀系数为5〜9ppm /℃。
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公开(公告)号：US09637408B2
公开(公告)日：2017-05-02
申请号：US12787711
申请日：2010-05-26
申请人： Bruce Gardiner Aitken , James Edward Dickinson, Jr. , Timothy J Kiczenski , Michelle Diane Pierson-Stull
发明人： Bruce Gardiner Aitken , James Edward Dickinson, Jr. , Timothy J Kiczenski , Michelle Diane Pierson-Stull
CPC分类号： H01L31/03925 , C01B19/007 , C01P2006/40 , C03C3/087 , C03C3/091 , H01L31/0296 , H01L31/0322 , H01L31/03923 , H01L31/0445 , Y02E10/541 , Y02E10/543
摘要： Sodium-containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ≧540° C., thermal expansion coefficient of from 6.5 to 9.5 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.
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公开(公告)号：US20100300536A1
公开(公告)日：2010-12-02
申请号：US12788763
申请日：2010-05-27
申请人： Bruce Gardiner Aitken , James Edward Dickinson, JR. , Timothy J. Kiczenski , Michelle Diane Pierson-Stull
发明人： Bruce Gardiner Aitken , James Edward Dickinson, JR. , Timothy J. Kiczenski , Michelle Diane Pierson-Stull
CPC分类号： C03C3/064 , C03C3/078 , C03C3/089 , C03C3/091 , H01L31/0296 , H01L31/0322 , H01L31/048 , Y02E10/541 , Y02P70/521
摘要： A compositional range of fusion-formable, high strain point sodium free, silicate, aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points≧540° C., thermal expansion coefficient of from 6.5 to 10.5 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.
摘要翻译： 本文描述了可熔融成型的高应变点无钠，硅酸盐，硅铝酸盐和硼硅铝酸盐玻璃的组成范围。 该玻璃可用作光电器件的基板，例如，诸如CIGS光伏器件的薄膜光伏器件。 这些玻璃的特征在于应变点≧540℃，热膨胀系数为6.5〜10.5ppm /℃，液相线粘度超过5万泊。 因此，它们理想地适合于通过熔融法形成片材。
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公开(公告)号：US20100300535A1
公开(公告)日：2010-12-02
申请号：US12787711
申请日：2010-05-26
申请人： Bruce Gardiner Aitken , James Edward Dickinson, JR. , Timothy J. Kiczenski , Michelle Diane Pierson-Stull
发明人： Bruce Gardiner Aitken , James Edward Dickinson, JR. , Timothy J. Kiczenski , Michelle Diane Pierson-Stull
CPC分类号： H01L31/03925 , C01B19/007 , C01P2006/40 , C03C3/087 , C03C3/091 , H01L31/0296 , H01L31/0322 , H01L31/03923 , H01L31/0445 , Y02E10/541 , Y02E10/543
摘要： Sodium-containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ≦540° C., thermal expansion coefficient of from 6.5 to 9.5 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.
摘要翻译： 本文描述了含钠硅铝酸盐和硼硅铝酸盐玻璃。 该玻璃可用作光电器件的基板，例如，诸如CIGS光伏器件的薄膜光伏器件。 这些玻璃可以表征为具有应变点＆nlE; 540℃，热膨胀系数为6.5至9.5ppm /℃，以及超过50,000泊的液相线粘度。 因此，它们理想地适合于通过熔融法形成片材。
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