Desulfurization process and novel bimetallic sorbent systems for same
    1.
    发明授权
    Desulfurization process and novel bimetallic sorbent systems for same 有权
    脱硫工艺和新型双金属吸附剂体系相同

    公开(公告)号:US07427581B2

    公开(公告)日:2008-09-23

    申请号:US10347915

    申请日:2003-01-21

    申请人: Gyanesh P. Khare

    发明人: Gyanesh P. Khare

    CPC分类号: C10G25/003 Y10S502/517

    摘要: Novel sorbent systems for the desulfurization of cracked-gasoline and diesel fuels are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promotors are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline and diesel fuels whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product. Such sorbents can also be utilized for the treatment of other sulfur-containing streams such as diesel fuels.

    摘要翻译: 提供用于裂化汽油和柴油燃料脱硫的新型吸附剂系统,其由诸如由氧化锌和无机或有机载体形成的颗粒载体上的双金属促进剂组成。 这样的双金属促进剂由镍,钴,铁,锰,铜,锌,钼,钨,银,锡,锑和钒中的至少两种金属形成,其价态被还原,优选为零。 提供了用于生产这种吸附剂的方法,其中吸附剂由浸渍的颗粒载体制备,或在颗粒化,干燥和煅烧之前与载体复合材料混合。 进一步公开的是使用这种新型吸附剂在裂化汽油和柴油燃料的脱硫中,由此不仅实现硫的去除,而且脱硫产物中的烯烃保留量也增加。 这种吸附剂也可用于处理其它含硫物流如柴油燃料。

    Sorbent compositions
    2.
    发明授权
    Sorbent compositions 有权
    吸附剂组合物

    公开(公告)号:US06350422B1

    公开(公告)日:2002-02-26

    申请号:US09575518

    申请日:2000-05-22

    IPC分类号: B01D5352

    摘要: A process for removing hydrogen sulfide from a fluid stream by contacting a hydrogen sulfide-containing stream with a sorbent composition wherein said sorbent composition is produced by mixing at least one zinc component which is zinc oxide or a compound convertible to zinc oxide, at least one silica component where the silica component comprises silica or a compound convertible to silica, at least one colloidal metal oxide, and optionally at least one pore generator component so as to form a mixture, extruding the mixture, sphering the resulting extrudate to form spherical particles having a size of form about 0.5 to about 15 millimeters drying the resulting spherical particles, calcining the dried particles, steaming the resulting calcined particles, sulfiding the steamed particles by contacting them with sulfides or sulfur at a temperature of about 200° C. to 1400° C. and subjecting the sulfided particles to a temperature sufficient to bum off substantially all of the sulfur on the sulfided particle so as to provide a sorbent composition having improved attrition and crush strength and which is then useful for the desulfurization of hydrogen sulfide-containing fluid stream.

    摘要翻译: 通过使含硫化氢的物流与吸附剂组合物接触来从流体物流中除去硫化氢的方法,其中所述吸附剂组合物是通过混合至少一种锌成分或氧化锌可转化成的化合物,至少一种 二氧化硅组分,其中二氧化硅组分包括二氧化硅或可转化为二氧化硅的化合物,至少一种胶体金属氧化物和任选的至少一个孔产生剂组分,以形成混合物,挤出混合物,将所得挤出物悬浮,形成具有 形成约0.5至约15毫米的尺寸,干燥所得的球形颗粒,煅烧干燥颗粒,蒸发所得煅烧颗粒,通过使蒸汽颗粒与硫化物或硫在大约200℃至1400℃的温度下接触来硫化蒸汽颗粒 并且使硫化颗粒经受足以烧毁基本上所有硫的温度的温度 以提供具有改善的磨耗和压碎强度的吸附剂组合物,然后可用于含硫化氢的流体物流的脱硫。

    Sorbent compositions
    5.
    发明授权
    Sorbent compositions 失效
    吸附剂组合物

    公开(公告)号:US5710089A

    公开(公告)日:1998-01-20

    申请号:US482696

    申请日:1995-06-07

    申请人: Gyanesh P. Khare

    发明人: Gyanesh P. Khare

    摘要: A process to make a sorbent composition said process comprising: (a) contacting (i) at least one zinc component, where said zinc component consists essentially of zinc oxide, or a compound convertible to zinc oxide, (ii) at least one silica component, where said silica component consists essentially of silica, or a compound convertible to silica, (iii) at least one colloidal oxide component, where said colloidal oxide component consists essentially of particles of a metal oxide where said metal oxide is selected from the group consisting of alumina, silica, titania, zirconia, tin oxide, antimony oxide, cerium oxide, yttrium oxide, copper oxide, iron oxide, manganese oxide, molybdenum oxide, tungsten oxide, chromium oxide, and mixtures thereof, (iv) at least one pore generator component, wherein the amount of pore generator is from 1 to about 15 weight percent based on the total weight of said sorbent composition, and wherein said sorbent composition consists essentially of components (a)(i) through (a)(iv) to form a moist composition, where said moist composition has a moisture content from about 22 to about 31 weight percent based on the weight of said moist composition; (b) extruding said moist composition to form an extruded, moist composition where said extruded, moist composition has a moisture content from about 22 to about 31 weight percent based on the weight of said extruded, moist composition; and (c) sphering said extruded, moist composition to form a sphered, extruded, moist composition that has a particle size from about 0.5 to about 15 millimeters.

    摘要翻译: 一种制备吸附剂组合物的方法,所述方法包括:(i)至少一种锌组分,其中所述锌组分基本上由氧化锌组成,或可转化为氧化锌的化合物,(ii)至少一种二氧化硅组分 其中所述二氧化硅组分基本上由二氧化硅或可转化为二氧化硅的化合物组成,(iii)至少一种胶体氧化物组分,其中所述胶态氧化物组分基本上由金属氧化物颗粒组成,其中所述金属氧化物选自 的氧化铝,二氧化硅,二氧化钛,氧化锆,氧化锡,氧化锑,氧化铈,氧化钇,氧化铜,氧化铁,氧化锰,氧化钼,氧化钨,氧化铬及其混合物,(iv) 发电机组件,其中基于所述吸附剂组合物的总重量,孔发生器的量为1至约15重量%,并且其中所述吸附剂组合物基本上由组分( a)(i)至(a)(iv)以形成湿润组合物,其中基于所述湿润组合物的重量,所述湿润组合物的水分含量为约22至约31重量% (b)挤出所述湿润组合物以形成挤出的湿润组合物,其中所述挤出的湿润组合物的水分含量基于所述挤出的湿润组合物的重量为约22至约31重量% 和(c)将所述挤出的湿润组合物拉伸以形成具有约0.5至约15毫米的粒度的纺丝,挤出,湿润的组合物。

    Isomerization process and catalyst therefor
    7.
    发明授权
    Isomerization process and catalyst therefor 失效
    异构化方法和催化剂

    公开(公告)号:US5202519A

    公开(公告)日:1993-04-13

    申请号:US941360

    申请日:1992-09-04

    申请人: Gyanesh P. Khare

    发明人: Gyanesh P. Khare

    摘要: A catalyst composition is prepared by mixing at least an aluminum halide (preferably AlCl.sub.3), at least one copper(II) salt (preferably CuCl.sub.2), calcium aluminate and at least one alcohol (preferably ethanol), shaping the mixture, and drying the shaped particles. The thus-obtained catalyst composition is employed in the isomerization of alkanes and/or cycloalkanes.

    摘要翻译: 通过将至少一种卤化铝(优选AlCl 3),至少一种铜(II)盐(优选CuCl 2),铝酸钙和至少一种醇(优选乙醇)混合来制备催化剂组合物,使混合物成形,并干燥成型 粒子。 由此获得的催化剂组合物用于烷烃和/或环烷烃的异构化。

    Processed support and methods of making and using same
    8.
    发明授权
    Processed support and methods of making and using same 有权
    处理的支持和制作和使用方法

    公开(公告)号:US08835341B2

    公开(公告)日:2014-09-16

    申请号:US13227037

    申请日:2011-09-07

    申请人: Gyanesh P. Khare

    发明人: Gyanesh P. Khare

    IPC分类号: B01J29/06

    摘要: A method for removing tightly bound sodium from a zeolitic support comprising contacting the support with a sodium specific removal agent to produce a treated support. A method comprising providing an aromatization catalyst comprising a treated support, and contacting the aromatization catalyst with a hydrocarbon feed in a reaction zone under conditions suitable for the production of an aromatic product. A catalyst support comprising an L-zeolite having less than 0.35 wt. % sodium.

    摘要翻译: 从沸石载体中去除紧密结合的钠的方法,包括使载体与特定钠去除剂接触以产生经处理的载体。 一种方法,包括提供包含经处理的载体的芳构化催化剂,并且在适合于生产芳族产物的条件下,使芳族化催化剂与反应区中的烃进料接触。 一种催化剂载体,其包含小于0.35wt。 %钠。

    Catalysts Having an Improved Crush Strength and Methods of Making and Using Same
    9.
    发明申请
    Catalysts Having an Improved Crush Strength and Methods of Making and Using Same 审中-公开
    具有改进的压碎强度的催化剂及其制造和使用方法

    公开(公告)号:US20130035530A1

    公开(公告)日:2013-02-07

    申请号:US13570940

    申请日:2012-08-09

    申请人: Gyanesh P. KHARE

    发明人: Gyanesh P. KHARE

    IPC分类号: C07C2/02 C07C4/18 C07C5/00

    摘要: A method of preparing a catalyst comprising selecting a zeolite having a mean particle size of equal to or less than about 6 microns, blending the zeolite with a binder and water to form a paste, shaping the paste into a bound zeolite support, adding a metal to the bound zeolite support to form a metalized catalyst support, and adding at least one halide to the metalized catalyst support to form the catalyst. A catalytic reforming process for converting hydrocarbons to aromatics comprising: contacting a catalyst comprising a silica bound zeolite, a Group VIII metal supported thereby, and at least one halide with a hydrocarbon feed in a reaction zone, wherein the silica bound zeolite comprises a zeolite having a mean particle size of equal to or less than about 6 microns and a median particle size of equal to or less than about 5 microns.

    摘要翻译: 一种制备催化剂的方法,包括选择平均粒度等于或小于约6微米的沸石,将沸石与粘合剂和水混合以形成糊料,将糊状物成型为结合的沸石载体,加入金属 与结合的沸石载体形成金属化催化剂载体,并向金属化的催化剂载体中加入至少一种卤化物以形成催化剂。 一种用于将烃转化为芳族化合物的催化重整方法,包括:将包含二氧化硅结合的沸石,由其负载的第Ⅷ族金属和至少一种卤化物与烃进料在反应区中的催化剂接触,其中二氧化硅结合的沸石包含沸石, 平均粒度等于或小于约6微米,中值粒度等于或小于约5微米。