-
公开(公告)号：US20140066585A1
公开(公告)日：2014-03-06
申请号：US14074426
申请日：2013-11-07
IPC分类号： C08F210/14
CPC分类号： C08F210/14 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/905 , C08F4/659 , C08F2500/04 , C08F2500/03 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F4/6411
摘要： Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed.
摘要翻译： 公开了包含多价杂芳基供体配体的第4族金属络合物及其作为烯烃聚合催化剂的组分的用途，特别适用于制备具有高全同立构规整度和低分子量的丙烯共聚物产物。
-
公开(公告)号：US08604145B2
公开(公告)日：2013-12-10
申请号：US13349860
申请日：2012-01-13
IPC分类号： C08F4/64 , C08F4/76 , C08F210/06
CPC分类号： C08F210/14 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/905 , C08F4/659 , C08F2500/04 , C08F2500/03 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F4/6411
摘要： Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene/ethylene copolymer products having high isotacticity and low molecular weight, are disclosed.
摘要翻译： 公开了包含多价杂芳基供体配体的第4族金属络合物及其作为烯烃聚合催化剂组分的用途，特别适用于制备具有高全同立构规整性和低分子量的丙烯/乙烯共聚物产物。
-
公开(公告)号：US08349984B2
公开(公告)日：2013-01-08
申请号：US13329486
申请日：2011-12-19
IPC分类号： C08F210/02
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08L7/00 , Y10S526/905 , C08F4/64193 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F4/659 , C08F2500/01 , C08F2500/08 , C08F2500/09 , C08F2/06
摘要： A catalyst composition comprising a zirconium complex of a polyvalent aryloxyether and a polymerization processes employing the same, especially a continuous, solution polymerization of ethylene and one or more C3-30 olefins or diolefins to prepare interpolymers having improved processing properties, are disclosed.
摘要翻译： 公开了一种催化剂组合物，其包含多价芳氧基醚的锆络合物和使用其的聚合方法，特别是乙烯和一种或多种C 3-30烯烃或二烯烃的连续溶液聚合以制备具有改进的加工性质的互聚物。
-
公开(公告)号：US08299189B2
公开(公告)日：2012-10-30
申请号：US12300863
申请日：2007-04-24
IPC分类号： C08F4/16 , C08F4/64 , C08F4/76 , C08F210/00 , C08F210/18
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08L7/00 , Y10S526/905 , C08F4/64193 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F4/659 , C08F2500/01 , C08F2500/08 , C08F2500/09 , C08F2/06
摘要： A catalyst composition comprising a zirconium complex of a polyvalent aryloxyether and the use thereof in a continuous solution polymerization of ethylene, one or more C3-30 olefins, and a conjugated or nonconjugated diene to prepare interpolymers having improved processing properties are disclosed.
摘要翻译： 公开了包含多价芳氧基醚的锆络合物的催化剂组合物及其在乙烯，一种或多种C 3-30烯烃和共轭或非共轭二烯的连续溶液聚合中的用途，以制备具有改进的加工性质的互聚物。
-
公开(公告)号：US20120088894A1
公开(公告)日：2012-04-12
申请号：US13329486
申请日：2011-12-19
IPC分类号： C08F210/14 , C08F210/04
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08L7/00 , Y10S526/905 , C08F4/64193 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F4/659 , C08F2500/01 , C08F2500/08 , C08F2500/09 , C08F2/06
摘要： A catalyst composition comprising a zirconium complex of a polyvalent aryloxyether and a polymerization processes employing the same, especially a continuous, solution polymerization of ethylene and one or more C3-30 olefins or diolefins to prepare interpolymers having improved processing properties, are disclosed.
摘要翻译： 公开了一种催化剂组合物，其包含多价芳氧基醚的锆络合物和使用其的聚合方法，特别是乙烯和一种或多种C 3-30烯烃或二烯烃的连续溶液聚合以制备具有改进的加工性质的互聚物。
-
公开(公告)号：US07344775B2
公开(公告)日：2008-03-18
申请号：US11669342
申请日：2007-01-31
IPC分类号： D01F6/30 , C08F210/06
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F110/06 , C08F210/06 , C08F2420/02 , Y10T428/2904 , Y10T428/2913 , Y10T428/2915 , Y10T428/2929 , Y10T442/3065 , Y10T442/608 , C08F4/64044 , C08F2500/12 , C08F2500/20 , C08F2500/24 , C08F210/16 , C08F2500/15 , C08F2500/08 , C08F2500/03 , C08F2500/26
摘要： Fibers comprising a propylene homopolymer or a copolymer of propylene and at least one of ethylene and one or more unsaturated comonomers exhibit desirable properties. The homopolymers are characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. The copolymers are characterized as (A) comprising at least about 60 weight percent (wt %) of units derived from propylene, and (B) having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译： 包含丙烯均聚物或丙烯与乙烯和一种或多种不饱和共聚单体中的至少一种的共聚物的纤维显示出所需的性质。 均聚物的特征在于具有对应于约14.6和约15.7ppm的区域误差的大约相同强度的峰的13 C NMR峰。 共聚物的特征在于包含至少约60重量％（wt％）来自丙烯的单元的（A），和（B）具有以下特性中的至少一个：（i） 对应于约14.6和约15.7ppm的区域误差的NMR峰值，约等于强度的峰，（ii）当共聚物的共聚单体含量为至少约3重量％时，B值大于约1.4，（ iii）偏度指数S≈大于约-1.20，（iv）具有保持基本相同的T曲线，以及（ⅳ） 随着共聚物中共聚单体的量的增加而降低，和（v）比用齐格勒 - 纳塔（ZN）催化剂制备的可比较的共聚物报告更多的γ型晶体的X射线衍射图谱。
-
公开(公告)号：US06924342B2
公开(公告)日：2005-08-02
申请号：US10100557
申请日：2002-03-15
IPC分类号： C08F2/00 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F290/04 , C08L23/04 , C08L23/06 , C08L23/08 , C08F4/44 , B01J31/38 , C08F4/72
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymerization process comprises contacting one or more olefinic comonomers in the presence of at least a high molecular weight catalyst and at least a low molecular weight catalyst in a single reactor, and effectuating the polymerization of the olefinic comonomers in the reactor to obtain an olefin polymer. Preferably, both catalysts have the ability to incorporate a substantially similar amount of comonomers in the olefin polymer. The polymers produced by the process may have a relatively higher level of long chain branching while maintaining a relatively narrow molecular weight distribution, i.e., MWD less than about 6. These interpolymers may exhibit processability similar to or better than LDPE but have physical properties similar to metallocene catalyzed polymers.
摘要翻译： 聚合方法包括在单个反应器中在至少一种高分子量催化剂和至少一种低分子量催化剂的存在下使一种或多种烯属共聚单体接触，并使反应器中烯属共聚单体的聚合得到烯烃聚合物 。 优选地，两种催化剂具有在烯烃聚合物中引入基本相似量的共聚单体的能力。 通过该方法生产的聚合物可以具有相对较高水平的长链支化，同时保持相对窄的分子量分布，即MWD小于约6.这些互聚物可以表现出与LDPE相似或优于LDPE的加工性能，但具有类似于 茂金属催化聚合物。
-
公开(公告)号：US20120101241A1
公开(公告)日：2012-04-26
申请号：US12300863
申请日：2007-04-24
IPC分类号： C08F2/38 , C08F210/18 , C08F2/34
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08L7/00 , Y10S526/905 , C08F4/64193 , C08F210/08 , C08F2500/03 , C08F2500/12 , C08F4/659 , C08F2500/01 , C08F2500/08 , C08F2500/09 , C08F2/06
摘要： A catalyst composition comprising a zirconium complex of a polyvalent aryloxyether and the use thereof in a continuous solution polymerization of ethylene, one or more C3-30 olefins, and a conjugated or nonconjugated diene to prepare interpolymers having improved processing properties are disclosed.
摘要翻译： 公开了包含多价芳氧基醚的锆络合物的催化剂组合物及其在乙烯，一种或多种C 3-30烯烃和共轭或非共轭二烯的连续溶液聚合中的用途，以制备具有改进的加工性质的互聚物。
-
公开(公告)号：USRE42276E1
公开(公告)日：2011-04-05
申请号：US12604905
申请日：2009-10-23
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要翻译： 聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。 一些聚合物组合物的特征在于基本上不存在戊基或甲基支链和满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约12.5，y大于或等于 一些聚合物的特征在于满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约3，y大于或等于约4.5，以及 分子量分布大于3.还公开了制备聚合物的方法。
-
公开(公告)号：US07897679B2
公开(公告)日：2011-03-01
申请号：US11769491
申请日：2007-06-27
IPC分类号： C08K5/01
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , Y10T428/31909 , C08F4/659 , C08F4/65904 , C08F4/64144 , C08L2666/04 , C08L2666/06 , C08F2500/12 , C08F2500/20 , C08F2500/15 , C08F2500/24 , C08F2500/26 , C08F2500/03 , C08F2500/08 , C08F2/001
摘要： Unique copolymers comprising propylene, ethylene and/or one or more unsaturated comonomers are characterized as having: at least one, preferably more than one, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta catalyst These polypropylene polymers are made using a nonmetallocene, metal-centered, heteroaryl ligand catalyst. These polymers can be blended with other polymers, and are useful in the manufacture of films, sheets, foams, fibers and molded articles.
摘要翻译： 包含丙烯，乙烯和/或一种或多种不饱和共聚单体的独特共聚物的特征在于具有以下特性中的至少一个，优选多于一个：（i）对应于约14.6和约约14.6的区域误差的13 C NMR峰 15.7ppm，当共聚物的共聚单体含量为至少约3重量％时，约等于强度的峰，（ii）B值大于约1.4，（iii）偏度指数为6，大于约-1.20 ，（iv）具有保持基本相同的Tme的DSC曲线和随着共聚物中共聚单体的量增加而减小的Tmax，以及（v）报告更多的γ型晶体的X射线衍射图比 用齐格勒 - 纳塔催化剂制备的可比共聚物这些聚丙烯聚合物使用非金属茂金属中心的杂芳基配体催化剂制备。 这些聚合物可以与其它聚合物共混，并且可用于制造薄膜，片材，泡沫，纤维和模制品。
-
-
-
-
-
-
-
-
-
搜索结果
51 条记录 (耗时 0.037 秒)
