公开(公告)号：US09186617B2

公开(公告)日：2015-11-17

申请号：US13228652

申请日：2011-09-09

Applicant: David C. Calabro ,  Lisa S. Baugh ,  Pavel Kortunov ,  Benjamin A. McCool ,  Michael Siskin ,  Dennis G. Peiffer ,  Quanchang Li

Inventor： David C. Calabro ,  Lisa S. Baugh ,  Pavel Kortunov ,  Benjamin A. McCool ,  Michael Siskin ,  Dennis G. Peiffer ,  Quanchang Li

IPC: B01D53/62 ,  B01D53/14 ,  B01D53/77 ,  B01D53/78 ,  B01D53/96

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20478 ,  B01D2252/2056 ,  B01D2252/30 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

Abstract: A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.

Abstract translation: 描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子 溶剂在足以吸附至少一些CO 2的条件下进行。 然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。 该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富含CO 2的吸附剂溶液，然后循环至 用于解吸CO 2的再生区（有利地<100℃）。 在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

公开(公告)号：US08715397B2

公开(公告)日：2014-05-06

申请号：US13228869

申请日：2011-09-09

Applicant: Pavel Kortunov ,  Lisa S. Baugh ,  David C. Calabro ,  Michael Siskin ,  Preeti Kamakoti ,  Quanchang Li

Inventor： Pavel Kortunov ,  Lisa S. Baugh ,  David C. Calabro ,  Michael Siskin ,  Preeti Kamakoti ,  Quanchang Li

IPC: B01D53/14

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20478 ,  B01D2252/2056 ,  B01D2252/30 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

Abstract: A CO2 amine scrubbing process uses an absorbent mixture combination of an amine CO2 sorbent in combination with a non-nucleophilic, relatively stronger, typically nitrogenous, base. The weaker base(s) are nucleophilic and have the ability to react directly with the CO2 in the gas stream while the relatively stronger bases act as non-nucleophilic promoters for the reaction between the CO2 and the weaker base. The sorption and desorption temperatures can be varied by selection of the amine/base combination, permitting effective sorption temperatures of 70 to 90° C., favorable to scrubbing flue gas.

Abstract translation: CO 2胺洗涤方法使用胺二氧化碳吸附剂与非亲核相对较强的通常含氮碱的组合的吸收混合物组合。 较弱的碱是亲核的，并且具有与气流中的CO 2直接反应的能力，而相对较强的碱作为CO 2和较弱碱之间的反应的非亲核促进剂。 吸附和解吸温度可以通过选择胺/碱组合来改变，允许有效吸附温度为70-90℃，有利于洗涤烟道气。

公开(公告)号：US20120160097A1

公开(公告)日：2012-06-28

申请号：US13332576

申请日：2011-12-21

Applicant: Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki ,  Stephen M. Cundy

Inventor： Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki ,  Stephen M. Cundy

IPC: B01D53/62 ,  C08J9/00 ,  B01D53/02

CPC classification number: B01J20/262 ,  B01D53/02 ,  B01D2253/202 ,  B01D2253/311 ,  B01D2257/504 ,  B01J20/267 ,  B01J20/28069 ,  Y02C10/04 ,  Y02C10/08

Abstract: This disclosure involves an adsorption-desorption material, e.g., crosslinked epoxy-amine material having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and a CO2 adsorption capacity of at least about 0.2 millimoles CO2 per gram of crosslinked material, and/or linear epoxy-amine material having an Mw from about 160 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and a CO2 adsorption capacity of at least about 0.2 millimoles CO2 per gram of linear material. This disclosure also involves processes for preparing the crosslinked epoxy-amine materials and linear epoxy-amine materials, as well as selective removal of CO2 and/or other acid gases from a gaseous stream using the epoxy-amine materials.

Abstract translation: 该公开内容涉及吸附 - 解吸材料，例如具有约500至约1×10 6的Mw，约0.2cc / g至约2.0cc / g的总孔体积和CO 2吸附容量的交联的环氧胺材料 每克交联材料至少约0.2毫摩尔二氧化碳，和/或具有约160至约1×10 6 Mw的直链环氧胺材料，总孔体积为约0.2cc / g至约2.0cc / g， 和每克线性材料至少约0.2毫摩尔二氧化碳的CO2吸附容量。 本公开还涉及制备交联的环氧胺材料和线性环氧胺材料的方法，以及使用环氧胺材料从气流中选择性除去CO 2和/或其它酸性气体。

公开(公告)号：US07268195B2

公开(公告)日：2007-09-11

申请号：US11542517

申请日：2006-10-02

Applicant: Zerong Lin ,  David C. Calabro ,  James C. Vartuli

Inventor： Zerong Lin ,  David C. Calabro ,  James C. Vartuli

IPC: C08F4/02 ,  C08F4/22 ,  B01J21/16 ,  B01J23/26

CPC classification number: C08F10/00 ,  B01J29/045 ,  B01J35/002 ,  C08F110/02 ,  C08F210/16 ,  C08F4/025 ,  C08F4/24 ,  C08F2500/12 ,  C08F2500/07 ,  C08F210/14

Abstract: This invention relates to a catalyst system comprising a catalyst and a support comprising a non-layered inorganic porous crystalline phase material, wherein the support comprises a hexagonal arrangement of uniformly-sized pores having an average pore diameter greater than or equal to about 13 Å, an X-ray diffraction pattern having a calculated d100 value of greater than or equal to about 18 Å, an adsorption capacity of greater than or equal to about 15 grams benzene per 100 grams support at 50 torr and at 25° C., and a pore wall thickness of less then or equal to about 25 Å.

Abstract translation: 本发明涉及包含催化剂和包含非层状无机多孔结晶相材料的载体的催化剂体系，其中载体包括平均孔径大于或等于约的均匀尺寸孔的六边形排列， 具有大于或等于约18的计算值大于或等于约的X射线衍射图，在50托下每100克载体吸附量大于或等于约15克苯， 在25℃下，孔壁厚度小于或等于约25埃。

公开(公告)号：US6049018A

公开(公告)日：2000-04-11

申请号：US234544

申请日：1999-01-21

Applicant: David C. Calabro ,  Jane C. Cheng ,  Robert A. Crane, Jr. ,  Charles T. Kresge ,  Sandeep S. Dhingra ,  Michael A. Steckel ,  David L. Stern ,  Simon C. Weston

Inventor： David C. Calabro ,  Jane C. Cheng ,  Robert A. Crane, Jr. ,  Charles T. Kresge ,  Sandeep S. Dhingra ,  Michael A. Steckel ,  David L. Stern ,  Simon C. Weston

IPC: C07D487/04 ,  B01J29/04 ,  B01J29/70 ,  C01B39/08 ,  C01B39/46 ,  C01B39/48 ,  C07B61/00 ,  C07C2/54 ,  C07C2/66 ,  C07C4/18 ,  C07C5/22 ,  C07C5/27 ,  C07C6/12 ,  C07C15/073 ,  C07C15/085 ,  C07D209/56 ,  C07D487/00 ,  C01B39/50

CPC classification number: C07C6/126 ,  B01J29/04 ,  B01J29/70 ,  C01B39/085 ,  C01B39/48 ,  C07C2/66 ,  C07C4/18 ,  C07C5/2708 ,  C07C6/123 ,  C07C2529/70

Abstract: This invention relates to a new synthetic porous crystalline material, designated MCM-68, a method and novel polycyclic organic cation for its preparation and its use in catalytic conversion of organic compounds. The new crystalline material exhibits a distinctive X-ray diffraction pattern and has a unique crystal structure which contains at least one channel system, in which each channel is defined by a 12-membered ring of tetrahedrally coordinated atoms, and at least two further, independent channel systems, in each of which each channel is defined by a 10-membered ring of tetrahedrally coordinated atoms, wherein the number of unique 10-membered ring channels is twice the number of 12-membered ring channels.

Abstract translation: 本发明涉及一种新的合成多孔结晶材料，称​​为MCM-68，其制备方法和新型多环有机阳离子及其在有机化合物催化转化中的应用。 新的结晶材料表现出独特的X射线衍射图案，并且具有独特的晶体结构，其包含至少一个通道系统，其中每个通道由四面体配位的原子的12元环定义，并且至少两个独立的 通道系统，其中每个通道由四面体配位原子的10元环定义，其中唯一的10-元环通道的数目是12元环通道数目的两倍。

公开(公告)号：US09186618B2

公开(公告)日：2015-11-17

申请号：US13228734

申请日：2011-09-09

Applicant: Lisa S. Baugh ,  Pavel Kortunov ,  David C. Calabro ,  Michael Siskin

Inventor： Lisa S. Baugh ,  Pavel Kortunov ,  David C. Calabro ,  Michael Siskin

IPC: B01D53/62 ,  B01D53/78 ,  B01D53/96 ,  B01D53/14

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20478 ,  B01D2252/2056 ,  B01D2252/30 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

Abstract: Ionic liquids are capable of acting as solvents for amine CO2 absorbent compounds in CO2 separation processes and when so used enhance the sorption of the CO2 by the amine. A cyclic sorption process for separating CO2 from a gas stream, such as flue gas or natural gas, brings the gas stream into contact with an absorbent solution of an amine CO2 sorbent in an ionic liquid solvent followed by desorbing the CO2 to regenerate the amine.

Abstract translation: 离子液体能够作为二氧化碳分离过程中胺二氧化碳吸收剂化合物的溶剂，当这样使用时，胺可以增强二氧化碳的吸附。 用于从气流（例如废气或天然气）中分离CO 2的循环吸附方法使气流与胺CO 2吸附剂在离子液体溶剂中的吸收剂溶液接触，然后解吸CO 2以再生胺。

公开(公告)号：US09115260B2

公开(公告)日：2015-08-25

申请号：US13332500

申请日：2011-12-21

Applicant: Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki ,  Stephen M. Cundy

Inventor： Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki ,  Stephen M. Cundy

IPC: C07C211/48 ,  C07C211/50 ,  C07C211/49 ,  B01J20/26 ,  B01J20/22 ,  B01J20/28 ,  C08J9/26 ,  B01D53/02 ,  B01D53/62 ,  C08G73/02 ,  B01J20/30 ,  B01J20/34

CPC classification number: B01D53/02 ,  B01D53/40 ,  B01D53/62 ,  B01D2251/80 ,  B01D2253/202 ,  B01D2253/311 ,  B01D2256/24 ,  B01D2257/504 ,  B01D2258/0283 ,  B01J20/262 ,  B01J20/264 ,  B01J20/267 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/3085 ,  B01J20/3425 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/56 ,  C07C211/53 ,  C08G73/00 ,  C08G73/02 ,  C08G73/0206 ,  C08J9/141 ,  C08J9/26 ,  C08J9/28 ,  C08J2201/026 ,  C08J2201/0502 ,  C08J2203/14 ,  C08J2379/02 ,  Y02C10/04 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2982

Abstract: An adsorption-desorption material, in particular, crosslinked organo-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear organo-amine polymeric materials having an Mw from about 160 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear organo-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the adsorption-desorption materials.

Abstract translation: 一种吸附 - 解吸材料，特别是具有约500至约1×10 6 M w，约0.2cc / g至约2.0cc / g的总孔容积和在约0.2cc / g至约2.0cc / g的吸附能力的交联的有机 - 胺聚合物材料 每克吸附 - 解吸材料吸收最少约0.2毫摩尔的二氧化碳，和约160至约1×10 6的Mw，约0.2cc / g至约2.0cc / g的总孔体积的线性有机胺聚合物， 并且每克吸附 - 解吸材料吸附能力为至少约0.2毫摩尔吸附二氧化碳。 本公开还涉及制备交联和线性有机胺材料的方法，以及使用吸附 - 解吸材料从气流中选择性除去CO 2和/或其它酸性气体。

公开(公告)号：US08845886B2

公开(公告)日：2014-09-30

申请号：US13472832

申请日：2012-05-16

Applicant: David C. Calabro ,  Dennis G. Peiffer ,  Benjamin A. McCool ,  Stanley E. Jakubowicz

Inventor： David C. Calabro ,  Dennis G. Peiffer ,  Benjamin A. McCool ,  Stanley E. Jakubowicz

IPC: C10G31/09 ,  B01D39/00 ,  B01D39/14 ,  B01D39/20 ,  C08L79/08 ,  C08G73/10

CPC classification number: C08L79/08 ,  B01D39/2068 ,  C08G73/1082 ,  C08K3/22 ,  C10G31/09 ,  C10G2300/1033 ,  C10G2300/208

Abstract: This invention relates to a process for separating a hydrocarbon stream via a filtration process to produce an upgraded permeate stream with decreased Conradson Carbon Residue (“CCR”) content. The invention involves the modification of a porous ceramic filter by functionalizing the surface of the ceramic filter with an multi-ring aromatic-diimide polymer. Preferably, the multi-ring aromatic-diimide polymer is comprised of a multi-ring aromatic monomer component. The functionalized filters of the present invention can be used in a process to selectively separate components of a hydrocarbon stream to produce an improved permeate (or “filtrate”) product stream with a lower CCR content and improved processing capabilities. The functionalized filters of the present invention are particularly beneficial in filtration processes for upgrading heavy hydrocarbon feedstreams, such as whole crudes, topped crudes, synthetic crude blends, shale oils, oils derived from bitumens, oils derived from tar sands, atmospheric resids, vacuum resids, or other heavy hydrocarbon streams.

Abstract translation: 本发明涉及通过过滤方法分离烃流以产生具有降低的康拉多森碳残余物（“CCR”）含量的升级的渗透物流的方法。 本发明涉及通过用多环芳族 - 二酰亚胺聚合物官能化陶瓷过滤器的表面来改性多孔陶瓷过滤器。 优选地，多环芳族 - 二酰亚胺聚合物由多环芳族单体组分组成。 本发明的官能化过滤器可用于选择性地分离烃流的组分以产生具有较低CCR含量和改进的处理能力的改进的渗透物（或“滤液”）产物流的方法。 本发明的官能化过滤器特别有益于用于改质重烃原料流的过滤方法，例如整个原油，顶部原油，合成粗混合物，页岩油，来自沥青的油，源自沥青砂的油，常压渣油，真空渣油 ，或其他重质烃流。

公开(公告)号：US20120164044A1

公开(公告)日：2012-06-28

申请号：US13332512

申请日：2011-12-21

Applicant: Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki

Inventor： Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki

IPC: B01D53/04 ,  C08G73/02 ,  C08J9/00 ,  B01D53/047

CPC classification number: C08J9/26 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/62 ,  B01D2253/202 ,  B01D2253/311 ,  B01D2257/304 ,  B01D2257/504 ,  C08G73/02 ,  C08G73/0206 ,  C08J9/28 ,  C08J2201/026 ,  C08J2201/0502 ,  C08J2379/02 ,  Y02C10/04 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2982

Abstract: An adsorption-desorption material, in particular, crosslinked vinylepoxide-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear vinylepoxide-amine polymeric materials having an Mw from about 140 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear vinylepoxide-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the vinylepoxide materials.

Abstract translation: 吸附解吸材料，特别是具有约500至约1×10 6的Mw，约0.2cc / g至约2.0cc / g的总孔容积和在 每克吸附 - 解吸材料吸收最少约0.2毫摩尔的二氧化碳，以及Mw为约140至约1×10 6，总孔体积为约0.2cc / g至约2.0cc / g的线型乙烯氧化物 - 胺聚合物材料， 并且每克吸附 - 解吸材料吸附能力为至少约0.2毫摩尔吸附二氧化碳。 本公开还涉及制备交联和线性乙烯氧化物 - 胺材料的方法，以及使用乙烯氧化物材料从气流中选择性除去CO 2和/或其它酸性气体。

公开(公告)号：US20120164043A1

公开(公告)日：2012-06-28

申请号：US13332500

申请日：2011-12-21

Applicant: Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki ,  Stephen M. Cundy

Inventor： Dennis G. Peiffer ,  David C. Calabro ,  Quanchang Li ,  Mobae Afeworki ,  Stephen M. Cundy

IPC: B01D53/62 ,  C08J9/00 ,  C08G73/04 ,  B01D53/40

CPC classification number: B01D53/02 ,  B01D53/40 ,  B01D53/62 ,  B01D2251/80 ,  B01D2253/202 ,  B01D2253/311 ,  B01D2256/24 ,  B01D2257/504 ,  B01D2258/0283 ,  B01J20/262 ,  B01J20/264 ,  B01J20/267 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/3085 ,  B01J20/3425 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/56 ,  C07C211/53 ,  C08G73/00 ,  C08G73/02 ,  C08G73/0206 ,  C08J9/141 ,  C08J9/26 ,  C08J9/28 ,  C08J2201/026 ,  C08J2201/0502 ,  C08J2203/14 ,  C08J2379/02 ,  Y02C10/04 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2982

Abstract: An adsorption-desorption material, in particular, crosslinked organo-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear organo-amine polymeric materials having an Mw from about 160 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear organo-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the adsorption-desorption materials.

Abstract translation: 一种吸附 - 解吸材料，特别是具有约500至约1×10 6 M w，约0.2cc / g至约2.0cc / g的总孔容积和在约0.2cc / g至约2.0cc / g的吸附能力的交联的有机 - 胺聚合物材料 每克吸附 - 解吸材料吸收最少约0.2毫摩尔的二氧化碳，和约160至约1×10 6的Mw，约0.2cc / g至约2.0cc / g的总孔体积的线性有机胺聚合物， 并且每克吸附 - 解吸材料吸附能力为至少约0.2毫摩尔吸附二氧化碳。 本公开还涉及制备交联和线性有机胺材料的方法，以及使用吸附 - 解吸材料从气流中选择性除去CO 2和/或其它酸性气体。