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公开(公告)号：US5122360A
公开(公告)日：1992-06-16
申请号：US441793
申请日：1989-11-27
CPC分类号： C01B13/328 , B01J14/00 , B01J19/088 , B01J2208/00548 , C01P2004/32 , C01P2004/61 , C01P2004/62
摘要： The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.
摘要翻译： 本发明提供一种制备金属氧化物粉末的方法。 制备基本上是有机的第一溶液。 制备第二溶液，其是在第一溶液中基本上不混溶的水溶液，并且以液滴形式递送至第一溶液。 第二溶液的液滴通过形成第二溶液的微滴的脉冲电场而雾化。 第一溶液中的试剂扩散入第二溶液的微滴中并与反应物反应，形成金属氢氧化物或草酸盐颗粒。 然后回收金属氢氧化物或金属草酸盐颗粒并干燥以制备金属氧化物粉末。 还公开了一种制备金属氧化物粉末的装置。
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公开(公告)号：US4978647A
公开(公告)日：1990-12-18
申请号：US333064
申请日：1989-04-04
摘要： The invention is a gel bead comprising propylene glycol alginate and bone gelatin and is capable of removing metals such as Sr and Cs from solution without adding other adsorbents. The invention could have application to the nuclear industry's waste removal activities.
摘要翻译： 本发明是包含丙二醇藻酸盐和骨明胶的凝胶珠，并且能够从溶液中除去诸如Sr和Cs的金属而不添加其它吸附剂。 本发明可以应用于核工业的废物清除活动。
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3.发明授权Zirconium and hafnium separation in sulfate solutions using continuous ion exchange chromatography 失效使用连续离子交换层析在硫酸盐溶液中的锆和铪分离
公开(公告)号：US5618502A
公开(公告)日：1997-04-08
申请号：US502995
申请日：1995-07-17
申请人： Charles H. Byers , Warren G. Sisson , Thomas S. Snyder , Richard J. Beleski , Umesh P. Nayak , Timothy L. Francis
发明人： Charles H. Byers , Warren G. Sisson , Thomas S. Snyder , Richard J. Beleski , Umesh P. Nayak , Timothy L. Francis
IPC分类号： C01G27/00 , B01D15/02 , B01J41/20 , C01G25/00 , C22B3/42 , C22B34/14 , G01N30/02 , G01N30/58
CPC分类号： C22B34/14 , B01J41/20 , C01G25/003 , C22B3/42 , B01D2215/022 , G01N30/02 , G01N30/58 , Y02P10/234
摘要： A method and system for improved continuous ion exchange chromatographic elemental separations of zirconium and hafnium and also for isotopic separations thereof from crude zirconium minerals by using zirconium (also containing hafnium) sulfate feedstock solutions, sulfate eluant solutions, anionic exchange resins, and reduced ion exchange column operating temperatures. The method and system of the invention provides sulfate feedstock solutions by completely converting the carbochlorination products of zircon sand to sulfate solutions prior to feeding to the ion exchange chromatographic column. The method and system of the invention is performed in a continuously operating continuous annular chromatograph (CAC). Nuclear grade substantially purified zirconium and hafnium metals are produced.
摘要翻译： 通过使用锆（还含有铪）硫酸盐原料溶液，硫酸盐洗脱剂溶液，阴离子交换树脂和还原离子交换，改进锆和铪的连续离子交换色谱分离的方法和系统，以及与粗锆矿物的同位素分离 色谱柱工作温度。 本发明的方法和系统通过在送入离子交换色谱柱之前将锆石砂的碳氯化产物完全转化成硫酸盐溶液来提供硫酸盐原料溶液。 本发明的方法和系统在连续操作的连续环状色谱仪（CAC）中进行。 生产核级基本纯化的锆和铪金属。
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公开(公告)号：US5207973A
公开(公告)日：1993-05-04
申请号：US832091
申请日：1992-02-06
IPC分类号： B01J14/00 , B01J19/00 , B01J19/08 , B01J19/26 , B22F9/14 , C01B13/32 , C01B33/12 , C01F11/02 , C01F17/00 , C01G3/00 , C01G3/02 , C01G23/00 , C01G25/00
CPC分类号： C01G25/00 , B01J14/00 , B01J19/088 , B01J19/26 , B22F9/14 , C01B13/328 , C01B33/126 , C01F11/02 , C01F17/0043 , C01G23/003 , C01G3/006 , C01G3/02 , B01J2208/00548 , C01P2004/32 , C01P2004/61 , C01P2004/62
摘要： The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.
摘要翻译： 本发明提供一种制备金属氧化物粉末的方法。 制备基本上是有机的第一溶液。 制备第二溶液，其是在第一溶液中基本上不混溶的水溶液，并且以液滴形式递送至第一溶液。 第二溶液的液滴通过形成第二溶液的微滴的脉冲电场而雾化。 第一溶液中的试剂扩散入第二溶液的微滴中并与反应物反应，形成金属氢氧化物或草酸盐颗粒。 然后回收金属氢氧化物或金属草酸盐颗粒并干燥以制备金属氧化物粉末。 还公开了一种制备金属氧化物粉末的装置。
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5.发明授权Diffusion transfer film system with protective layer of copper salt, chitosan and selected polyols 失效具有铜盐，壳聚糖和选择的多元醇保护层的扩散转移膜系统
公开(公告)号：US4386151A
公开(公告)日：1983-05-31
申请号：US400906
申请日：1982-07-22
CPC分类号： G03C8/06
摘要： A silver diffusion transfer film unit which comprises, in order, a support, a silver precipitating layer, a protective layer comprising chitosan having a copper salt and a polyol selected from the group consisting of glycerol, sorbitol, polyvinyl alcohol, inositol, ethylene glycol, propylene glycol and hydroxyethyl cellulose disposed therein, a release layer, and a photosensitive silver halide layer. In a particularly preferred embodiment, the film unit is an additive color diffusion transfer film unit.
摘要翻译： 银扩散转移膜单元，其依次包括载体，银沉淀层，包含具有铜盐的壳聚糖的保护层和选自甘油，山梨醇，聚乙烯醇，肌醇，乙二醇， 设置在其中的丙二醇和羟乙基纤维素，脱模层和感光卤化银层。 在一个特别优选的实施方案中，胶片单元是一种加色扩散转移膜单元。
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6.发明授权Zirconium and hafnium separation in chloride solutions using continuous ion exchange chromatography 失效使用连续离子交换层析在氯化物溶液中的锆和铪分离
公开(公告)号：US5762890A
公开(公告)日：1998-06-09
申请号：US733893
申请日：1996-10-18
申请人： Charles H. Byers , Warren G. Sisson , Thomas S. Snyder , Richard J. Beleski , Timothy L. Francis , Umesh P. Nayak
发明人： Charles H. Byers , Warren G. Sisson , Thomas S. Snyder , Richard J. Beleski , Timothy L. Francis , Umesh P. Nayak
IPC分类号： G01N30/60 , B01D15/08 , B01D59/30 , B01J39/04 , B01J39/26 , B01J41/04 , B01J41/20 , C22B3/42 , C22B3/44 , C22B34/14 , G01N30/58 , G01N30/88 , C01G25/00 , C01G27/00
CPC分类号： B01D59/30 , B01D15/1892 , B01D15/361 , C22B3/44 , C22B34/14 , G01N30/58 , Y02P10/234
摘要： A method and system for improved ion exchange chromatographic elemental separations of zirconium and hafnium elements and also, if desired, separations of the isotopes thereof from crude zirconium minerals by using improved crude aqueous zirconium (also containing hafnium) chloride feedstock solutions, aqueous chloride eluant solutions, cationic or anionic exchange resins, and reduced ion exchange chromatographic operating temperatures. The method and system of the invention provides improved crude aqueous zirconium chloride feedstock solutions by carbochlorinating zircon sand and hydrolyzing and dissolving the chlorination products under controlled conditions to substantially eliminate cross-polymerization of the carbochlorination products, which undesirably yield inseparable zirconium and hafnium co-polymers during hydrolysis, by inhibiting the hydrolysis exotherm and/or the free acid generation during hydrolysis.
摘要翻译： 用于改进锆和铪元素的离子交换色谱分离的方法和系统，并且如果需要，通过使用改进的粗制水性锆（也含有铪）氯化物原料溶液，氯化铵水溶液溶液，将其与粗锆矿物分离 ，阳离子或阴离子交换树脂，以及降低的离子交换色谱操作温度。 本发明的方法和系统通过碳氢化锆石砂提供改进的粗氯化锆原料溶液，并在受控条件下水解和溶解氯化产物以基本上消除碳氯化产物的交联聚合，这不利地产生不可分离的锆和铪共聚物 在水解期间，通过抑制水解过程中的水解放热和/或游离酸的产生。
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公开(公告)号：US4915843A
公开(公告)日：1990-04-10
申请号：US276627
申请日：1988-11-28
IPC分类号： G01N30/26 , B01D15/08 , B01D15/18 , B01D15/42 , B01J39/26 , G01N30/02 , G01N30/58 , G01N30/60
CPC分类号： B01D15/1892 , B01D15/422 , B01J39/26 , G01N2030/587 , G01N30/02
摘要： Chromatographic species are continuously separated by displacement chromatography using an apparatus that comprises an inlet distribution manifold, a particulate bed, and a plurality of collector receptacles. The particulate bed is moved with respect to the inlet distributor manifold and the collector receptacles.
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公开(公告)号：US4838705A
公开(公告)日：1989-06-13
申请号：US59112
申请日：1987-06-08
摘要： The apparatus determines the content by weight of a volatile fluid, such as water, in a sample under test where the volatile fluid is typically less than one-half percent by weight by heating the sample in a sealed chamber to evaporate the volatile fluid under test. The evaporated fluid is passed through a collector which senses and collects only the evaporated volatile fluid of interest which collection correspondingly increases the weight of the collector. Measuring the weight change of the collector and comparing it with the initial weight of the test sample provides a determination of the percent of the sensed volatile fluid in the test sample.
摘要翻译： 该装置通过在密封室中加热样品以蒸发被测试的挥发性流体来确定待测试样品中的挥发性流体（例如水）的含量，其中挥发性流体通常小于重量百分之二十的重量百分比 。 蒸发的液体通过收集器，该收集器仅感测并收集所关注的蒸发的挥发性流体，该收集物相应地增加收集器的重量。 测量收集器的重量变化并将其与测试样品的初始重量进行比较，可以确定测试样品中感测到的挥发性液体的百分比。
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公开(公告)号：US4204869A
公开(公告)日：1980-05-27
申请号：US897945
申请日：1978-04-04
CPC分类号： G03C8/28
摘要： Silver-precipitating nuclei are prepared by partially oxidizing a stannous salt reducing agent and then reducing a noble metal salt or complex with said reducing agent.
摘要翻译： 通过部分氧化亚锡盐还原剂然后与所述还原剂还原贵金属盐或络合物来制备银沉淀核。
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公开(公告)号：US4995985A
公开(公告)日：1991-02-26
申请号：US514067
申请日：1990-04-25
摘要： The invention is a gel bead comprising propylene glycol alginate and bone gelatin and is capable of removing metals such as Sr and Cs from solution without adding other adsorbents. The invention could have application to the nuclear industry's waste removal activities.
摘要翻译： 本发明是包含丙二醇藻酸盐和骨明胶的凝胶珠，并且能够从溶液中除去诸如Sr和Cs的金属而不添加其它吸附剂。 本发明可以应用于核工业的废物清除活动。
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